Crown-Ether-Functionalized Mn(III) Salicylaidimine Complexes as Ditopic Carriers. Efficient Transport of Tryptophan and Serotonin across a CHCl3 Barrier

Inorganic Chemistry

Volumn 37, Issue 20, 1998, Pages 5042-5043

  Rosa, Dell T ^a   Young, Victor G ^a   Coucouvanis, D ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000751368     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9808910     Document Type: Article

References (21)

1. (a) Jonasdottir, S. G.; Kim, C.-G.; Kampf, J.; Coucouvanis, D. Inorg. Chim. Acta 1996, 243, 255. and references therein,
2. (b) Malinak, S. M.; Coucouvanis, D. Inorg. Chem. 1996, 35, 4810. Malinak, S. M.; Rosa, D. T.; Coucouvanis, D. Inorg. Chem. 1998, 37, 1175-1190.
3. (b) Malinak, S. M.; Coucouvanis, D. Inorg. Chem. 1996, 35, 4810. Malinak, S. M.; Rosa, D. T.; Coucouvanis, D. Inorg. Chem. 1998, 37, 1175-1190.
4. (a) Gok, Y.; Degirmencioglu, I.; Karabocek, S. Synth. React. Inorg. Met-Org. Chem. 1997, 27, 331-345.
5. (b) Karabocek, S.; Karabocek, N. Polyhedron 1997, 16, 3771-1774.
6. Gul, A.; Okur, A. I.; Cihan, A.; Tan, N.; Bekaroglu, O. Synth. React. Inorg. Met-Org. Chem. 1986, 16, 871-884.
7. Van Staveren, C. J.; Van Eerden, J.; Van Veggel, F. C. J. M.; Harkema, S.; Reinhoudt, D. N. J. Am. Chem. Soc. 1988, 110, 4994.
8. Cooper, J. R.; Bloom, F. E.; Roth, R. H. The Biochemical Basis of Neuropharmacology; Oxford University Press: Oxford. 1996.
9. (a) Behr, J.-R: Lehn, J.-M. J. Am. Chem. Soc. 1973, 95, 6108.
10. (b) Newcomb, M.; Helgeson, R. C.; Cram, D. J. J. Am. Chem. Soc. 1979, 101, 7367.
11. Rebek, J., Jr.; Askew, B.; Nemeth, D.; Parris, K. J. Am. Chem. Soc. 1987, 109, 2432.
12. Reetz, M. T.; Huff, J.; Rudolph, J.; Tollner, K.; Deege, A.; Goddard, R. J. Am. Chem. Soc. 1994, 116, 11588-11589.
13. Paugam, M.-F.; Bien, J. T.; Smith, B. D.; Chrisstoffels, L. A. J.; de Jong, F.; Reinhoudt, D. N. J. Am. Chem. Soc. 1996, 118, 9820-9825.
14. Rudkevich, F. P.; Mercer-Chalmers, J. D.; Verboom, W.; Ungaro, R.; de Jong, F.; Reinhoudt, D. N. J. Am. Chem. Sac. 1995, 117, 6124-6125.
15. Schmidtchen, F. P. J. Org, Chem. 1986, 51, 5161.
16. Aoyama, Y.; Asakawa, M.; Yamagishi, A.; Toi, H.; Ogoshi, H. J. Am. Chem. Soc. 1990. 112, 3145-3151.
17. - derivatives of Bz-18-C-6, III. were virtually identical to the alkali metal ion "free" crown.
18. Satisfactory elemental analyses, mass spectroscopic data, infrared speciroscopic data, and electronic spectroscopic data are available as Supporting Information.
19. Crystal data for I: space group P̄. a = 10.9387(2) Å, b = 14.3794(2) Å, c = 18.4478(4) Å, α = 104.958(1)°, β = 104.245(1)°, γ = 99.140(1)°, Z = 2, R = 0.059.
20. -1).
21. The appropriate data and rate plots have been deposited as Supporting Information.