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Volumn 18, Issue 16, 1999, Pages 3245-3248

Transition metal silyl complexes. 60.†,1 enhanced reactivity of a platinum dimethyl complex toward trimethoxysilane due to a P,N-chelating Co ligand

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EID: 0000826339     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990123w     Document Type: Article
Times cited : (16)

References (40)
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    • note
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    • 3 are assumed to proceed by cis-oxidative addition followed by a cis-reduetive elimination step from an octahedral coordinated platinum(IV) species: (a) Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V. J. Chem. Soc. A 1971, 587. (b) Anderson, D. W. W.; Ebsworth, E. A. V.; MacDoughall, J. K.; Rankin, D. W. H. J. Inorg. Nucl. Chem. 1973, 2259. (c) Levy, C. J.; Puddephatt, R. J.; Vittal, J. J. Organometallics 1994, 13, 1559.
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    • 3 are assumed to proceed by cis-oxidative addition followed by a cis-reduetive elimination step from an octahedral coordinated platinum(IV) species: (a) Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V. J. Chem. Soc. A 1971, 587. (b) Anderson, D. W. W.; Ebsworth, E. A. V.; MacDoughall, J. K.; Rankin, D. W. H. J. Inorg. Nucl. Chem. 1973, 2259. (c) Levy, C. J.; Puddephatt, R. J.; Vittal, J. J. Organometallics 1994, 13, 1559.
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    • 3 are assumed to proceed by cis-oxidative addition followed by a cis-reduetive elimination step from an octahedral coordinated platinum(IV) species: (a) Bentham, J. E.; Cradock, S.; Ebsworth, E. A. V. J. Chem. Soc. A 1971, 587. (b) Anderson, D. W. W.; Ebsworth, E. A. V.; MacDoughall, J. K.; Rankin, D. W. H. J. Inorg. Nucl. Chem. 1973, 2259. (c) Levy, C. J.; Puddephatt, R. J.; Vittal, J. J. Organometallics 1994, 13, 1559.
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    • note
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    • and references cited therein
    • Molecular oxygen has recently been shown to be a possible source for oxygen incorporated into dimethyl platinum(II) complexes: Rostovtsev, V. V.; Labinger, J. A.; Bercaw, J. E.; Lasseter, T. L.; Goldberg, K. I. Organometallics 1998, 17, 4530 and references cited therein.
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    • note
    • 3 protons was based on a CH - COSY experiment.


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