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Volumn 7, Issue 8, 1996, Pages 2417-2422

Synthesis and some reactions of the first chiral tin hydride containing a C2-symmetric binaphthyl substituent

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Indexed keywords

ORGANOTIN COMPOUND;

EID: 0030221456     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00300-X     Document Type: Article
Times cited : (95)

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    • Alkylation of 7 was surprisingly difficult to achieve. The reaction with a Grignard reagent afforded a very complicated mixture of unidentified products. A redistribution reaction with tetramethyltin gave mixtures of 7 and 8 ; attempts to drive the reaction to completion led to decomposition of both compounds. Likewise, among the reducing agents surveyed, only alane provided a clean product
    • 12) Alkylation of 7 was surprisingly difficult to achieve. The reaction with a Grignard reagent afforded a very complicated mixture of unidentified products. A redistribution reaction with tetramethyltin gave mixtures of 7 and 8 ; attempts to drive the reaction to completion led to decomposition of both compounds. Likewise, among the reducing agents surveyed, only alane provided a clean product.
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    • Under air the very stable radical generated from 9 can be scavenged by dioxygen molecules before hydrogen abstraction occurs; in addition, by-products containing an ethyl group were found, whose formation is probably the result of the high amounts of triethylborane used during the reaction
    • 15) Under air the very stable radical generated from 9 can be scavenged by dioxygen molecules before hydrogen abstraction occurs; in addition, by-products containing an ethyl group were found, whose formation is probably the result of the high amounts of triethylborane used during the reaction.
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    • 119Sn-NMR spectra), the melting temperature ranges from 220 °C to 270 °C, probably because of fast decomposition of the hydride: as the fusion begins, the sample turns in a red-brown oil that slowly decomposes and becomes clear at 270 °C
    • 119Sn-NMR spectra), the melting temperature ranges from 220 °C to 270 °C, probably because of fast decomposition of the hydride: as the fusion begins, the sample turns in a red-brown oil that slowly decomposes and becomes clear at 270 °C.


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