Mediated energy transfer in covalently linked porphyrin dimers

Journal of Physical Chemistry A

Volumn 101, Issue 12, 1997, Pages 2218-2220

  Jensen, Kristine Kilså ^a   Van Berlekom, Sofia B ^a   Kajanus, Johan ^a   Mårtensson, Jerker ^a   Albinsson, Bo ^a  

^a CHALMERS UNIVERSITY OF TECHNOLOGY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000475590     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970246z     Document Type: Article

References (42)

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36. The MM+ force field as implemented in the program package HyperChem, Hypercube Inc.
37. AM1 model Hamiltonian as implemented in the program package MOPAC 6.0. The angular deviation at room temperature was estimated from the Boltzmann distribution by varying the dihedral angle between the porphyrin and phenyl planes, optimizing the structure, and calculating the potential energy at these fixed dihedral angles.
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39. The fluorescence lifetimes were measured with the phase and modulation technique using a SPEX Fluorolog τ2 spectrofluorimeter. Fifteen modulation frequencies were selected on a logarithmic scale in the range 10-300 MHz. The samples were excited at 530 nm, and the emission was collected through a 540 nm cutoff filter. A diluted silica sol scattering solution was used as reference.
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