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TEM photographs were taken by using a Hitachi-9000 NAR electron microscope. Specimens were prepared by placing a drop of the ethanol solution of the polymer-stabilized metal clusters upon a copper grid covered with a perforated carbon film and evaporating the solvent. The particle diameters were measured from the enlarged photographs. The particle size distribution histograms were obtained on the basis of the measurements of more than 300 particles
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-4 mol) was added and mixed. After the mixture was freeze-dried and reduced, the sodium dodecyl benzene-sulfonate-stabilized platinum nanocluster in the solid state was obtained (the average diameter was 2.16 nm with σ = 0.40 nm). This nanocluster is unstable when dispersed in water and will deposit after 2 weeks standing, but it can be stored without change for a much longer time in the solid state
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-4 mol) was added and mixed. After the mixture was freeze-dried and reduced, the sodium dodecyl benzene-sulfonate-stabilized platinum nanocluster in the solid state was obtained (the average diameter was 2.16 nm with σ = 0.40 nm). This nanocluster is unstable when dispersed in water and will deposit after 2 weeks standing, but it can be stored without change for a much longer time in the solid state.
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