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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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See, for example: (a) Aitken, C. T.; Harrod, J. F.; Samuel, E. J. Am Chem. Soc. 1986, 108, 4059. (b) Woo, H.-G.; Heyn, R. H.; Tilley, T. D. J. Am. Chem. Soc. 1992, 114, 5698. (c) Jiang, Q.; Pestana, D. C.; Carroll, P. J.; Berry, D. H. Organometallics 1994, 13, 3679. (d) Kreutzer, K. A.; Fisher, R. A.; Davis, W. M.; Spaltenstein, E.; Buchwald, S. L. Organometallics 1991, 10, 4031. (e) Corey, J. Y.; Zhu, X.-H. J. Organomet. Chem. 1992, 439, 1. (f) Kingston, B. M.; Lappert, M. F. J. Chem. Soc., Dalton Trans. 1972, 69. (g) Schubert, U.; Schenkel, A. Chem Ber. 1988, 121, 939. (h) Parkin, G.; Bunel, E.; Burger, B. J.; Trimmer, M. S.; Van Asselt, A.; Bercaw, J. E. J. Mol. Catal. 1987, 41, 21. (i) Hengge, E.; Weinberger, M. J. Organomet. Chem. 1992, 433, 21. (j) Takahashi, T.; Hasegawa, M.; Suzuki, N.; Saburi, M.; Rousset, C. J.; Fanwick, P. E.; Negishi, E. J. Am. Chem. Soc. 1991, 113, 8564. (k) For a more complete list, see reviews in ref 1.
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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49
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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51
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For other bridging alkylidene ligands, see: (a) Hartner, F. W., Jr.; Schwartz, J.; Clift, S. M. J. Am. Chem. Soc. 1983, 105, 640. (b) Hursthouse, M. B.; Jones, R. A.; Abdul Malik, K. M.; Wilkinson, G. J. Am. Chem. Soc. 1979, 101, 4128. (c) Schrock, R. R.; Sharp, P. R. J. Am. Chem. Soc. 1978, 100, 2389. (d) Schmidt, G. F.; Muetterties, E. L.; Beno; M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (e) Müller, J.; Passon, B.; Pickardt, J. J. Organomet. Chem. 1982, 228, C51. (f) Isobe, K.; Okeya, S.; Meanwell, N. J.; Smith, A. J.; Adams, H.; Maitlis, P. M. J. Chem. Soc., Dalton Trans. 1984, 1215. (g) Jones, R. A.; Wilkinson, G.; Galas, A. M. R.; Hursthouse; M. B.; Abdul Malik, K. M. J. Chem. Soc., Dalton Trans. 1980, 1771.
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2 contains two bridging halide ligands. Schultz, A. J.; Williams, J. M.; Schrock, R. R.; Rupprecht, G. A.; Fellmann, J. D. J. Am. Chem. Soc. 1979, 101, 1593. Rupprecht, G. A.; Messerle, L. W.; Fellmann, J. D.; Schrock, R. R. J. Am. Chem. Soc. 1980, 102, 6236.
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2 contains two bridging halide ligands. Schultz, A. J.; Williams, J. M.; Schrock, R. R.; Rupprecht, G. A.; Fellmann, J. D. J. Am. Chem. Soc. 1979, 101, 1593. Rupprecht, G. A.; Messerle, L. W.; Fellmann, J. D.; Schrock, R. R. J. Am. Chem. Soc. 1980, 102, 6236.
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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85034485822
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Reference 13
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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65
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0000353779
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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Caulton, K.G.1
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Streib, W.E.3
Xue, Z.4
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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Buchwald, S.L.1
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0000302056
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For activation parameters involving cyclometalation transition state, see, e.g.: (a) McDade, C.; Green, J. C.; Bercaw, J. E. Organometallics 1982, 1, 1629. (b) Bulls, A. R.; Schaefer, W. P.; Serfas, M.; Bercaw, J. E. Organometallics 1987, 6, 1219. (c) Vilardo, J. S.; Lockwood, M. A.; Hanson, L. G.; Clark, J. R.; Parkin, B. C.; Fanwick, P. E.; Rothwell, I. P. J. Chem. Soc., Dalton Trans. 1997, 3353. (d) Rothwell, I. P. Acc. Chem. Res. 1988, 21, 153. (e) Smith, G. M.; Carpenter, J. D.; Marks, T. J. J. Am. Chem. Soc. 1986, 108, 6805. (f) Wood, C. D.; McLain, S. J.; Schrock, R. R. J. Am. Chem. Soc. 1979, 101, 3210. (g) Cheon, J.; Rogers, D. M.; Girolami, G. S. J. Am. Chem. Soc. 1997, 119, 6804. (h) Reference 13. (i) Caulton, K. G.; Chisholm, M. H.; Streib, W. E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082. (j) Buchwald, S. L.; Nielson, R. B. J. Am. Chem., Soc. 1988, 110, 3171. (k) Coles, N.; Harris, M. C. J.; Whitby, R. J.; Blagg, J. Organometallics 1994, 13, 190.
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Coles, N.1
Harris, M.C.J.2
Whitby, R.J.3
Blagg, J.4
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68
-
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85034459994
-
-
note
-
2 = 0.926.
-
-
-
-
69
-
-
85034481099
-
-
note
-
3) was observed. The mechanism for the formation of a small amount of the disilane is not clear.
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-
-
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70
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0001075969
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(a) Fellmann, J. D.; Schrock, R. R.; Rupprecht, G. A. J. Am. Chem. Soc. 1981, 103, 5752.
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(b) Fellmann, J. D.; Rupprecht, G. A.; Wood, C. D.; Schrock, R. R. J. Am. Chem. Soc. 1978, 100, 5964.
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74
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3743130636
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J. P. Thesis, ULP Strasbourg
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(b) Le Ny, J. P. Thesis, ULP Strasbourg, 1984.
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(1984)
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Ny, L.1
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