Preparation and structural feature of (η3-allyl)dicarbonylnitrosyliron complexes with planar chirality

Tetrahedron Asymmetry

Volumn 7, Issue 8, 1996, Pages 2219-2222

  Nakanishi, Saburo ^a   Yamaguchi, Hiroshi ^a   Okamoto, Kenji ^a   Takata, Toshikazu ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX;

ARTICLE; CIRCULAR DICHROISM; DRUG STRUCTURE; DRUG SYNTHESIS; PRIORITY JOURNAL; X RAY ANALYSIS;

EID: 0030220919     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00276-5     Document Type: Article

References (13)

1. 1) Iron Compounds in Organic Synthesis, Pearson, A. J., Academic Press, London, p 46 (1994).
2. 2) Roustan, J. L. A.; Houlihan, F.; Can. J. Chem., 1979, 57, 2790.
3. 3) Roustan, J. L. A.; Merour, J. Y.; Houlihan, F.; Tetrahedron Lett., 1979, 39, 3721.
4. 4) Xu, Y.; Zhou, B.; J. Org. Chem.., 1987, 52, 974.
5. 5) Zhou, B.; Xu, Y.; J. Org. Chem., 1988, 53, 4419.
6. 6) Itoh, K.; Nakanishi, S.; Otsuji, Y.; Chem. Lett., 1987, 2103.
7. 7) Itoh, K.; Nakanishi, S.; Otsuji, Y.; Chem. Lett., 1988, 473.
8. 8) Itoh, K.; Nakanishi, S.; Otsuji, Y.; Chem, Lett., 1989, 615.
9. 9) Itoh, K.; Nakanishi, S.; Otsuji, Y.; Bull. Chem. Soc., Jpn, 1991, 64, 2965.
10. 10) Itoh, K.; Nakanishi, S.; Otsuji, Y.; J. Organomet. Chem., 1994, 473, 215.
11. 11) Itoh, K.; Otsuji, Y.; Nakanishi, S.; Tetrahedron Lett., 1995, 36, 2103.
12. 13C NMR (67 MHz, CDC13) δ 217.76, 216.47, 142.77, 128.68, 127.47, 126.43, 96.54, 76.75, 49.19, 21.44, 19.6.
13. 3. From a crystal dimensions 0.150 × 0.150 × 0.500 mm, 4366 independent reflections were measured over a 2θ range of 6-55.2° using Mo-Kα radiation (λ=0.71069 Å) at 23°C. The Fe atom was found from a three dimensional Patterson map, and the nonhydrogen atoms were located by subsequent difference Fourier syntheses. All hydrogen atoms were included at calculated positions. Full matrix least-squares refinement using 1643 reflections with I>3.00 σ (I) converged to final agreement factors R=0.045, Rw=0.045 with GOF=3.31.