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Alkyl and dialkyl boranes can react with late-transition-metal compounds via nonoxidative pathways: (a) Baker, R. T.; Ovenall, E. W.; Harlow, R. L.; Westcott, S. A.; Taylor, N. J.; Marder, T. B. Organometallics 1990, 9, 3028. (b) Baker, R. T.; Calabrese, J. C.; Westcott, S. A.; Marder, T. B. J. Am. Chem. Soc. 1995, 117, 8777. (c) Westcott, S. A.; Blom, H. P.; Marder, T. B.; Baker, R. T.; Calabrese, J. C. Inorg. Chem. 1993, 32, 2175. (d) Hartwig, J. F.; Bhandari, S.; Rablen, P. R. J. Am. Chem. Soc. 1994, 116, 1839.
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note
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In this paper, "alkyl/hydride" exchange refers to an alkyl transfer from the metal to boron with concomitant transfer of hydride from boron to the metal. The term "hydride/alkyl" exchange, on the other hand, refers to the reverse process, i.e., alkyl from boron to metal and hydride from metal to boron.
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1H NMR: 5.70 ppm, 10H; 5.30 ppm, 2H).
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Addition of a small amount of THF to benzene solutions of 4 results in formation of an adduct in which the phenyl resonances for the benzylidene moiety return to a "normal" pattern. Although we have not fully characterized 4·THF, it is apparent that the THF donor is able to displace the multihapto benzylidene ligand.
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41
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85085633075
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13C NMR spectrum was broad; measurement of the C1-H coupling constant was accomplished using the HMQC pulse sequence with gated decoupling.
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8 may also have been present, but no attempt was made to detect and quantify this isotopomer.
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