A mild and efficient Nef reaction for the conversion of nitro to carbonyl group by dimethyldioxirane (DMD) oxidation of nitronate anions

Synlett

Volumn , Issue 12, 1998, Pages 1335-1336

  Adam, Waldemar ^a   Makosza, Mieczyslaw ^b   Saha Möller, Chantu R ^a   Zhao, Cong Gui ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b INSTITUTE OF ORGANIC CHEMISTRY   (Poland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000422460     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-1947     Document Type: Article

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35. 4 was removed by filtration and washed with acetone (3×10 mL). The crude product, obtained after evaporation (20 °C, 30 mbar) of the solvent, was purified by silica gel chromatography with 30-50% ether in petroleum ether (b.p. 30-50 °C) as eluent (1:1 EtOAc/n-hexane was used for 3d).