A Homoleptic Thioether Coordination Sphere That Supports Nickel(I)

Inorganic Chemistry

Volumn 35, Issue 19, 1996, Pages 5408-5409

  Ge, Pinghua ^a   Riordan, Charles G ^a   Yap, Glenn P A ^b   Rheingold, Arnold L ^b  

^a KANSAS STATE UNIVERSITY   (United States)

^b UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001407704     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960515k     Document Type: Article

References (33)

1. (a) Ragsdale, S. W. Crit. Rev. Biochem. Mol. Biol. 1991, 26, 261-300.
2. (b) Lancaster, J. R., Ed. The Bioinorganic Chemistry of Nickel; VCH Publishers: New York, 1988; Chapters 8-10.
3. Volbeda, A.; Charon, M.-H.; Piras, C.; Hatchikian, E. C.; Frey, M.; Fontecilla-Camps, J. C. Nature 1995, 373, 580-587. The authors describe the Ni coordination sphere as neither square planar nor tetrahedral.
4. (a) Cramer, S. P.; Pan, W.-H.; Eidness, M. K.; Morton, T.; Ragsdale, S. W.; Der Vartanian, D. V.; Ljungdahl, L. G.; Scott, R. A. Inorg. Chem. 1987, 26, 2477-2479.
5. (b) Bastian, N. R.; Diekert, G.; Niederhoffer, E. C.; Teo, B.-K.; Walsh, C. T.; Orme-Johnson, W. H. J. Am. Chem. Soc. 1988, 110, 5581-5582.
6. (c) Xia, J.; Dong, J.; Wang, S.; Scott, R. A.; Lindahl, P. A. J. Am. Chem. Soc. 1995, 117, 7065-7070.
7. For potentials vs NHE, see for example: (a) Coremans, J. M. C. C.; van der Zwaan, J. W.; Albracht, S. P. J. Biochim. Biophys. Acta 1989, 997, 256-267. (b) Gorst, C. M.; Ragsdale, S. W. J. Biol. Chem. 1991, 266, 20687-20693.
8. For potentials vs NHE, see for example: (a) Coremans, J. M. C. C.; van der Zwaan, J. W.; Albracht, S. P. J. Biochim. Biophys. Acta 1989, 997, 256-267. (b) Gorst, C. M.; Ragsdale, S. W. J. Biol. Chem. 1991, 266, 20687-20693.
9. 4 complex which is stable to electrochemical reduction, see: Yamamura, T.; Sakurai, S.; Arai, H.; Miyamae, H. J. Chem. Soc., Chem. Commun. 1993, 1656-1658.
10. 4: (a) Ram, M. S.; Riordan, C. G.; Ostrander, R.; Rheingold, A. L. Inorg. Chem. 1995, 34, 5884-5892. (b) Szalda, D. J.; Fujita, E.; Sanzenbacher, R.; Paulus, H.; Elias, H. Inorg. Chem. 1994, 33, 5855-5863. (c) Suh, M. P.; Kang, S.; Goedken, V. L.; Park, S. Inorg. Chem. 1991, 30, 360-365. (d) Lahiri, G. K.; Schussel, L. J.; Stolzenberg, A. M. Inorg. Chem. 1992, 31, 4991-5000.
11. 4: (a) Ram, M. S.; Riordan, C. G.; Ostrander, R.; Rheingold, A. L. Inorg. Chem. 1995, 34, 5884-5892. (b) Szalda, D. J.; Fujita, E.; Sanzenbacher, R.; Paulus, H.; Elias, H. Inorg. Chem. 1994, 33, 5855-5863. (c) Suh, M. P.; Kang, S.; Goedken, V. L.; Park, S. Inorg. Chem. 1991, 30, 360-365. (d) Lahiri, G. K.; Schussel, L. J.; Stolzenberg, A. M. Inorg. Chem. 1992, 31, 4991-5000.
12. 4: (a) Ram, M. S.; Riordan, C. G.; Ostrander, R.; Rheingold, A. L. Inorg. Chem. 1995, 34, 5884-5892. (b) Szalda, D. J.; Fujita, E.; Sanzenbacher, R.; Paulus, H.; Elias, H. Inorg. Chem. 1994, 33, 5855-5863. (c) Suh, M. P.; Kang, S.; Goedken, V. L.; Park, S. Inorg. Chem. 1991, 30, 360-365. (d) Lahiri, G. K.; Schussel, L. J.; Stolzenberg, A. M. Inorg. Chem. 1992, 31, 4991-5000.
13. 4: (a) Ram, M. S.; Riordan, C. G.; Ostrander, R.; Rheingold, A. L. Inorg. Chem. 1995, 34, 5884-5892. (b) Szalda, D. J.; Fujita, E.; Sanzenbacher, R.; Paulus, H.; Elias, H. Inorg. Chem. 1994, 33, 5855-5863. (c) Suh, M. P.; Kang, S.; Goedken, V. L.; Park, S. Inorg. Chem. 1991, 30, 360-365. (d) Lahiri, G. K.; Schussel, L. J.; Stolzenberg, A. M. Inorg. Chem. 1992, 31, 4991-5000.
14. 2: (e) Marganian, C. A.; Vazir, H.; Baidya, N.; Olmstead, M. M.; Mascharak, P. K. J. Am. Chem. Soc. 1995, 117, 1584-1594. (f) Baidya, N.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chem. 1991, 30, 929-937.
15. 2: (e) Marganian, C. A.; Vazir, H.; Baidya, N.; Olmstead, M. M.; Mascharak, P. K. J. Am. Chem. Soc. 1995, 117, 1584-1594. (f) Baidya, N.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chem. 1991, 30, 929-937.
16. 2: (g) Farmer, P. J.; Reibenspies, J. H.; Lindahl, P. A.; Darensbourg, M. Y. J. Am. Chem. Soc. 1993, 115, 4665-4674.
17. 3C: (h) Stavropoulos, P.; Muetterties, M. C.; Carrié, M.; Holm, R. H. J. Am. Chem. Soc. 1991, 113, 8485-8492.
18. 5: (i) Suh, M. P.; Oh, K. Y.; Lee, J. W.; Bae, Y. Y. J. Am. Chem. Soc. 1996, 118, 777-783.
19. (a) Ge, P.; Haggerty, B.; Rheingold, A. L.; Riordan, C. G. J. Am. Chem. Soc. 1994, 116, 8406-8407.
20. (b) Ohrenberg, C.; Ge, P.; Schebler, P.; Riordan, C. G.; Yap, G. P. A.; Rheingold, A. L. Inorg. Chem. 1996, 35, 749-754.
21. (c) Ohrenberg, C.; Saleem, M. M.; Riordan, C. G.; Yap, G. P. A.; Verma, A. K.; Rheingold, A. L. J. Chem. Soc., Chem. Commun. 1996, 1081-1082.
22. 4, 1,4,8,11-tetrathiacyclotetradecane; tmc. 1,4,8,11-tetramethyl1,4,8,11 -tetraazacyclotetradecane.
23. 4): C, 60.70; H, 6.37; S, 20.25. Found: C. 60.49; H, 6.17; S. 19.85.
24. 2) = 8.53%.
25. Halcrow, M. A.; Christou, G. Chem. Rev 1994, 94, 2421-2481.
26. Cotton, F. A.; Murillo, C. A. Inorg, Chim. Acta 1976, 17, 121-124.
27. 6-50 °C): 07.54,7.31,7.17,7.10,7.00,1.97, 1.84, 1.71, 1.59.
28. -1 ≈ 41.0).
29. Rosen, W.; Busch, D. H. J. Am. Chem. Soc. 1969, 91, 4694-4697.
30. 1 was stirred in THF over Na/Hg for 30 min. The solution was transferred to an EPR tube, and the spectrum was recorded at 77 K. An identical spectrum was obtained in DME.
31. (a) Huang, J.; Ostrander, R. L.; Rheingold, A. L.; Leung, Y.; Walters. M. A. J. Am. Chem. Soc. 1994, 116, 6769-6776.
32. (b) Krüger, H.-J.: Peng, G.; Holm, R. H. Inorg. Chem. 1991, 30, 734-742.
33. Mills, D. K.; Hsiao, Y. M.; Farmer, P. J.; Atnip, E. V.; Reibenspies, J. H.; Darensbourg, M. Y. J. Am. Chem. Soc. 1991, 113, 1421-1423.