Solubility of individual polychlorinated biphenyl (PCB) congeners in supercritical fluids: CO2, CO2/MeOH and CO2/n-C4H10

Journal of Supercritical Fluids

Volumn 14, Issue 3, 1999, Pages 197-211

  Anitescu, G ^a,b   Tavlarides, L L ^a  

^a Syracuse University   (United States)

^b UNIVERSITY OF BUCHAREST   (Romania)

Author keywords

Capillary GC analysis; CO2; Equilibrium solubility; Methanol; n Butane; PCB congeners; Supercritical fluid

Indexed keywords

EID: 0000436197     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(98)00109-0     Document Type: Article

References (50)

1. C.A. Eckert, B.L. Knutson, P.G. Debenedetti, Supercritical fluids as solvents for chemical and material processing, Nature 383 (1996) 313.
2. M.A. McHugh, V.J. Krukonis, Supercritical Fluid Extraction-Principles and Practice, 2nd ed., Butterworths-Heinemann, Boston, MA, 1994.
3. A. Akgerman, R.K. Roop, R.K. Hess, S.D. Yeo, Supercritical extraction in environmental control, in: T.J. Bruno, J.F. Ely (Eds.), Supercritical Fluid Technology: Review in Modern Theory and Applications, chap. 14, CRC Press, Bocca Raton, FL, 1991.
4. M.E.P. McNally, Advances in environmental supercritical fluid extraction, Anal. Chem. 67 (1995) 308A.
5. B.W. Wright, J.L. Fulton, A.J. Kopriva, R.D. Smith, Analytical supercritical fluid extraction methodologies, in: B.A. Charpantier, M.R. Sevenants (Eds.), Supercritical Fluid Extraction and Chromatography: Techniques and Applications, chap. 3, American Chemical Society, Washington, DC, 1988.
6. B.W. Wright, C.W. Wright, J.S. Fruchter, Supercritical fluid extraction of coal tar contaminated soil samples, Energy Fuels 3 (1989) 474.
7. A.T. Andrews, Supercritical carbon dioxide extraction of polycyclic aromatic hydrocarbons from contaminated soil, Ph.D. Dissertation, Rutgers, The State University of New Jersey, New Brunswick, 1990.
8. S.B. Hawthorne, Analytical-scale supercritical fluid extraction, Anal. Chem. 62 (1990) 633A.
9. K.M. Dooley, C.P. Kao, R.P. Gambrell, F.C. Knopf, The use of en trainers in the supercritical extraction of soils contaminated with hazardous organics, Ind. Engng Chem. Res. 26 (10) (1987) 2058.
10. S.B. Hawthorne, D.J. Miller, M.D. Burford, J.J. Langenfeld, S. Eckert-Tilotta, P. K Louie, Factors controlling quantitative supercritical fluid extraction of environmental samples, J. Chromatogr. 642 (1993) 301.
11. M.D. Burford, S.B. Hawthorne, D.J. Miller, Extraction rates of spiked versus native PAHs from heterogenous environmental samples using supercritical fluid extraction and sonication in methylene chloride, Anal. Chem. 65 (1993) 1497.
12. K Wuchner, R.T. Ghijsen, U.A.Th. Brinkman, R. Grob, J. Mathieu, Extraction of organophosphorus pesticides from soil by off-line supercritical fluid extraction, Analyst 118 (1993) 11.
13. 2-cosolvent extraction of contaminated soils and sediments, Environ. Prog. 9 (4) (1990) 197.
14. H. Creutznacher, New extraction technique for the organic environmental analysis. Part 2: Use of supercritical fluid extraction in the laboratory to extract PCBs from soil samples, GIT Labor-Fachz 41 (3) (1997) 277.
15. P. Chen, W. Zhou, L.L. Tavlarides, Remediation of PCB contaminated soils and sediments by supercritical fluid extraction, Environ. Prog. 16 (3) (1997) 227.
16. B. Enders, G. Schwedt, Supercritical fluid extraction, microwave assisted extraction, and Soxhlet extraction of PCBs in soil and sewage sludge, J. Prakt. Chem./Chem. Ztg 339 (3) (1997) 250.
17. 2 for the extraction of PCBs and PAHs, Anal. Chem. 4 (1992) 1614.
18. B.O. Brady, C.P. Kao, K.M. Dooley, F.C. Knopf, R.P. Gambrell, Supercritical extraction of toxic organics from soils, Ind. Engng Chem. Res. 26 (1987) 261.
19. J.J. Langenfeld, S.B. Hawthorne, D.J. Miller, J. Pawliszyn, Effects of temperature and pressure on supercritical fluid extraction efficiencies of polycyclic aromatic hydrocarbons andpolychlorinatedbiphenyls, Anal. Chem. 65 (1993) 338.
20. S. Bøwadt, B. Johanson, Analysis of PCBs in sulfurcontaining sediments by off-line SFE and HRGC-ECD, Anal. Chem. 66 (1994) 667.
21. G. Markows, High pressure extraction of PCBs from soils and other fine-grained solids, Ber. Forschungszent. Juelich (1996) 1.
22. L.L. Tavlarides, P. Chen, W. Zhou, W.S. Amato, Supercritical extraction of polychlorinated biphenyls from soils and sediments: remediation and possible risks, in: Proceedings of U.S. EPA 21st Annual RREL Res. Symposium, Cincinnati, OH, April, 1995.
23. S. Taniguchi, A. Murakami, M. Hosomi, A. Miyamura, R. Uchida, Chemical decontamination of PCB contaminated soil, Chemosphere 34 (5)6)7) (1997) 1631.
24. R.V. Galiulin, R.R. Galiulina, Monitoring and reclamation of chemically polluted soils and sites. Part 2: PCBs, Agrokhimia 1 (1997) 81.
25. G.Y. Rhee, R.C. Sokol, C.M. Bethoney, B. Bush, Dechlorination of PCBs by Hudson River sediment organisms: specificity to the chlorination pattern of congeners, Environ. Sci. Technol. 27 (1993) 1190.
26. C.M. Carnana, New processes tackle PCBs, Chem. Engng Prog. 93 (2) (1997) 11.
27. K.D. Bartle, A.A. Clifford, S.A. Jafar, G.F. Shilstone, Solubilities of solids and liquids with low volatility in supercritical carbon dioxide, J. Phys. Chem. Ref. Data 20 (4) (1991) 713.
28. K.P. Johnston, D.H. Ziger, C.A. Eckert, Solubilities of hydrocarbon solids in supercritical fluids. The augmanted van der Waals treatment, Ind. Engng Chem. Fundamentals 21 (1982) 191.
29. K.D. Bartle, A.A. Clifford, S.A. Jafar, Measurement of solubility in supercritical fluids using chromatographic retention: the solubility of fluorene, phenanthrene, pyrene in carbon dioxide, J. Chem. Engng Data 35 (1990) 355.
30. E. Yu, M. Richter, P. Chen, X. Wang, Z. Zhang, L.L. Tavlarides, Solubilities of PCBs in supercritical carbon dioxide, Ind. Engng Chem. Res. 34 (1) (1995) 340.
31. D.J. Miller, S.B. Hawthorne, Solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide from 313 K to 523 K and pressures from 100 bar to 450 bar, J. Chem. Engng Data 41 (1996) 779.
32. G. Anitescu, L.L. Tavlarides, Solubilities of solids in supercritical fluids: I. New quasistatic experimental method for polycyclic aromatic hydrocarbons (PAHs) + pure fluids, J. Supercrit. Fluids 10 (1997) 175-189.
33. 2/cosolvent, J. Supercrit. Fluids 11 (1997) 37-51.
34. M.C. Jones, Mass transfer in supercritical extraction from solid matrices, in: T.J. Bruno, J.F. Ely (Eds.), Supercritical Fluid Technology: Review in Modern Theory and Applications, chap. 10, CRC Press, Bocca Raton, FL, 1991.
35. J.L. Snyder, R.L. Grob, M.E. McNally, T.S. Oostdyk, Comparison of supercritical fluid extraction with classical sonication and Soxhlet extraction for selected pesticides, Anal. Chem. 65 (1992) 1940.
36. J.M. Dobbs, J.M. Wang, K.P. Johnston, Nonpolar cosolvents for solubility enhancement in supercritical carbon dioxide, J. Chem. Engng Data 31 (1986) 303.
37. J.M. Dobbs, J.M. Wang, R.J. Lahiere, K.P. Johnston, Modification of a supercritical phase behavior using polar cosolvents, Ind. Engng Chem. Res. 26 (1987) 56.
38. J. Tehrani, Successful supercritical fluid extraction strategies, Am. Laboratory, 1993, 40HH.
39. R.H. Olds, H.H. Reamer, B.H. Sage, W.N. Lacey, Phase equilibria in hydrocarbon systems. Volumetric behavior of n-butane, Ind. Engng Chem. 36 (1944) 282.
40. J.C. Rainwater, H. Ingham, J.J. Lynch, Vapor-liquid equilibrium of carbon dioxide with i-butane and n-butane, J. Res. NIST 95 (1990) 701.
41. M.P. Ekart, K.L. Bennett, S.M. Ekart, G.S. Gurdial, C.L. Liotta, C.A. Eckert, Cosolvent interactions in supercritical fluid solutions, AIChE J. 39 (2) (1993) 235.
42. A. Tavana, J. Chang, A.D. Randolph, Scanning of cosolvents for supercritical fluids solubilization of organics, AIChE J. 35 (1989) 645.
43. J.M. Dobbs, K.P. Johnston, Selectivity in pure and mixed supercritical solvents, Ind. Engng Chem. Res. 26 (1987) 1476.
44. W.E. Hollar, P. Ehrlich, Solubility of naphthalene in mixtures of carbon dioxide and ethane, J. Chem. Engng Data 35 (1990) 271.
45. 8) up to 333 K and 17.7 MPa, Fluid Phase Equil. 57 (1990) 205.
46. M.D. Erickson, Analytical Chemistry of PCBs, Lewis, Chelsea, MI. 1992.
47. M. McHugh, M.E. Paulaitis, Solid solubilities of naphthalene and biphenyl in supercritical carbon dioxide, J. Chem. Engng Data 25 (1980) 326.
48. V.A. McFarland, J.U. Clarke, Environmental occurrence, abundance and potential toxicity of poly chlorinated biphenyl congeners: considerations for a congener-specific analysis, Environ. Health Perspect. 81 (1989) 225.
49. K.P. Johnston, D.G. Peck, S. Kim, Modeling supercritical mixtures: how predictive is it?, Ind. Engng Chem. Res. 28 (1989) 1115.
50. S.K Kumar, K.P. Johnston, Modeling the solubility of solids in supercritical fluids with density as the independent variable, J. Supercrit. Fluids 1 (1988) 15.