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18
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0042120374
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note
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The slight preference for syn product is attributed to the intermediacy of an endocyclic radical wherein the 3-OH is linked to the carbonyl via a hydrogen bond.
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19
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0042621516
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note
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2 to permit formation of traces of cyclic boronate even without deliberate exposure of the reaction mixture to air.
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21
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0041619546
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note
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1H NMR.
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22
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0346267223
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The formation of the oxazaborolidine was monitored by NMR spectroscopy
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