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Volumn 102, Issue 23, 1998, Pages 4246-4255

Nonadiabatic electron transfer: Exact analytical expression of through-conjugated-bridge effective coupling and its asymptotics and zeros

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EID: 0000954796     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp9731359     Document Type: Article
Times cited : (16)

References (55)
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    • note
    • M(E) of monomer M in the forbidden energy zones of the oligomer constructed of such monomers, tells us that if a bridge possesses the property of complete switching, it is "inherited" from monomers and can be expected only in a band gap of the oligomer.
  • 40
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    • note
    • One of implications of zero effective coupling is that in such a case, the conductance of molecular wire in the quantum-point-contact arrangement will also be equal to zero. This is shown by calculations (to be published elsewhere) which rigorously take into account the oligomer-contact interaction within an approach similar to that used in refs 11, 14, 31.
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