Synthesis of planar chiral η3-allyldicarbonylnitrosyliron complexes and stereochemistry of the complex forming reaction

Journal of Organometallic Chemistry

Volumn 554, Issue 2, 1998, Pages 167-170

  Yamaguchi, Hiroshi ^a   Nakanishi, Saburo ^a   Takata, Toshikazu ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

CD spectroscopy; Nitrosyl ligand; Planar chirality; 3 Allyliron complexes

Indexed keywords

EID: 0000817238     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(97)00678-5     Document Type: Article

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39. 1H-NMR (270 MHz, CDCl3) δ 7.80 (d, J=1.8 Hz, 2H), 7.33 (d, J=7.9 Hz, 2H), 6.67 (dd, J=15.9, 5.5 Hz, 1H), 5.87 (d, J=15.9, 1.8 Hz, 1H), 5.25-5.10 (m, 1H), 4.75-4.65 (m, 1H), 2.44 (s, 3H), 1.41 (d, J=6.7 Hz, 3H), 2.10-1.00 (m, 9H), 0.91 (d, J=6.7 Hz, 3H), 0.89 (d, J=7.3 Hz, 3H), 0.74 (d, J=7.3 Hz, 3H).
40. 3) δ 216.21, 215.91, 172.39, 96.80, 75.13, 61.16, 55.22, 47.03, 40.65, 34.26, 31.61, 26.30, 23.47, 22.07, 20.80, 16.37.