Synthesis and Characterization of [Mo2O5]2+-Bridged Complexes Containing Cofacially-Oriented, Catechol-Functionalized Macrocyclic and SALPHEN Ligands

Inorganic Chemistry

Volumn 35, Issue 17, 1996, Pages 4810-4811

  Malinak, Steven M ^a   Coucouvanis, Dimitri ^a  

^a UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000645761     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960407y     Document Type: Article

References (27)

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2. Rosa, D. T.; Reynolds, R. A.; Malinak, S. M.; Coucouvanis, D. To be reported separately.
3. Collman, J. P.; Wagenknecht. P. S.; Hutchison, J. E. Angew. Chem., Int. Ed. Engl. 1994, 33, 1537 and references therein.
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11. Please see the Supporting Information section for complete details on the characterization of this complex.
12. Filowitz, M.; Ho, R. K. C.: Klemperer, W. G.; Shum, W. Inorg. Chem. 1979, 18, 93.
13. max = 45°, 1 > 2σ(I)). The refinement of 826 parameters with all atoms present has converged to R1 = 9.7 and wR2 = 23.4, respectively.
14. max = 40°. 1 > 2σ(I)). The refinement of 558 parameters with all atoms present has converged to R1 = 9.95 and wR2 = 20.57, respectively.
15. Kim, K.; Collman, J. P.; Ibers, J. A. J. Am. Chem. Soc. 1988, 110, 4242.
16. Collman, J. P.; Chong, A. O.; Jameson, G. B.; Oakley, R. T.; Rose. E.; Schmittou, E. R.; Ibers. J. A. J. Am. Chem. Soc., 1981, 103, 516.
17. For ligands A and B of I. the atoms with the largest deviation from planarity are O(4) (0.308(8) Å) and O(8) (0.352(8) Å), respectively.
18. For ligands A and B of III, the atoms with the largest deviation from planarity are C(12) (0.39(2) Å) and O(8) (0.30(1) Å), respectively.
19. Blatchford, T. P.; Chisolm, M. H.; Huffman, J. C. Inorg. Chem. 1988, 27, 2059.
20. 4 added as supporting electrolyte) show multiple broad, poorly defined oxidation waves between 0.0 and 1.5 V which are inconclusive and will not be discussed here.
21. (a) Chachaty, C.; Forchioni, A.; Ronfard-Haret, J. C. Mol. Phys. 1976, 31, 325.
22. (b) Chachaty, C.; Rigny, P. J. Chim. Phys. 1982, 79, 203.
23. Lisowski, L.; Latos-Grażyński, L.; Szterenberg, L. Inorg. Chem. 1992, 31, 1933.
24. 3 presents the 3-H resonances at 2.58, 2.90, and 3.36 ppm (289 K). Wojaczyński, J.; Latos-Grażyński. L. Unpublished results.
25. Lindsey, J. S.; Schreiman. I C.; Hsu, H. C.; Kearney, P. C.; Marguerettaz, A. M. J. Org. Chem. 1987, 52, 827.
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