Determination of first hyperpolarizability of nonlinear optical chromophores by second harmonic scattering using an external reference

Journal of Chemical Physics

Volumn 104, Issue 20, 1996, Pages 7821-7829

  Pauley, M A ^a   Guan, H W ^a   Wang, C H ^a   Jen, Alex K Y ^b  

^a UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^b Optical Materials Division   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

APPROXIMATION THEORY; AROMATIC COMPOUNDS; CALCULATIONS; COMPOSITION EFFECTS; MOLECULAR DYNAMICS; NONLINEAR OPTICS; OPTICAL PROPERTIES; SECOND HARMONIC GENERATION;

ANILINES; CHROMOPHORES; DEPOLARIZATION RATIO; DIMETHYLAMINO NITROSTILBENE; FIRST HYPERPOLARIZABILITY; HISTOGRAM; HYPER RAYLEIGH SCATTERING; MOLECULAR INTERACTIONS; TRICYANOVINYLTHIOPHENE DERIVATIVES;

LIGHT SCATTERING;

EID: 0030149143     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.471669     Document Type: Article

References (34)

1. D. S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals (Academic, Orlando, 1987), Vol. 2.
2. Nonlinear Optical Properties of Organic and Polymeric Materials, ACS Symposium Series 233, edited by D. J. Williams (American Chemical Society, Washington, DC, 1982).
3. D. S. Chemla and J. Zyss, Nonlinear Optical Properties of Organic Molecules and Crystals (Academic, Orlando, 1987), Vols. 1 and 2.
4. D. M. Burland, R. D. Miller, and C. A. Walsh, Chem. Rev. 94, 31 (1994).
5. K. D. Singer and A. F. Garito, J. Chem. Phys. 75, 3572 (1981).
6. G. F. Levine and C. G. Bethea, J. Chem. Phys. 60, 3856 (1974).
7. G. F. Levine and C. G. Bethea, J. Chem. Phys. 63, 2666 (1975).
8. C. G. Bethea, Appl. Opt. 14, 1447 (1975).
9. L.-T. Cheng, W. Tam, S. H. Stevenson, G. R. Meredith, G. Rikken, and S. R. Marder, J. Phys. Chem. 95, 10631 (1991).
10. L.-T. Cheng, W. Tam, S. R. Marder, A. E. Stiegman, G. Rikken, and C. W. Spangler, J. Phys. Chem. 95, 10643 (1991).
11. M. Stählein, D. M. Burland, and J. E. Rice, Chem. Phys. Lett. 191, 245 (1992).
12. D. M. Burland, C. A. Walsh, F. Kajzar, and C. Sentein, J. Opt. Soc. Am. B 8, 2269 (1991).
13. R. W. Terhune, P. D. Maker, and C. M. Savage, Phys. Rev. Lett. 14, 681 (1965).
14. K. Clays and A. Persoons, Phys. Rev. Lett. 66, 2980 (1991).
15. K. Clays and A. Persoons, Rev. Sci. Instrum. 63, 3285 (1992).
16. T. Verbiest, K. Clays, C. Samyn, J. Wolff, D. Reinhoudt, and A. Persoons, J. Am. Chem. Soc. 116, 9320 (1994).
17. T. Verbiest, E. Hendrickx, and A. Persoons, Nonlin. Opt. Prop. Org. Mat. V 1775, 206 (1992).
18. K. Clays, A. Persoons, and L. D. Maeyer, in Modern Nonlinear Optics, Advances in Chemical Physics, Vol. 85, part 3, edited by I. Prigogine and S. A. Rice (Wiley, New York, 1994).
19. V. P. Rao, A. K.-Y. Jen, K. Y. Wong, and K. J. Drost, Tet. Lett. 75, 1747 (1993).
20. M. A. Pauley, C. H. Wang, and A. K.-Y. Jen, J. Chem. Phys. 102, 6400 (1995).
21. O. Song and C. H. Wang, J. Chem. Phys. (in press).
22. -30 esu [(ε-1)/(2ε+1) is related to the reaction field experienced by the solute molecules as the result of interaction with the permanent dipole moment of the solvent molecules (C. C. Teng and A. F. Garito, this Ref.)]
23. CRC Handbook of Chemistry and Physics, 65th Edition, edited by R. C. Weast (CRC, Boca Raton, 1984).
24. F. Kazjar, I. Ledoux, and J. Zyss, Phys. Rev. A 36, 2210 (1987).
25. G. T. Heesink, A. G. T. Ruiter, N. F. V. Hulst, and B. Bolger, Phys. Rev. Lett. 7, 999 (1993).
26. -30 esu.
27. J. L. Oudar, J. Chem. Phys. 67, 446 (1977).
28. O.-K. Song (unpublished result).
29. J. N. Woodford (unpublished result).
30. R. Bersohn, Y. H. Pao, and H. L. Frish, J. Chem. Phys. 45, 3184 (1966).
31. S. Kielich, Bull. Acad. Polon. Sci. 12, 53 (1964).
32. S. J. Cyvin, J. E. Rauch, and J. C. Decius, J. Chem. Phys. 43, 4083 (1965).
33. L. Y. Yuan, Acta Phys. Sinica 20, 164 (1964).
34. M. A. Pauley and C. H. Wang (in preparation).