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Volumn 62, Issue 19, 1997, Pages 6547-6561

Palladium-Catalyzed Isomerization of Aryl-Substituted Epoxides: A Selective Synthesis of Substituted Benzylic Aldehydes and Ketones

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EID: 0000578843     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo970743b     Document Type: Article
Times cited : (97)

References (94)
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    • 22b benzene = 2.27; t-BuOH = 12.47
    • 22b benzene = 2.27; t-BuOH = 12.47.
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    • note
    • -1.
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    • (a) For a report on the direct oxidative addition of the C-H bond of a terminal alkyne to Pd(0), see: Chukhadzhyan, G. A.; Evoyan, Z. K.; Melkonyan, L. N. Zh. Obshch. Khim. 1975, 45, 1114-1117; Chem. Abstr. 83, 97535c.
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    • Chem. Abstr. , vol.83
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    • ( b) For a recent report on Pd-catalyzed reactions of terminal alkynes that proceed via C-H activation, see: Trost, B. M.; Matsubara, S.; Caringi, J. J. Am. Chem. Soc. 1989, 111, 8745-8746.
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    • For specific examples, see: (a) Benfield, F. W. S.; Green, M. L. H. J. Chem. Soc., Dation Trans. 1974, 1324-1331. (b) Eilbracht, P.; Mayser, U. Chem. Ber. 1980, 113, 2211-2220. (c) Crabtree, R. H.; Dion, R. P. J. Chem. Soc., Chem. Commun. 1984, 1260-1261.
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