Solubilities of solids in supercritical fluids - I. New quasistatic experimental method for polycyclic aromatic hydrocarbons (PAHs)+pure fluids

Journal of Supercritical Fluids

Volumn 10, Issue 3, 1997, Pages 175-189

  Anitescu, G ^a   Tavlarides, L L ^a  

^a SYRACUSE UNIVERSITY   (United States)

Author keywords

C2H6; Capillary GC analysis; CO2; Equilibrium solubility; PAH; Quasistatic method; Supercritical fluid

Indexed keywords

EID: 0000894939     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0896-8446(97)00024-7     Document Type: Article

References (16)

1. P. Sandra, A. Kot, F. David, Supercritical fluids in separation science. Trends and concerns, in 16th International Symposium on Capillary Chromatography, Vol. 2. Riva del Garda, Italy, 1994, p. 1515.
2. S.B. Hawthorne, D.J. Miller, Extraction and recovery of polycyclic aromatic hydrocarbons from environmental solids using supercritical fluids. Anal. Chem. 59 (1987) 1705.
3. B.W. Wright, C.W. Wright, J.S. Fruchter, Supercritical fluid extraction of coal tar contaminated soil samples. Energy Fuels 3 (1989) 474.
4. J.J. Langenfeld, S.B. Hawthorne, D.J. Miller, J. Pawliszyn, Effects of temperature and pressure on supercritical fluid extraction efficiencies of polycyclic aromatic hydrocarbons and polychlorinated biphenyls, Anal. Chem. 65 (1993) 338.
5. K.D. Bartle, A.A. Clifford, S.A. Jafar, G.F. Shilstone, Solubilities of solids and liquids of low volatility in supercritical carbon dioxide, J. Phys. Chem. Ref. Data 20 (4) (1991) 713.
6. K.P. Johnston, D.H. Ziger, C.A. Eckert, Solubilities of hydrocarbon solids in supercritical fluids. The augmented van der Waals treatment, Ind. Engng Chem. Fundam. 21 (1982) 191.
7. K.D. Bartle, A.A. Clifford, S.A. Jafar, Measurement of solubility in supercritical fluids using chromatographic retention: the solubility of fluorene, phenanthrene, pyrene in carbon dioxide, J. Chem. Engng Data 35 (1990) 355.
8. A.T. Andrews, Supercritical carbon dioxide extraction of polycyclic aromatic hydrocarbons from contaminated soil, Ph.D. Dissertation, Rutgers, The State University of New Jersey, NewBrunswick, 1990.
9. E. Yu, M. Richter, P. Chen, X. Wang, Z. Zhang, L.L. Tavlarides, Solubilities of polychlorinated biphenyls in supercritical carbon dioxide, Ind. Engng Chem. Res. 34 (1) (1995) 340.
10. D.J. Miller, S.B. Hawthorne, Solubility of polycyclic aromatic hydrocarbons in supercritical carbon dioxide from 313K to 523K and pressures from 100 bar to 450 bar, J. Chem. Engng Data 41 (1996) 779.
11. G.-T. Liu, K. Nagahama, Solubility of organic solid mixture in supercritical fluids, J. Supercritic. Fluids 9 (1996) 152.
12. M.A. McHugh, V.J. Krukonis, Supercritical Fluid Extraction - Principles and Practice, 2nd ed, Butterworths-Heinemann, Boston, MA, 1994.
13. J.F. Brennecke, C.A. Eckert, Phase equilibria for supercritical fluid process design, AIChE J. 35 (9) (1989) 1409.
14. Y.J. Kwon, G.A. Mansoori, Solubility modeling of solids in supercritical fluids using the Kirkwood-Buff fluctuation integral with the hard-sphere expansion (HSE) theory, J. Supercritic. Fluids 6 (1993) 173.
15. S.K. Kumar, K.P. Johnston, Modeling the solubility of solids in supercritical fluids with density as the independent variable. J. Supercritic. Fluids 1 (1988) 15.
16. C. Lütge, I. Reiß, A. Schleußinger, S.J. Schultz, Modeling the extraction of perylene from spiked soil material by dense carbon dioxide, J. Supercrit. Fluids 7 (4) (1994) 265.