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note
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nr is proportional to the excited state/ground-state vibrational overlap factors (i.e., the Franck-Condon factors) which decrease with temperature due to the decrease in Boltzmann population of excited vibronic levels and decreased electronphonon coupling to outer-sphere solvent modes. In the context of this "typical behavior" of low-to-medium molecular weight organic compounds, the temperature-dependent photophysics of 1 and 2 is unusual.
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33745566635
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The fluorescence quantum yields of 1 and 2 are 0.70 and 0.80, respectively. Walters, K. A.; Ley, K. D.; Cavalheiro, C.; Schanze, K. S. Submitted
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The fluorescence quantum yields of 1 and 2 are 0.70 and 0.80, respectively. Walters, K. A.; Ley, K. D.; Cavalheiro, C.; Schanze, K. S. Submitted.
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33
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0001752788
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