Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization of the Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n (M = Zr, Hf; n = 1, 2)

Inorganic Chemistry

Volumn 37, Issue 4, 1998, Pages 764-769

  Lugmair, Claus G ^a   Tilley, T Don ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000723442     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971211g     Document Type: Article

References (42)

1. (a) Brinker, C. J.; Scherer, G. W. Sol-Gel Science: Academic Press: Boston, MA, 1990.
2. (b) Sol-Gel Technology for Thin Films, Fibers. Preforms. Electronics, and Specialty Shapes: Klein, L. C., Ed., Noyes: Park Ridge. NJ. 1988.
3. (c) Corriu, R. J. P.; Leclercq, D. Angew. Chem., Int. Ed. Engl. 1996, 35, 1421.
4. (d) Guglielmi, M.; Carturan, G. J. Non-Cryst. Solids 1988, 100, 16.
5. (c) Brinker, C. J. J. Non-Cryst. Solids 1988. 100, 31.
6. (f) Schmidt, H. J. Non-Cryst. Solids 1988, 100, 51.
7. (g) Sanchez, C.; Livage, J.; Henry, M.; Babonneau, F. J. Non-Cryst. Solids 1988, 100, 65.
8. (a) Williams.,A. G.; Interrante, L. V. In Better Ceramics Through Chemistry Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings. Vol. 32; North-Holland: New York, 1984: p 152.
9. (b) Apblett, A. W.; Warren, A. C.; Barron, A. R. Chem. Mater. 1992, 4, 167.
10. (c) Chaput, F.; Lecomte, A.; Dauger, A., Boilot, J. P. Chem. Mater. 1989, 1, 199.
11. (d) Mehrotra, R. C. J. Non-Cryst. Solids 1990, 121, 1.
12. (e) Hubert-Pfalzgraf, L. G. New. J. Chem. 1987, 11, 663.
13. (f) Bradley, D. C. Polyhedron 1994, 13, 1111.
14. (g) Chandler, C. D.; Roger, C.; Hampden-Smith, M. J. Chem. Rev. 1993, 93, 1205
15. (a) Miller, J. B.; Tabone, E. R.; Ko, E. I. Langmuir 1996, 12, 2878
16. (b) Treadwell, D. R.; Dabbs, D. M.; Aksay, I. A. Chem. Mater. 1996. 8, 2056.
17. (c) Pouxviel, J. C.; Boilot, J. P. In Ultrastructure Processing of Advanced Ceramics: Mackenzie, J. D., Ulrich, D. R., Eds.; Wiley New York, 1988; p 197.
18. (d) Pouxviel, J. C.; Boilot, J. P.; Dauger, A. Huber, L. Mater. Res. Soc. Symp. Proc. 1986, 73, 269.
19. Assink, R. A.; Kay, B. D. J. Non-Cryst. Solids 1988, 99, 359.
20. (a) Livage, J., Henry, M.; Sanches, C. Prog. Solid State Chem. 1988, 18, 259.
21. (b) Livage, J.; Henry, M In Ultrasructure Processing of Advanced Ceramics: Mackenzie, J. D., Ulirich, D. R., Eds.; Wiley New York, 1988.
22. (a) Larbot, A.; Hours, T.; Bergez, P.; Charpin, J.; Cot. L. J. Non-Cryst. Solids 1992, 147-148, 85.
23. (b) Hartel, R. W.; Berglund, K. A. In Retter Ceramics Through Chemistry. II; Brinker, C. J., Clark, D. E., Ulrich, D. R., Eds.; Materials Research Society Symposia Proceedings. Vol. 73; Pittsburgh, PA, 1986; p 633.
24. (c) Barringer, H. A.; Bowen, H. K. Langmuir 1985, 1, 414.
25. (d) Davies, L.; Daza, L.; Grange, P. J. Mater. Sci. 1995, 30, 5087.
26. (a) Bradley, D. C. Coord. Chem. Rev. 1967, 2, 299
27. (b) Bradley, D. C.; Carter, D. G. Can. J. Chem. 1961, 39, 1434.
28. (c) Bradley, D. C.; Prevedorou-Demas, C. J. Chem. Soc. 1994, 1580.
29. (d) Bradley, D. C.; Carter, D. G. Can. J. Chem. 1962, 40, 15.
30. English, W. D., Sommer, L. H. J. Am. Chem. Soc. 1955, 77, 170.
31. (a) Morosin, B. Acta Crystallogr. 1977. B33, 303
32. (b) Day, V. W.; Eberspacher, T. A.; Klemperer, W. G.; Park, C. W.; Rosenberg, F. S. J. Am. Chem. Soc. 1991, 113, 8190.
33. (a) Terry, K. W.; Tilley, T. D. Chem. Mater. 1991, 3, 1001.
34. (b) Terry, K. W.; Lugmair, C. G., Tilley, T. D. J. Am. Chem. Soc. 1997, 119, 9745.
35. The proposed structures for 5 and 6 in eq 2 are based on a single-crystal X-ray diffraction analysis, which gave a highly disordered structure that appeared to contain approximately octahedral complexes with cis water ligands
36. Thewalt, U.; Lesser, W. J. Organomet. Chem. 1984, 276, 341
37. Fay, R. C. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; pp 384-387.
38. (a) Ward, D. A.; Ko, E. I. Chem. Mater. 1993, 5, 956.
39. (b) Miller, J. B.; Rankin, S. E.; Ko, E. I. J Catal. 1994, 148, 673.
40. (c) Okubo, T.; Nagamoto, H. J. Mater. Sci. 1995, 30, 749.
41. (d) Ray, J.; Chatterjee, M.; Ganguli, D. J. Mater. Sci. Lett. 1992, 11, 968.
42. (e) Toba, M.; Mizukami, F.; Niwa, S.; Sano, T.; Maeda, K.; Annila, A.; Komppa, V. J. Mol. Catal. 1994, 94, 85.