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85037268243
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note
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In such a gas-liquid system, it is important to ensure that the rates measured are not mass-transfer controlled. A series of experiments was performed at various agitation speeds, and above 1000 rpm no increase in conversion was detected. Hence, all measurements hereafter pertain to 1000 rpm stirring.
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32
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85037261195
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note
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As could be expected, heterogeneous Pd/C which is a known catalyst for Ar-Ar coupling under reducing conditions, did not catalyze the reaction under these oxidative conditions.
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33
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39
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85037270008
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We also investigated the use of NaBr, LiCl, and paraldehyde as promoters, but no increase in yield was observed.
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