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85034472963
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note
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2Si: C, 61.63; H, 10.34. Found: C, 61.82; H, 10.44.
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18
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0040535406
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Silacycloalkanes used in this work except for disilacyclopentanes are commercially available. Disilacyclopentanes were prepared by the Na/K-promoted cyclization of 1,3-bis(chlorosilyl)propanes: Kumada, M.; Tamao, K.; Takubo, T.; Ishikawa, M. J. Organomet. Chem. 1967, 9, 43.
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85034480360
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note
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In the absence of 1c, hexyltrimethylsilane reacted with tert-butyl diazoacetate under catalytic conditions to give the corresponding β C-H bond insertion product in 36% yield.
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24
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85034483054
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note
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Under the same reaction conditions, less strained silacycloalkanes such as 1b and 1c did not react with benzoyl chloride.
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