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Volumn 8, Issue 8, 1996, Pages 2030-2040

Coordination networks based on multitopic ligands and silver(I) salts: A study of network connectivity and topology as a function of counterion

Author keywords

[No Author keywords available]

Indexed keywords

CHAINLIKE STRUCTURE; COORDINATION BONDS; COORDINATION NETWORKS; HEXAFLUOROPHOSPHATES; MULTITOPIC LIGANDS; NETWORK CONNECTIVITY; STRUCTURAL STUDIES; SUPRAMOLECULAR NETWORKS;

EID: 0000680482     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm950594i     Document Type: Article
Times cited : (206)

References (66)
  • 1
    • 84892892931 scopus 로고
    • For leading references on hydrogen-bonded networks, see: (a) An issue of August was entirely devoted to organic solid-state chemistry, with special emphasis on hydrogen-bonded networks
    • For leading references on hydrogen-bonded networks, see: (a) An issue of Chemistry of Materials (August 1994) was entirely devoted to organic solid-state chemistry, with special emphasis on hydrogen-bonded networks.
    • (1994) Chemistry of Materials
  • 26
    • 84892862073 scopus 로고    scopus 로고
    • note
    • A multitopic ligand is one equipped with multiple coordination sites and, as a function of a rigid geometry, is unable to chelate to a metal center. This type of ligand should be contrasted with multidentate ligands such as ethylenediamine for which chelation is a common mode of binding.
  • 28
    • 0000407885 scopus 로고
    • Supramolecular Architecture
    • 2 structures. See (a) Bein, T., Ed., American Chemical Society: Washington, DC, Chapter 19
    • 2 structures. See (a) Robson, R.; Abrahams, B. F.; Batten, S. R.; Gable, R. W.; Hoskins, B. F.; Liu, J. Supramolecular Architecture; Bein, T., Ed., ACS Symposium Series 499, American Chemical Society: Washington, DC, 1992; Chapter 19.
    • (1992) ACS Symposium Series , vol.499
    • Robson, R.1    Abrahams, B.F.2    Batten, S.R.3    Gable, R.W.4    Hoskins, B.F.5    Liu, J.6
  • 32
    • 33947334481 scopus 로고
    • For networks based on Ag-N coordination bonds, see: (a)
    • For networks based on Ag-N coordination bonds, see: (a) Vranka, R. G.; Amma, E. L. Inorg. Chem. 1966, 5, 1020-1023.
    • (1966) Inorg. Chem. , vol.5 , pp. 1020-1023
    • Vranka, R.G.1    Amma, E.L.2
  • 37
    • 0001143338 scopus 로고    scopus 로고
    • Also see refs 2c,d and 6d
    • (f) Yaghi, O. M.; Li, H. J. Am. Chem. Soc. 1996, 118, 295-296. Also see refs 2c,d and 6d.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 295-296
    • Yaghi, O.M.1    Li, H.2
  • 38
    • 84892887551 scopus 로고    scopus 로고
    • We have compiled a coordination geometry table of d-block transition metals and their ions from the structures contained in the Cambridge Structural Database. This table can be downloaded from the Internet as individual gif files from
    • We have compiled a coordination geometry table of d-block transition metals and their ions from the structures contained in the Cambridge Structural Database. This table can be downloaded from the Internet as individual gif files from URL http://www.sulfur.scs.uiuc.edu.
  • 43
    • 33845278206 scopus 로고
    • For a review of coordination propensities of hexafluorophosphate and tetrafluoroborate ions and their comparison to triflate, see
    • For a review of coordination propensities of hexafluorophosphate and tetrafluoroborate ions and their comparison to triflate, see: Beck, W.; Sünkel, K. Chem. Rev. 1988, 88, 1405-1421.
    • (1988) Chem. Rev. , vol.88 , pp. 1405-1421
    • Beck, W.1    Sünkel, K.2
  • 50
    • 84892856712 scopus 로고    scopus 로고
    • XPREP program module is available in the SHELXTL PLUS program marketed by Siemens, Inc., Madison, WI
    • XPREP program module is available in the SHELXTL PLUS program marketed by Siemens, Inc., Madison, WI.
  • 52
    • 84892840136 scopus 로고    scopus 로고
    • 2 program is marketed by Molecular Simulations, Inc., Waltham, MA 02154
    • 2 program is marketed by Molecular Simulations, Inc., Waltham, MA 02154.
  • 54
    • 0000216506 scopus 로고
    • Recently, Ciani and co-workers reported the crystal structure of [Ag(1,4-pyrazine)2]PF6. Undulating 2-D sheets constitute this structure. See
    • Recently, Ciani and co-workers reported the crystal structure of [Ag(1,4-pyrazine)2]PF6. Undulating 2-D sheets constitute this structure. See: Carlucci, L; Ciani, G.; Proserpio, D. M.; Sironi, A. Inorg. Chem. 1995, 34, 5698-5700.
    • (1995) Inorg. Chem. , vol.34 , pp. 5698-5700
    • Carlucci, L.1    Ciani, G.2    Proserpio, D.M.3    Sironi, A.4
  • 55
    • 84892844002 scopus 로고    scopus 로고
    • See ref 5, p 711
    • See ref 5, p 711.
  • 56
    • 84892843174 scopus 로고    scopus 로고
    • See ref 5, p 817
    • See ref 5, p 817.
  • 57
    • 84892872537 scopus 로고    scopus 로고
    • For a rare example of six-coordinate silver(I), see ref 2d
    • For a rare example of six-coordinate silver(I), see ref 2d.
  • 58
    • 84892893341 scopus 로고    scopus 로고
    • It should be noted that additional steric constraints may also be introduced by the coordinating counterion
    • It should be noted that additional steric constraints may also be introduced by the coordinating counterion.
  • 59
    • 84892880310 scopus 로고    scopus 로고
    • If only one ligand enters the coordination sphere, a network solid will not result
    • If only one ligand enters the coordination sphere, a network solid will not result.
  • 60
    • 84892897191 scopus 로고    scopus 로고
    • The use of noncoordinating solvents such as benzene usually avoids the competition from the solvent to enter into the coordination sphere of the metal
    • The use of noncoordinating solvents such as benzene usually avoids the competition from the solvent to enter into the coordination sphere of the metal.
  • 61
    • 84892891135 scopus 로고    scopus 로고
    • A linear chain structure consisting of alternating pyrazine and silver(I) units with a coordinating nitrate ion was reported by Vranka and Amma. See ref 7a
    • A linear chain structure consisting of alternating pyrazine and silver(I) units with a coordinating nitrate ion was reported by Vranka and Amma. See ref 7a.
  • 62
    • 84892885886 scopus 로고    scopus 로고
    • A three-dimensional, diamondoid network of 4,4′-bipyridine and silver(I) triflate crystallized from isopropyl alcohol/acetone has been reported. See ref 7b
    • A three-dimensional, diamondoid network of 4,4′-bipyridine and silver(I) triflate crystallized from isopropyl alcohol/acetone has been reported. See ref 7b.
  • 64
    • 84892843212 scopus 로고    scopus 로고
    • See ref 5, p 77
    • See ref 5, p 77.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.