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3743121583
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note
-
Gas pressures are given in atmospheres according to the following convention: ambient = 1 atm; 15 and 30 psi gauge readings = 2 and 3 atm.
-
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20
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0001737117
-
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(a) While this manuscript was in the final stages of preparation, an independent synthesis and crystal structure of 4 was reported, see: Fawcett, J.; Hope, E. G.; Kemmitt, R. D. W.; Paige, D. R.; Russell, D. R.; Stuart, A. M.; Cole-Hamilton, D. J.; Payne, M. J. J. Chem. Soc., Chem. Commun. 1997, 1127.
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85086293077
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note
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12a and April 14, 1997 (our communication to the Cambridge Structural Database).
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22
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85086291783
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note
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2 (M = Ir, Rh) in the Cambridge Structural Database.
-
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28
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33748271040
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For the graphical method used to obtain the melting point, see: Cammenga, H. K.; Epple, M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1171.
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For overviews of the many mechanisms by which alkyl halides can undergo oxidative addition, see: (a) Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987; pp 306-322.
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85086292895
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note
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31P NMR.
-
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32
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85086292103
-
-
note
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-1), opposite to the trend in Scheme 1. These cases (6, 11) might reflect a different product stereochemistry.
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33
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3743123881
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Unpublished results, University of Utah
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0000361033
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CP = 14.1, 13.1 Hz, C2, C3) 30.2, 30.1 (2 s, C4, C5), 32.7 (s. C6), 23.5 (s, C7), 14.8 (s C8). The last three assignments follow from well-established chemical shift patterns in n-alkanes and the first from those of n-alkylphospnines, see: Jolly, P. W.; Mynott, R. Adv. Organomet. Chem. 1981, 19, 257.
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3743089215
-
-
note
-
A correct microanalysis could not be obtained for this oil. The data are presented as one gauge of sample purity.
-
-
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-
61
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0001890535
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The Enraf-Nonius CAD 4 SDP - A Real-time System for Concurrent X-ray Data Collection and Crystal Structure Determination
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Schenk, H., Olthof-Hazelkamp, R., van Konigsveld, H., Bassi, G. C., Eds.; Delft University Press: Delft, Holland
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(a) Sheldrick, G. M. SHELXS-93; University of Göttingen: Göttingen, Germany 1993.
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0003872738
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Ibers, J. A., Hamilton, W. C., Eds.; Kynoch: Birmingham, England, Tables 2.2B and 2.3.1
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Cromer, D. T.; Waber, J. T. In International Tables for X-ray Crystallography; Ibers, J. A., Hamilton, W. C., Eds.; Kynoch: Birmingham, England, 1974; Vol. IV, Tables 2.2B and 2.3.1.
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Cromer, D.T.1
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3743120420
-
-
note
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All data associated with the structures have been deposited in the Cambridge Crystallographic Database.
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