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26
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note
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A multitopic ligand is one equipped with multiple coordination sites and, as a function of a rigid geometry, is unable to chelate to a metal center. This type of ligand should be contrasted with multidentate ligands such as ethylenediamine for which chelation is a common mode of binding.
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28
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Supramolecular Architecture
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2 structures. See (a) Bein, T., Ed., American Chemical Society: Washington, DC, Chapter 19
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2 structures. See (a) Robson, R.; Abrahams, B. F.; Batten, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. Supramolecular Architecture; Bein, T., Ed., ACS Symposium Series 499, American Chemical Society: Washington, DC, 1992; Chapter 19.
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Robson, R.1
Abrahams, B.F.2
Batten, S.R.3
Gable, R.W.4
Hoskins, B.F.5
Liu, J.6
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(b) Hoskins, B. F.; Robson, R.; Scarlett, N. V. Y. J. Chem. Soc., Chem. Commun. 1994, 2025-2026.
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Hoskins, B.F.1
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Scarlett, N.V.Y.3
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(c) Abrahams, B. F.; Hoskins, B. F.; Michail, D. M.; Robson, R. Nature 1994, 369, 727-729.
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Abrahams, B.F.1
Hoskins, B.F.2
Michail, D.M.3
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(d) Gardner G. B.; Venkataraman, D.; Moore, J. S.; Lee, S. Nature 1995, 374, 792-795.
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Gardner, G.B.1
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32
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33947334481
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For networks based on Ag-N coordination bonds, see: (a)
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For networks based on Ag-N coordination bonds, see: (a) Vranka, R. G.; Amma, E. L. Inorg. Chem. 1966, 5, 1020-1023.
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Inorg. Chem.
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Vranka, R.G.1
Amma, E.L.2
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33
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(b) Carlucci, L.; Ciani, G.; Proserpio, D. M.; Sironi, A. J. Chem. Soc., Chem. Commun. 1994, 2755-2756.
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34
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0029403184
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(c) Venkataraman, D.; Gardner, G. B.; Lee, S.; Moore, J. S. J. Am. Chem. Soc. 1995, 117, 11600-11601.
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(d) Hirsch, K. A.; Venkataraman, D.; Wilson, S. R.; Moore, J. S.; Lee, S. J. Chem. Soc., Chem. Commun. 1995, 2199-2200.
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Hirsch, K.A.1
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37
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0001143338
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Also see refs 2c,d and 6d
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(f) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1996, 118, 295-296. Also see refs 2c,d and 6d.
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Yaghi, O.M.1
Li, H.2
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38
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84892887551
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We have compiled a coordination geometry table of d-block transition metals and their ions from the structures contained in the Cambridge Structural Database. This table can be downloaded from the Internet as individual gif files from
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We have compiled a coordination geometry table of d-block transition metals and their ions from the structures contained in the Cambridge Structural Database. This table can be downloaded from the Internet as individual gif files from URL http://www.sulfur.scs.uiuc.edu.
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39
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84892851245
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For the details of the search, see: in press
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For the details of the search, see: Venkataraman, D.; Du, Y.; Wilson, S. R.; Hirsch, K. A.; Zhang, P.; Moore, J. S. J. Chem. Educ., in press.
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J. Chem. Educ.
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Venkataraman, D.1
Du, Y.2
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Hirsch, K.A.4
Zhang, P.5
Moore, J.S.6
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43
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33845278206
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For a review of coordination propensities of hexafluorophosphate and tetrafluoroborate ions and their comparison to triflate, see
-
For a review of coordination propensities of hexafluorophosphate and tetrafluoroborate ions and their comparison to triflate, see: Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405-1421.
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Chem. Rev.
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Beck, W.1
Sünkel, K.2
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84985631233
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Grimm, M.; Kirste, B.; Kurreck, H. Angew. Chem., Int. Ed. Engl. 1986, 25, 1097-1098.
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Blessing, R. H.; Coppens, P.; Becker, P. J. Appl. Cryst. 1974, 7, 488-492.
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Blessing, R.H.1
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50
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84892856712
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XPREP program module is available in the SHELXTL PLUS program marketed by Siemens, Inc., Madison, WI
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XPREP program module is available in the SHELXTL PLUS program marketed by Siemens, Inc., Madison, WI.
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52
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84892840136
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2 program is marketed by Molecular Simulations, Inc., Waltham, MA 02154
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2 program is marketed by Molecular Simulations, Inc., Waltham, MA 02154.
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53
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0002698918
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Yvon, K.; Jeitschko, W.; Parthe, E. J. Appl. Cryst. 1977, 10, 73-74.
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Yvon, K.1
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Parthe, E.3
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54
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0000216506
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Recently, Ciani and co-workers reported the crystal structure of [Ag(1,4-pyrazine)2]PF6. Undulating 2-D sheets constitute this structure. See
-
Recently, Ciani and co-workers reported the crystal structure of [Ag(1,4-pyrazine)2]PF6. Undulating 2-D sheets constitute this structure. See: Carlucci, L; Ciani, G.; Proserpio, D. M.; Sironi, A. Inorg. Chem. 1995, 34, 5698-5700.
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(1995)
Inorg. Chem.
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Carlucci, L.1
Ciani, G.2
Proserpio, D.M.3
Sironi, A.4
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55
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84892844002
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See ref 5, p 711
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See ref 5, p 711.
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56
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84892843174
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See ref 5, p 817
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See ref 5, p 817.
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84892872537
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For a rare example of six-coordinate silver(I), see ref 2d
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For a rare example of six-coordinate silver(I), see ref 2d.
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58
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84892893341
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It should be noted that additional steric constraints may also be introduced by the coordinating counterion
-
It should be noted that additional steric constraints may also be introduced by the coordinating counterion.
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59
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84892880310
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If only one ligand enters the coordination sphere, a network solid will not result
-
If only one ligand enters the coordination sphere, a network solid will not result.
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60
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84892897191
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The use of noncoordinating solvents such as benzene usually avoids the competition from the solvent to enter into the coordination sphere of the metal
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The use of noncoordinating solvents such as benzene usually avoids the competition from the solvent to enter into the coordination sphere of the metal.
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84892891135
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A linear chain structure consisting of alternating pyrazine and silver(I) units with a coordinating nitrate ion was reported by Vranka and Amma. See ref 7a
-
A linear chain structure consisting of alternating pyrazine and silver(I) units with a coordinating nitrate ion was reported by Vranka and Amma. See ref 7a.
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62
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84892885886
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A three-dimensional, diamondoid network of 4,4′-bipyridine and silver(I) triflate crystallized from isopropyl alcohol/acetone has been reported. See ref 7b
-
A three-dimensional, diamondoid network of 4,4′-bipyridine and silver(I) triflate crystallized from isopropyl alcohol/acetone has been reported. See ref 7b.
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64
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84892843212
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See ref 5, p 77
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See ref 5, p 77.
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65
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84892849200
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Submitted for publication
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(a) Venkataraman, D.; Gardner, G. B.; Covey, A. C.; Lee, S.; Moore, J. S. Submitted for publication.
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Venkataraman, D.1
Gardner, G.B.2
Covey, A.C.3
Lee, S.4
Moore, J.S.5
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