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85034461505
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85050441345
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3GeBr. See: Harris, D. M.; Nebergall, W. H.; Johnson, O. H. Inorg. Synth. 1957, 5, 70-72 and 76-78. We used a modification of this procedure as described in the Supporting Information.
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85034482625
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note
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A catalytic amount of acid is not required, but it was essential to liberate the O-benzylhydroxylamine from the commercially available hydrochloride salt.
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33
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0001444010
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Ionic vs radical behavior of selenides and sulfides: Kropp, P. J.; Fryxell, G. E.; Tubergen, M. W.; Hager, M. W.; Harris, G. D., Jr.; McDermott, T. P., Jr.; Tornero-Velez, R. J. Am. Chem. Soc. 1991, 113, 7300-7310.
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Helmchen, G., Hoffmann, R. W., Mulzer, J., Schaumann, E., Eds.; Thieme: New York
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(a) Russell, G. A.; Ngoviwatchai, P.; Tashtoush, H. I. Organometallics 1988, 7, 696-702.
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85034479866
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3GeH presumably also occurred in previously reported kinetic experiments (see ref 1)
-
3GeH presumably also occurred in previously reported kinetic experiments (see ref 1).
-
-
-
-
44
-
-
85034463775
-
-
note
-
(b) Reaction of triphenylgermanium bromide and AIBN with triphenyltin hydride provides triphenylgermanium hydride and triphenyltin bromide.
-
-
-
-
45
-
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85034478940
-
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note
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2=NOBn (HOMO -9.6920 eV, LUMO 0.2470 eV).
-
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46
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0001527994
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-1 at 80 °C. (a) Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1981, 103, 7739. (b) Walling, C.; Cioffari, A. J. Am. Chem. Soc. 1972, 94, 6059-64. (c) Carlsson, D. J.; Ingold, K. U. J. Am. Chem. Soc. 1968, 90, 7047-55.
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-1 at 80 °C. (a) Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1981, 103, 7739. (b) Walling, C.; Cioffari, A. J. Am. Chem. Soc. 1972, 94, 6059-64. (c) Carlsson, D. J.; Ingold, K. U. J. Am. Chem. Soc. 1968, 90, 7047-55.
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-1 at 80 °C. (a) Chatgilialoglu, C.; Ingold, K. U.; Scaiano, J. C. J. Am. Chem. Soc. 1981, 103, 7739. (b) Walling, C.; Cioffari, A. J. Am. Chem. Soc. 1972, 94, 6059-64. (c) Carlsson, D. J.; Ingold, K. U. J. Am. Chem. Soc. 1968, 90, 7047-55.
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