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2. Furthermore, one of the templates in the structure is disordered and there is expected to be some contribution in the framework from fragmentation of the tetraethylammonium template in a 150°C hydrothermal synthesis. The refinement is, however, quite sufficient to discuss the overall framework structure of the microporous layered tin sulfide but not the details of their bond lengths and angles. It should be mentioned that considering neither charge-balancing tetraethylammonium template cations nor physisorbed/chemisorbed water guests were included in the calculation of the PXRD pattern of the TEA-SnS-1 structure, the goodness-of-fit between the observed and simulated patterns is remarkably good, and within the limits of the model presented quite acceptable for the purpose used in this study.
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