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With consideration of the coordinated atoms in three pairs, viz. Cl/Cl, N(py)/N(py), and and N(azo)/N(azo) the stereochemistry of the isomers can be defined by setting the relative positions (cis (c) or trans (t)) within the pair of identical atoms
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This reaction does not occur in a redox-inert solvent such as acetonitrile
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This reaction does not occur in a redox-inert solvent such as acetonitrile.
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36
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85034509495
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note
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2. Admittedly, the proposal is not a unique rationalization of the experimental results. It, however, appears to be the most plausible one.
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note
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2 is cathodic by ca. -1.0 V as compared to that in 1.
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