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(a) E.K. Barefield, A.M. Carrier, D.J. Sepelak, D.G. Van Derveer, Organometallics 1 (1982) 103.
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See Ref. [2a] pp. 508-509.
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For Pt(IV) α-aminoalkyl derivatives, see
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For Pt(IV) α-aminoalkyl derivatives, see C.R. Baar, L.P. Carbray, M.C. Jennings, R.J. Puddephatt, J. Am. Chem. Soc. 122 (2000) 176.
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33744681837
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Pt-P coupling (4820 Hz) for P trans to S [3].
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Pt-P coupling (4820 Hz) for P trans to S [3].
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21
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0000264395
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Since reductive elimination from Pt(IV) usually proceeds from a five-coordinate intermediate, prior dissociation of e.g. chloride trans to a hydride ligand may be required. See for example
-
Since reductive elimination from Pt(IV) usually proceeds from a five-coordinate intermediate, prior dissociation of e.g. chloride trans to a hydride ligand may be required. See for example, U. Fekl, A. Zahl, R. van Eldik, Organometallics 18 (1999) 4156.
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