Preparation of Luminescent Silicon Nanoparticles: A Novel Sonochemical Approach

Chemistry of Materials

Volumn 10, Issue 11, 1998, Pages 3278-3281

  Dhas, N Arul ^a   Raj, C Paul ^a   Gedanken, A ^a  

^a BAR ILAN UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000459659     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm980408j     Document Type: Article

References (28)

1. Canham, L. T. Appl. Phys. Lett. 1990, 57, 1046. Brus, L. E. J. Phys. Chem. 1994, 98, 3575.
2. Canham, L. T. Appl. Phys. Lett. 1990, 57, 1046. Brus, L. E. J. Phys. Chem. 1994, 98, 3575.
3. O'Neil, M.; Marohn, J.; McLendon, G. J. Phys. Chem. 1990, 94, 4356. Hasselbarth, A.; Eychmuller, A.; Weller, H. Chem. Phys. Lett. 1993, 203, 271. Takagi, H.; Ogawa, H.; Yamazaki, Y.; Ishizaki, A.; Nakagiri, T.; T. Appl. Phys. Lett. 1990, 56, 2379.
4. O'Neil, M.; Marohn, J.; McLendon, G. J. Phys. Chem. 1990, 94, 4356. Hasselbarth, A.; Eychmuller, A.; Weller, H. Chem. Phys. Lett. 1993, 203, 271. Takagi, H.; Ogawa, H.; Yamazaki, Y.; Ishizaki, A.; Nakagiri, T.; T. Appl. Phys. Lett. 1990, 56, 2379.
5. O'Neil, M.; Marohn, J.; McLendon, G. J. Phys. Chem. 1990, 94, 4356. Hasselbarth, A.; Eychmuller, A.; Weller, H. Chem. Phys. Lett. 1993, 203, 271. Takagi, H.; Ogawa, H.; Yamazaki, Y.; Ishizaki, A.; Nakagiri, T.; T. Appl. Phys. Lett. 1990, 56, 2379.
6. Norris, D. J.; Bawendi, M. G. Phys. Rev. 1996, B53, 16338. Woggon, U.; Gindele, F.; Wind, O.; Klingshirm, C. Phys. Rev. 1996, B54, 1506.
7. Norris, D. J.; Bawendi, M. G. Phys. Rev. 1996, B53, 16338. Woggon, U.; Gindele, F.; Wind, O.; Klingshirm, C. Phys. Rev. 1996, B54, 1506.
8. Littau, K. A.; Szajowshki, P. J.; Muller, A. J.; Kortan, A. R.; Brus, L. E. J. Phys. Chem. 1993, 97, 1224. Fojtik, A.; Henglein, A. Chem. Phys. Lett. 1994, 221, 363.
9. Littau, K. A.; Szajowshki, P. J.; Muller, A. J.; Kortan, A. R.; Brus, L. E. J. Phys. Chem. 1993, 97, 1224. Fojtik, A.; Henglein, A. Chem. Phys. Lett. 1994, 221, 363.
10. Heinrich, J. L.; Curtis, C. L.; Credo, G. M.; Kavavagh, K. L.; Sailor, M. J. Science 1992, 255, 66. Noguchi, H.; Kondo, T.; Uosaki, K. J. Phys. Chem. B 1997, 101, 4978. Kim, N. Y.; Laibinis, P. E. J. Am. Chem. Soc. 1997, 119, 2297.
11. Heinrich, J. L.; Curtis, C. L.; Credo, G. M.; Kavavagh, K. L.; Sailor, M. J. Science 1992, 255, 66. Noguchi, H.; Kondo, T.; Uosaki, K. J. Phys. Chem. B 1997, 101, 4978. Kim, N. Y.; Laibinis, P. E. J. Am. Chem. Soc. 1997, 119, 2297.
12. Heinrich, J. L.; Curtis, C. L.; Credo, G. M.; Kavavagh, K. L.; Sailor, M. J. Science 1992, 255, 66. Noguchi, H.; Kondo, T.; Uosaki, K. J. Phys. Chem. B 1997, 101, 4978. Kim, N. Y.; Laibinis, P. E. J. Am. Chem. Soc. 1997, 119, 2297.
13. Bley, R. A.; Kauzlarich, S. M. J. Am. Chem. Soc. 1996, 118, 12461.
14. Heath, J. R. Science 1992, 258, 1131.
15. Suslick, K. S. Ultrasound: Its Chemical, Physical and Biological Effects VCH: Weinheim, 1988.
16. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
17. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
18. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
19. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
20. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
21. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
22. Suslick, K. S.; Choe, S. B.; Cichowlas, A. A.; Grinstaff, M. W. Nature 1991, 353, 414. Hyeon, T.; Fang, M.; Suslick, K S. J. Am. Chem. Soc. 1996, 118, 5492. Arul Dhas, N.; Cohen, H.; Gedanken, A. J. Phys. Chem. 1997, B101, 6834. Arul Dhas, N.; Gedanken, A. J. Phys. Chem. 1997, B101, 9495. Okitsu, K.; Bandow, H.; Maeda, Y.; Nagata, Y. Chem. Mater. 1996, 8, 315. Grieser, F. Stud. Surf. Sci. Catal. 1997, 103, 57. Gutierrez, M.; Henglein, A.; Dohrmann, J. J. Phys. Chem. 1987, 91, 1, 6687.
23. Arul Dhas, N.; Gedanken, A. Silicon Nanoclusters and a Method For Producing Same. US Patent, P-1340-USP (pending).
24. The X-ray diffraction patterns were recorded by employing a Rigaku X-ray diffractometer (Model-2028, Cu Kα). IR spectra were recorded using a Nicolet (impact 410) FT-IR spectrometer, using transparent pellets of the compounds in KBr matrixes. The transmission electron micrographs were obtained by employing a JEOL-JEM 100SX electron microscope. The photoluminescence spectrum was obtained using an Perkin-Elmer luminescence spectrophotometer (model LS50B). The excitation wavelength was 260 nm. The UV-visible absorbance spectrum of the silicon was obtained using a Varian (model-DMS 100S) UV-visible spectrophotometer. ESR spectra were recorded on a Bruker ER 083 CS spectrometer, operating at X-band frequency (v = 9.7 GHz), with a 100 kHz magnetic field modulation.
25. Because of the rapid thermal quenching and interparticle collisions associated with the acoustic cavitation, a large amount of surface defect concentration is likely to be present in the sonochemical product. See Suslick, K. S. Sci. Am. 1989, 111, 2342.
26. Song, J. H.; Sailor, M. J. J. Am. Chem. Soc. 1997, 119, 7381.
27. Kelly, M. T.; Bocarsly, A. B. Chem. Mater. 1997, 9, 1659.
28. Sako, S.; Kimura, K. Surf. Sci. 1985, 156, 511.