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85036164018
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The presence of a tricritical point in such a model is traceable to its special symmetry. In general, tricritical behavior cannot occur in a binary fluid mixture except by accident
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The presence of a tricritical point in such a model is traceable to its special symmetry. In general, tricritical behavior cannot occur in a binary fluid mixture except by accident.
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19
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85036437311
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Strictly speaking there is four-phase coexistence since in zero field the demixed liquid comprises an [Formula Presented]-rich and a [Formula Presented]-rich phase in coexistence. For the case of nonconserved concentration considered here, the demixed liquid generally comprises either a homogeneous [Formula Presented]-rich phase or a [Formula Presented]-rich phase. Owing to symmetry, both these phases have the same density and we shall thus regard them as one single liquid phase. Note, however, that the two-phase nature of the demixed liquid is important in the context of the tricritical behavior
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Strictly speaking there is four-phase coexistence since in zero field the demixed liquid comprises an A-rich and a B-rich phase in coexistence. For the case of nonconserved concentration considered here, the demixed liquid generally comprises either a homogeneous A-rich phase or a B-rich phase. Owing to symmetry, both these phases have the same density and we shall thus regard them as one single liquid phase. Note, however, that the two-phase nature of the demixed liquid is important in the context of the tricritical behavior.
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22
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E. Lomba, J.-J. Weis, N. G. Almarza, F. Bresme, and G. Stell, Phys. Rev. E 49, 5169 (1994).PLEEE8
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The method is actually a variant of the “umbrella sampling” technique, G. M. Torrie and J. P. Valleau, J. Comput. Phys. 23, 187 (1977).JCTPAH
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tackle this problem. However, the precision of this method seems to be less than is obtainable from combined use of multicanonical and histogram reweighting techniques (see, e.g., c24). It is also not well suited for studying a transition from two-phase to three-phase coexistence as occurs on approaching a triple point. MOPHAM
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In principle, one could also apply the Gibbs ensemble simulation method [A. Z. Panagiotopoulos, Mol. Phys. 61, 813 (1987)] to tackle this problem. However, the precision of this method seems to be less than is obtainable from combined use of multicanonical and histogram reweighting techniques (see, e.g., 24). It is also not well suited for studying a transition from two-phase to three-phase coexistence as occurs on approaching a triple point.MOPHAM
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85036183574
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the full space of [Formula Presented], the tricritical end point terminates a line of tricritical points; see also c6
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In the full space of (T,μ,h), the tricritical end point terminates a line of tricritical points; see also 6.
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P. H. Poole, T. Grande, F. Sciortino, H. E. Stanley, and C. A. Angell, Comput. Mater. Sci 4, 373 (1995)
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