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Volumn 17, Issue 21, 1998, Pages 4597-4606

Reactivities of a bis(alkylidene) complex. Synthesis of a silyl bis(alkylidyne) complex and a reaction cycle among symmetric bis(alkylidyne), bis(alkylidene), and nonsymmetric bis(alkylidyne) compounds

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EID: 0001103870     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980652k     Document Type: Article
Times cited : (43)

References (74)
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    • (1980) J. Chem. Soc., Dalton Trans. , pp. 1771
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    • For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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    • For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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    • Reference 13
    • For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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    • (1991) J. Am. Chem. Soc. , vol.113 , pp. 6082
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    • For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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    • note
    • 2 = 0.926.
  • 69
    • 85034481099 scopus 로고    scopus 로고
    • note
    • 3) was observed. The mechanism for the formation of a small amount of the disilane is not clear.
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    • J. P. Thesis, ULP Strasbourg
    • (b) Le Ny, J. P. Thesis, ULP Strasbourg, 1984.
    • (1984)
    • Ny, L.1


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