Synthesis of nonbridged (anilide)(cyclopentadienyl)titanium(IV) complexes of the type Cp′TiCl2[N(2,6-Me2C6H3)(R)] and their use in catalysis for olefin polymerization

Organometallics

Volumn 21, Issue 14, 2002, Pages 3042-3049

  Nomura, Kotohiro ^a   Fujii, Kensaku ^a  

^a NARA INSTITUTE OF SCIENCE AND TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

POLYDISPERSITY;

CATALYSIS; COMPLEXATION; CRYSTALLIZATION; MOLECULAR WEIGHT; OLEFINS; POLYMERIZATION; SYNTHESIS (CHEMICAL); TOLUENE;

ORGANOMETALLICS;

EID: 0000486625     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020179h     Document Type: Article

References (48)

1. For example (review): (a) Brintzinger, H. H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
2. (b) Kaminsky, W. Macromol. Chem. Phys. 1996, 197, 3903.
3. (c) Kaminsky, W.; Arndt, M. Adv. Polym. Sci. 1997, 127, 143.
4. (d) Suhm, J.; Heinemann, J.; Wörner, C.; Müller, P.; Stricker, F.; Kressler, J.; Okuda, J.; Mülhaupt, R. Macromol. Symp. 1998, 129, 1.
5. (e) McKnight, A. L.; Waymouth, R. M. Chem. Rev. 1998, 98, 2587.
6. (f) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew. Chem., Int. Ed. 1999, 38, 429.
7. Ewart, S. W.; Baird, M. C. Top. Catal. 1999, 7, 1.
8. Baird, M. C. Chem. Rev. 2000, 100, 1471.
9. Nomura, K.; Naga, N.; Miki, M.; Yanagi, K.; Imai, A. Organometallics 1998, 17, 2152.
10. Nomura, K.; Naga, N.; Miki, M.; Yanagi, K. Macromolecules 1998, 31, 7588.
11. Nomura, K.; Komatsu, T.; Imanishi, Y. J. Mol. Catal. A 2000, 152, 249.
12. Nomura, K.; Komatsu, T.; Imanishi, Y. J. Mol. Catal. A 2000, 159, 127.
13. Nomura, K.; Oya, K.; Komatsu, T.; Imanishi, Y. Macromolecules 2000, 33, 3187.
14. Nomura, K.; Oya, K.; Imanishi, Y. J. Mol. Catal. A 2001, 174, 127.
15. 2AlCl (classical Ziegler type) catalyst system: Skupinski, W.; Wasilewski, A. J. Organomet. Chem. 1983, 282, 69.
16. Antiñolo, A.; Carrillo-Hermosilla, F.; Corrochano, A.; Fernández-Baeza, J.; Lara-Sanchez, A.; Ribeiro, M,; Lanfranchi, M.; Otero, A.; Pellinghelli, M, A.; Portela, M. F.; Santos, J. V. Organometallics 2000, 19, 2837.
17. Shah, S. A. A.; Dorn, H.; Voigt, A.; Roesky, H. W.; Parisini, E.; Schmidt, H.-G.; Noltemeyer, M. Organometallics 1996, 15, 3176.
18. Doherty, S.; Errington, R. J.; Jarvis, A. P.; Collins, S.; Clegg, W.; Elsegood, M. R. J. Organometallics 1998, 17, 3408.
19. Stephan, D. W.; Stewart, J. C.; Guérin, F.; Spence, R. E. v. H.; Xu, W.; Harrison, D. G. Organometallics 1999, 18, 1116.
20. Richter, J.; Edelmann, F. T.; Noltemeyer, M.; Schmidt, H.-G.; Schmulinson, M.; Eisen, M. S. J. Mol. Catal. A 1998, 130, 149.
21. Vollmerhaus, R.; Shao, P.; Taylor, N. J.; Collins, S. Organometallics 1999, 18, 2731.
22. Jayaratne, K. C.; Sita, L. R. J. Am. Chem. Soc. 2000, 122, 958.
23. Sita, L. R.; Babcock, R. Organometallics 1998, 17, 5228.
24. Jayaratne, K. C.; Keaton, R. J.; Henningsen, D. A.; Sita, L. R. J. Am. Chem. Soc. 2000, 122, 10490.
25. Keaton, R. J.; Jayaratne, K. C.; Henningsen, D. A.; Koterwas, L. A.; Sita, L. R. J. Am. Chem. Soc. 2001, 123, 6197.
26. Canich, J. A. M.; Hlatky, G. G.; Turner, H. W. U.S. Patent 542,236, 1990.
27. Canich, J. A. M. U.S. Patent 5, 026, 798, 1991.
28. Canich, J. A. M. Eur. Pat. Appl. 420, 436, 1991.
29. Stevens, J. C.; Timmers, F. J.; Wilson, D. R.; Schmidt, G. F.; Nickias, P. N.; Rosen, R. K; Knight, G. W.; Lai, S.-Y. Eur. Pat. Appl., 416815 1991.
30. Stevens, J. C.; Neithamer, D. R. Eur. Pat. Appl., 418, 022 1991.
31. Okuda, J.; Schattenmann, F. J.; Wocadlo, S.; Massa, W. Organometallics 1995, 14, 789.
32. Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K; Marks, T. J.; Deck, P. A.; Stern, C. L. Organometallics 1995, 14, 3132.
33. du Plooy, K. L.; Moll, U.; Wocadlo, S.; Massa, W.; Okuda, J. Organometallics 1995, 14, 3129.
34. Carpenetti, D. W.; Kloppenburg, L.; Kupec, J. T.; Petersen, J. L. Organometallics 1996, 15, 1572.
35. McKnight, A. L.; Masood, M. A.; Waymouth, R. M. Organometallics 1997, 16, 2879.
36. Nomura, K.; Komatsu, T.; Imanishi, Y. Macromolecules 2000, 33, 8122.
37. Vroegop, C. T.; Teuben, J. H.; van Bolhuis, F.; van der Linden, J. G. M. J. Chem. Soc., Chem. Commun, 1983, 550.
38. 2[MMe(Cy)]-MAO catalyst exhibited remarkable catalytic activity for ethylene polymerization: Nomura, K. Unpublished results.
39. Martín, A.; Mena, M.; Yélamos, C.; Serano, R. J. Organomet. Chem. 1994, 467, 79.
40. Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17.
41. Sinnema, P.-J.; Spaniol, T. P.; Okuda, J. J. Organomet. Chem. 2000, 598, 179.
42. Bai, Y.; Noltemeyer, M.; Roesky, H. W. Z. Anorg. Allg. Chem. 1991, 21, 595.
43. Pauling, L. The Nature of the Chemical Bond, 3rd ed.; Cornell University Press: Ithaca, NY, 1960.
44. Nomura, K.; Naga, N.; Takaoki, K. Macromolecules 1998, 31, 8009.
45. K.N. expresses his thanks to Mr. G. Uematsu (Tosoh Co.) for helpful comments concerning the analysis of polyethylene prepared by 8a.
46. 3), see the Supporting Information.
47. DIRDIF94: Beurskens, P. T.; Admiraal, G.; Beurskens, G.; Bosman, W. P.; de Delder, R.; Israel, R.; Smits, J. M. M. The DIRDIF94 Program System, Technical Report of the Crystallography Laboratory; University of Nijmegen, Njjmegen, The Netherlands, 1994.
48. teXsan: Crystal Structure Analysis Package; Molecular Structure Corp., The Woodlands, TX, 1985 and 1999.