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Volumn 16, Issue 18, 1997, Pages 3927-3933

Coupling reactions of terminal acetylenes with ruthenium complexes containing the ortho-metalated ligand 2,6-(PPh2CH2)2C6H3

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EID: 0000425573     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9700829     Document Type: Article
Times cited : (31)

References (104)
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    • See for example: (a) Muir, J. E.; Haynes, A.; Winter, M. J. J. Chem. Soc., Chem. Commun. 1996, 1765 and references therein. (b) Bergamini, P.; Costa, E.; Orpen, A, G.; Pringle, P. G.; Smith, M. B. Organometallics 1995, 14, 3178 and references therein. (c) Bergamini, P.; Costa, E.; Cramer, P.; Hogg, J.; Orpen, A. G.; Pringle, P. G. Organometallics 1994, 13, 1058. (d) Adams, H.; Bailey, N. A.; Bentley, G. W.; Tattershall, C. E.; Taylor, B. F.; Winter, M. J. J. Chem. Soc., Chem. Commun. 1992, 533. (e) Trace, R. L.; Sanchez, J.; Yang, J.; Yin, J.; Jones, W. M, Organometallics 1992, 11, 1440. (f) Hoover, J. F.; Stryker, J. M. J. Am. Chem. Soc. 1990, 112, 464.
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    • See for example: (a) Muir, J. E.; Haynes, A.; Winter, M. J. J. Chem. Soc., Chem. Commun. 1996, 1765 and references therein. (b) Bergamini, P.; Costa, E.; Orpen, A, G.; Pringle, P. G.; Smith, M. B. Organometallics 1995, 14, 3178 and references therein. (c) Bergamini, P.; Costa, E.; Cramer, P.; Hogg, J.; Orpen, A. G.; Pringle, P. G. Organometallics 1994, 13, 1058. (d) Adams, H.; Bailey, N. A.; Bentley, G. W.; Tattershall, C. E.; Taylor, B. F.; Winter, M. J. J. Chem. Soc., Chem. Commun. 1992, 533. (e) Trace, R. L.; Sanchez, J.; Yang, J.; Yin, J.; Jones, W. M, Organometallics 1992, 11, 1440. (f) Hoover, J. F.; Stryker, J. M. J. Am. Chem. Soc. 1990, 112, 464.
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    • Additional examples of acetylide-vinylidene coupling: (a) Santos, A.; López, J.; Matas, L.; Ros, J.; Galán, A.; Echavarren, A. M. Organometallics 1993, 12, 4215. (b) Hills, H.; Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A,; Rowley, A. T.; Bravo, M.; McKenna, C. E.; McKenna, M. C. J. Chem. Soc., Chem. Commun. 1991, 522. (c) Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A.; Rowley, A. T. J. Chem. Soc. Dalton Trans. 1993, 3151. (d), Jia, G.; Rheingold, A. L.; Meek, D. W. Organometaliics 1989, 8, 1378. (e) Jia, G.; Meek, D. W. Organometallics 1991, 10, 1444. (f) Gotzig, J.; Werner, H. J. Organomet. Chem. 1985, 287, 247.
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    • Additional examples of acetylide-vinylidene coupling: (a) Santos, A.; López, J.; Matas, L.; Ros, J.; Galán, A.; Echavarren, A. M. Organometallics 1993, 12, 4215. (b) Hills, H.; Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A,; Rowley, A. T.; Bravo, M.; McKenna, C. E.; McKenna, M. C. J. Chem. Soc., Chem. Commun. 1991, 522. (c) Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A.; Rowley, A. T. J. Chem. Soc. Dalton Trans. 1993, 3151. (d), Jia, G.; Rheingold, A. L.; Meek, D. W. Organometaliics 1989, 8, 1378. (e) Jia, G.; Meek, D. W. Organometallics 1991, 10, 1444. (f) Gotzig, J.; Werner, H. J. Organomet. Chem. 1985, 287, 247.
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    • Additional examples of acetylide-vinylidene coupling: (a) Santos, A.; López, J.; Matas, L.; Ros, J.; Galán, A.; Echavarren, A. M. Organometallics 1993, 12, 4215. (b) Hills, H.; Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A,; Rowley, A. T.; Bravo, M.; McKenna, C. E.; McKenna, M. C. J. Chem. Soc., Chem. Commun. 1991, 522. (c) Hughes, D. L.; Jimenez-Tenorio, M.; Leigh, G. J.; McGeary, C. A.; Rowley, A. T. J. Chem. Soc. Dalton Trans. 1993, 3151. (d), Jia, G.; Rheingold, A. L.; Meek, D. W. Organometaliics 1989, 8, 1378. (e) Jia, G.; Meek, D. W. Organometallics 1991, 10, 1444. (f) Gotzig, J.; Werner, H. J. Organomet. Chem. 1985, 287, 247.
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    • Allenylidene intermediates formed may undergo further reactions, see for example: (a) Selegue, J. P. J. Am. Chem. Soc. 1983,105, 5921. (b) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Lastra, E.; Borge, J.; Garcîa-Granda, S, Organometallics 1994, 13, 745. (c) Matsuzaka, H.; Koizumi, H.; Takagi, Y.; Nishio, M.; Hidai, M. J. Am. Chem. Soc. 1993, 115, 10396. (d) O'Connor, J. M.; Hiibner, K. J. Chem. Soc., Chem. Commun. 1995, 1209. (e) Pilette, D.; Ouzzine, K.; Le Bozec, H.; Dixneuf, P. H.; Rickard, C. E. F.; Roper, W. R. Organometallics 1992, 11, 809 and references therein.
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    • Cadierno, V.1    Gamasa, M.P.2    Gimeno, J.3    Lastra, E.4    Borge, J.5    Garcîa-Granda, S.6
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    • Allenylidene intermediates formed may undergo further reactions, see for example: (a) Selegue, J. P. J. Am. Chem. Soc. 1983,105, 5921. (b) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Lastra, E.; Borge, J.; Garcîa-Granda, S, Organometallics 1994, 13, 745. (c) Matsuzaka, H.; Koizumi, H.; Takagi, Y.; Nishio, M.; Hidai, M. J. Am. Chem. Soc. 1993, 115, 10396. (d) O'Connor, J. M.; Hiibner, K. J. Chem. Soc., Chem. Commun. 1995, 1209. (e) Pilette, D.; Ouzzine, K.; Le Bozec, H.; Dixneuf, P. H.; Rickard, C. E. F.; Roper, W. R. Organometallics 1992, 11, 809 and references therein.
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    • Allenylidene intermediates formed may undergo further reactions, see for example: (a) Selegue, J. P. J. Am. Chem. Soc. 1983,105, 5921. (b) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Lastra, E.; Borge, J.; Garcîa-Granda, S, Organometallics 1994, 13, 745. (c) Matsuzaka, H.; Koizumi, H.; Takagi, Y.; Nishio, M.; Hidai, M. J. Am. Chem. Soc. 1993, 115, 10396. (d) O'Connor, J. M.; Hiibner, K. J. Chem. Soc., Chem. Commun. 1995, 1209. (e) Pilette, D.; Ouzzine, K.; Le Bozec, H.; Dixneuf, P. H.; Rickard, C. E. F.; Roper, W. R. Organometallics 1992, 11, 809 and references therein.
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    • and references therein
    • Allenylidene intermediates formed may undergo further reactions, see for example: (a) Selegue, J. P. J. Am. Chem. Soc. 1983,105, 5921. (b) Cadierno, V.; Gamasa, M. P.; Gimeno, J.; Lastra, E.; Borge, J.; Garcîa-Granda, S, Organometallics 1994, 13, 745. (c) Matsuzaka, H.; Koizumi, H.; Takagi, Y.; Nishio, M.; Hidai, M. J. Am. Chem. Soc. 1993, 115, 10396. (d) O'Connor, J. M.; Hiibner, K. J. Chem. Soc., Chem. Commun. 1995, 1209. (e) Pilette, D.; Ouzzine, K.; Le Bozec, H.; Dixneuf, P. H.; Rickard, C. E. F.; Roper, W. R. Organometallics 1992, 11, 809 and references therein.
    • (1992) Organometallics , vol.11 , pp. 809
    • Pilette, D.1    Ouzzine, K.2    Le Bozec, H.3    Dixneuf, P.H.4    Rickard, C.E.F.5    Roper, W.R.6
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    • A number of metal complexes with PCP and related ligands have been reported; for example: (a) Rimml, H.; Venanzi, L. M. J. Organomet. Chem. 1983, 259, C6. (b) Rimml, H.; Venanzi, L. M. J. Organomet. Chem. 1984, 260, C52. (c) Gorla, F.; Venanzi, L. M.; Albinati, A. Organometallics 1994, 13, 43. (d) Gola, F.; Togni, A.; Venanzi, L. M.; Albinati, A.; Lianza, F. Organometallics 1994, 13, 1607. (e) Moulton, C. J.; Shaw, B. L. J. Chem. Soc., Dalton Trans. 1976, 1020. (f) Cross, R. J.; Kennedy, A. R.; Manojlovîc-Muir, L.; Muir, K. W. J. Organomet. Chem. 1995, 493, 243. (g) Kaska, W. C.; Nemeh, S.; Shirazi, A.; Potuznik, S. Organometallics 1988, 7, 13. (h) Nemeh, S.; Jensen, C.; Binamira-Soriaga, E.; Kaska, W. C. Organometallics 1983, 2, 1442.
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    • A number of metal complexes with PCP and related ligands have been reported; for example: (a) Rimml, H.; Venanzi, L. M. J. Organomet. Chem. 1983, 259, C6. (b) Rimml, H.; Venanzi, L. M. J. Organomet. Chem. 1984, 260, C52. (c) Gorla, F.; Venanzi, L. M.; Albinati, A. Organometallics 1994, 13, 43. (d) Gola, F.; Togni, A.; Venanzi, L. M.; Albinati, A.; Lianza, F. Organometallics 1994, 13, 1607. (e) Moulton, C. J.; Shaw, B. L. J. Chem. Soc., Dalton Trans. 1976, 1020. (f) Cross, R. J.; Kennedy, A. R.; Manojlovîc-Muir, L.; Muir, K. W. J. Organomet. Chem. 1995, 493, 243. (g) Kaska, W. C.; Nemeh, S.; Shirazi, A.; Potuznik, S. Organometallics 1988, 7, 13. (h) Nemeh, S.; Jensen, C.; Binamira-Soriaga, E.; Kaska, W. C. Organometallics 1983, 2, 1442.
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