Alkali metal derivatives of tris(trimethylsilyl)silane - Syntheses and molecular structures

Organosilicon Chemistry II: From Molecules to Materials

Volumn , Issue , 1996, Pages 493-498

  Klinkhammer, Karl Wilhelm ^a   Becker, Gerd ^a   Schwan, Wolfgang ^a  

^a UNIVERSITY OF STUTTGART   (Germany)

Author keywords

Alkali metal; C H bonds; Lithium; Potassium; X ray crystal structure

Indexed keywords

ALKALI METALS; LITHIUM; MOLECULAR STRUCTURE; POTASSIUM; TOLUENE; X RAYS;

C-H BOND; METAL DERIVATIVES; SOLVENT FREE; TRIS(TRIMETHYLSILYL)SILANE; X RAY CRYSTAL STRUCTURES; X-RAY CRYSTAL STRUCTURE ANALYSIS;

CRYSTAL STRUCTURE;

EID: 84955743196     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1002/9783527619894.ch56     Document Type: Chapter

References (6)

1. K. W. Klinkhammer, W. Schwarz, Z. Anorg. Allg. Chem. 1993, 619, 1777.
2. S. Henkel, K. W. Klinkhammer, W. Schwarz, Angew. Chem. 1994, 106, 721; Angew. Chem., Int. Ed. Engl. 1994, 33, 681.
3. Angew. Chem., Int. Ed. Engl. 1994, 33, 681.
4. K. W. Klinkhammer, W. Schwarz, J. Chem. Soc., Chem. Commun., in press.
5. 1/n, a = 15.327(4), b = 15.395(4), c = 20.649(6) A, β = 94.41(1) °. 7517 independent reflections (6.5 < 20< 48 °), R1 = 0.041.
6. C. Schade, P. v. R. Schleyer, Adv. Organomet. Chem. 1987, 27, 169.