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Volumn 573, Issue 1-2, 1999, Pages 305-312

Towards an understanding of the conjugate addition of organolithium reagents to α,β-unsaturated ketones: The isolation and solid-state structure of a monomeric lithium aluminate with very short agostic LiHC interactions1

Author keywords

Aluminium; Conjugate addition; Lithium; Solid state structure; , Unsaturated ketone

Indexed keywords

STAPHYLOCOCCUS PHAGE 3A;

EID: 0000718828     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)00876-6     Document Type: Article
Times cited : (56)

References (26)
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    • For other dimeric lithium phenolates see: (a)
    • For other dimeric lithium phenolates see: (a) B. Cetinkaya, I. Gümrükcü, M.F. Lappert, J.L. Atwood, R. Shakir, J. Am. Chem. Soc. 102 (1980) 2086; (b) J.C. Huffman, R.L. Geerts, K.G. Caulton, J. Crystallogr. Spectrosc. Res. 14 (1984) 541; (c) G. Kociok-Köhn, J. Pickardt, H. Schumann, Acta Crysallogr., Sect. C 47 (1991) 2649; (d) L. Matilainen, M. Klinga, M. Leskelä, Polyhedron 14 (1995) 635.
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    • Cetinkaya, B.1    Gümrükcü, I.2    Lappert, M.F.3    Atwood, J.L.4    Shakir, R.5
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    • (b)
    • For other dimeric lithium phenolates see: (a) B. Cetinkaya, I. Gümrükcü, M.F. Lappert, J.L. Atwood, R. Shakir, J. Am. Chem. Soc. 102 (1980) 2086; (b) J.C. Huffman, R.L. Geerts, K.G. Caulton, J. Crystallogr. Spectrosc. Res. 14 (1984) 541; (c) G. Kociok-Köhn, J. Pickardt, H. Schumann, Acta Crysallogr., Sect. C 47 (1991) 2649; (d) L. Matilainen, M. Klinga, M. Leskelä, Polyhedron 14 (1995) 635.
    • (1984) J. Crystallogr. Spectrosc. Res. , vol.14 , pp. 541
    • Huffman, J.C.1    Geerts, R.L.2    Caulton, K.G.3
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    • (c)
    • For other dimeric lithium phenolates see: (a) B. Cetinkaya, I. Gümrükcü, M.F. Lappert, J.L. Atwood, R. Shakir, J. Am. Chem. Soc. 102 (1980) 2086; (b) J.C. Huffman, R.L. Geerts, K.G. Caulton, J. Crystallogr. Spectrosc. Res. 14 (1984) 541; (c) G. Kociok-Köhn, J. Pickardt, H. Schumann, Acta Crysallogr., Sect. C 47 (1991) 2649; (d) L. Matilainen, M. Klinga, M. Leskelä, Polyhedron 14 (1995) 635.
    • (1991) Acta Crysallogr., Sect. C , vol.47 , pp. 2649
    • Kociok-Köhn, G.1    Pickardt, J.2    Schumann, H.3
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    • (d)
    • For other dimeric lithium phenolates see: (a) B. Cetinkaya, I. Gümrükcü, M.F. Lappert, J.L. Atwood, R. Shakir, J. Am. Chem. Soc. 102 (1980) 2086; (b) J.C. Huffman, R.L. Geerts, K.G. Caulton, J. Crystallogr. Spectrosc. Res. 14 (1984) 541; (c) G. Kociok-Köhn, J. Pickardt, H. Schumann, Acta Crysallogr., Sect. C 47 (1991) 2649; (d) L. Matilainen, M. Klinga, M. Leskelä, Polyhedron 14 (1995) 635.
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    • Matilainen, L.1    Klinga, M.2    Leskelä, M.3
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    • 2Li rings see Ref. [5] and: (a)
    • 2Li rings see Ref. [5] and: (a) W.J. Evans, T.J. Boyle, J.W. Ziller, Polyhedron 11 (1992) 1093; (b) D.A. Atwood, D. Rutherford, Inorg. Chem. 34 (1995) 4008; (c) A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, J.D. Smith, Organometallics 15 (1996) 4343; (d)W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, M. Hopman, J.D. Smith, J. Chem. Soc., Dalton Trans., (1997) 4689.
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    • Evans, W.J.1    Boyle, T.J.2    Ziller, J.W.3
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    • (b)
    • 2Li rings see Ref. [5] and: (a) W.J. Evans, T.J. Boyle, J.W. Ziller, Polyhedron 11 (1992) 1093; (b) D.A. Atwood, D. Rutherford, Inorg. Chem. 34 (1995) 4008; (c) A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, J.D. Smith, Organometallics 15 (1996) 4343; (d)W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, M. Hopman, J.D. Smith, J. Chem. Soc., Dalton Trans., (1997) 4689.
    • (1995) Inorg. Chem. , vol.34 , pp. 4008
    • Atwood, D.A.1    Rutherford, D.2
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    • (c)
    • 2Li rings see Ref. [5] and: (a) W.J. Evans, T.J. Boyle, J.W. Ziller, Polyhedron 11 (1992) 1093; (b) D.A. Atwood, D. Rutherford, Inorg. Chem. 34 (1995) 4008; (c) A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, J.D. Smith, Organometallics 15 (1996) 4343; (d)W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, M. Hopman, J.D. Smith, J. Chem. Soc., Dalton Trans., (1997) 4689.
    • (1996) Organometallics , vol.15 , pp. 4343
    • Avent, A.G.1    Chen, W.-Y.2    Eaborn, C.3    Gorrell, I.B.4    Hitchcock, P.B.5    Smith, J.D.6
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    • (d)
    • 2Li rings see Ref. [5] and: (a) W.J. Evans, T.J. Boyle, J.W. Ziller, Polyhedron 11 (1992) 1093; (b) D.A. Atwood, D. Rutherford, Inorg. Chem. 34 (1995) 4008; (c) A.G. Avent, W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, J.D. Smith, Organometallics 15 (1996) 4343; (d)W.-Y. Chen, C. Eaborn, I.B. Gorrell, P.B. Hitchcock, M. Hopman, J.D. Smith, J. Chem. Soc., Dalton Trans., (1997) 4689.
    • (1997) J. Chem. Soc., Dalton Trans. , pp. 4689
    • Chen, W.-Y.1    Eaborn, C.2    Gorrell, I.B.3    Hitchcock, P.B.4    Hopman, M.5    Smith, J.D.6
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    • For recent examples of very short LiHC agostic bonds in di-coordinate lithium compounds see: (a)
    • For recent examples of very short LiH C agostic bonds in di-coordinate lithium compounds see: (a) I. Hemme, B. Tecklenburg, M. Noltmeyer, U. Klingebiel, Chem. Ber. 128 (1995) 351; (b) C.J. Harlan, S.G. Bott, A.R. Barron, J. Am. Chem. Soc. 117 (1995) 6465.
    • (1995) Chem. Ber. , vol.128 , pp. 351
    • Hemme, I.1    Tecklenburg, B.2    Noltmeyer, M.3    Klingebiel, U.4
  • 20
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    • (b)
    • For recent examples of very short LiH C agostic bonds in di-coordinate lithium compounds see: (a) I. Hemme, B. Tecklenburg, M. Noltmeyer, U. Klingebiel, Chem. Ber. 128 (1995) 351; (b) C.J. Harlan, S.G. Bott, A.R. Barron, J. Am. Chem. Soc. 117 (1995) 6465.
    • (1995) J. Am. Chem. Soc. , vol.117 , pp. 6465
    • Harlan, C.J.1    Bott, S.G.2    Barron, A.R.3
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    • (a) University of Göttingen 1993 and
    • (a) G.M. Sheldrick, SHELXS and SHELXL, University of Göttingen (1986, 1993 and 1997).
    • (1986) SHELXS and SHELXL
    • Sheldrick, G.M.1


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