Organotrialkoxy- and organotrifluoroaluminates: Crystal structures of Li[(Me3Si)3CAlX3]·OC4H 8 (X = tBuO, F)

Organometallics

Volumn 15, Issue 21, 1996, Pages 4343-4346

  Avent, Anthony G ^a   Chen, Wu Yong ^a   Eaborn, Colin ^a   Gorrell, Ian B ^a   Hitchcock, Peter B ^a   Smith, J David ^a  

^a UNIVERSITY OF SUSSEX   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001052683     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om960496m     Document Type: Article

References (29)

1. See, for example: Trost, B. M., Fleming, I., Eds. Comprehensive Organic Synthesis; Pergamon: Oxford, U.K., 1991; Vol. 8, Reduction. Barron, A. R.; Wilkinson, G. Polyhedron 1986, 5, 1897-1915. Bulychev, B. M. Polyhedron 1990, 9, 387-408 and references therein.
2. See, for example: Trost, B. M., Fleming, I., Eds. Comprehensive Organic Synthesis; Pergamon: Oxford, U.K., 1991; Vol. 8, Reduction. Barron, A. R.; Wilkinson, G. Polyhedron 1986, 5, 1897-1915. Bulychev, B. M. Polyhedron 1990, 9, 387-408 and references therein.
3. See, for example: Trost, B. M., Fleming, I., Eds. Comprehensive Organic Synthesis; Pergamon: Oxford, U.K., 1991; Vol. 8, Reduction. Barron, A. R.; Wilkinson, G. Polyhedron 1986, 5, 1897-1915. Bulychev, B. M. Polyhedron 1990, 9, 387-408 and references therein.
4. Eaborn, C.; Gorrell, I. B.; Hitchcock, P. B.; Smith, J. D.; Tavakkoli, K. Organometallics 1994, 13, 4143-4144.
5. Wehmschulte, R. J.; Ellison, J. J.; Ruhlandt-Senge, K.; Power, P. P. Inorg. Chem. 1994, 33, 6300-6306.
6. Wehmschulte, R. J.; Power, P. P. Inorg. Chem., 1994, 33, 5611-5612. Wehmschulte, R. J.; Power, P. P. Inorg. Chem. 1996, 35, 3262-3267.
7. Wehmschulte, R. J.; Power, P. P. Inorg. Chem., 1994, 33, 5611-5612. Wehmschulte, R. J.; Power, P. P. Inorg. Chem. 1996, 35, 3262-3267.
8. Power, M. B.; Bott, S. G.; Atwood, J. L.; Barron, A. R. J. Am. Chem. Soc. 1990, 112, 3446-3451.
9. 6): δ -2.32 ppm.
10. 3. Final R (I > 2σ-(I): R1 = 0.0677, wR2 = 0.1305. R (all data): R1 = 0.1296, wR2 = 0.1733. S = 1.025. There are two independent molecules with essentially the same geometry. The quoted structural parameters are for molecule 1.
11. Matilainen, L.; Klinga, M.; Leskelä, M. Polyhedron 1995, 14, 635-638.
12. (a) Kottke, T.; Stalke, D. Angew. Chem., Int. Ed. Engl. 1993, 32, 580-582.
13. (b) Marsch, M.; Harms, K.; Lochmann, L.; Boche, G. Angew. Chem., Int. Ed. Engl. 1990, 29, 308-309.
14. (c) Veith, M.; Böhnlein, J.; Huch, V. Chem. Ber. 1989, 122, 841-849.
15. Cayton, R. H.; Chisholm, M. H.; Davidson, E. R.; DiStasi, V. F.; Du, P.; Huffman, J. C. Inorg. Chem. 1991, 30, 1020-1024.
16. Evans, W. J.; Boyle, T. J.; Ziller, J. W. Polyhedron 1992, 11, 1093-1097.
17. Haaland, A. In Coordination Chemistry of Aluminum; Robinson, G. H., Ed.; VCH: New York, 1993; Chapter 1.
18. Brothers, P. J.; Power, P. P. Adv. Organomet. Chem. 1996, 39, 1-69 and references therein. Barron, A. R. Polyhedron 1995, 14, 3197-3207.
19. Brothers, P. J.; Power, P. P. Adv. Organomet. Chem. 1996, 39, 1-69 and references therein. Barron, A. R. Polyhedron 1995, 14, 3197-3207.
20. 6): δ -3.7 ppm.
21. 3C groups were disordered with minor sites of occupancy 0.13 and 0.20.
22. Daniel, Ph.; Bulou, A.; Rousseau, M.; Nouet, J.; Fourquet, J. L.; Leblanc, M.; Burriel, R. J. Phys: Condensed Matter 1990, 2, 5663-5677.
23. Gundersen, G.; Haugen, T.; Haaland, A. J. Organomet. Chem. 1973, 54, 77-86.
24. Herron, N.; Harlow, R. L.; Thorn, D. L. Inorg. Chem. 1993, 32, 2985-2986.
25. Klingebiel, U.; Meyer, M.; Pieper, U.; Stalke, D. J. Organomet. Chem. 1991, 408, 19-25.
26. Wei, L.; Barnes, C. L.; Sharp, P. R. J. Chem. Soc., Chem. Commun. 1990, 1634-1636.
27. Stalke, D.; Klingebiel, U.; Sheldrick, G. M. J. Organomet. Chem. 1988, 344, 37-48. Pieper, U.; Walter, S.; Klingebiel, U.; Stalke, D. Angew. Chem., Int. Ed. Engl. 1990, 29, 209-211. Walter, S.; Klingebiel, U.; Noltemeyer, M. Chem. Ber. 1992, 125, 783-788.
28. Stalke, D.; Klingebiel, U.; Sheldrick, G. M. J. Organomet. Chem. 1988, 344, 37-48. Pieper, U.; Walter, S.; Klingebiel, U.; Stalke, D. Angew. Chem., Int. Ed. Engl. 1990, 29, 209-211. Walter, S.; Klingebiel, U.; Noltemeyer, M. Chem. Ber. 1992, 125, 783-788.
29. Stalke, D.; Klingebiel, U.; Sheldrick, G. M. J. Organomet. Chem. 1988, 344, 37-48. Pieper, U.; Walter, S.; Klingebiel, U.; Stalke, D. Angew. Chem., Int. Ed. Engl. 1990, 29, 209-211. Walter, S.; Klingebiel, U.; Noltemeyer, M. Chem. Ber. 1992, 125, 783-788.