Conversion of Alkyltantalum Chlorides to Fluorides Using Trimethyltin Fluoride as a Fluorinating Agent. Crystal Structures of (p-MeC6H4CH2)3TaF2, (Me3SnCl.Me3SnF.TaF5)n, (Me3Si)2CHTaCl4

Organometallics

Volumn 18, Issue 5, 1999, Pages 832-836

  Guzyr, Olexandr I ^a   Schormann, Mark ^a   Schimkowiak, Jürgen ^a   Roesky, Herbert W ^a   Lehmann, Christopher ^a   Walawalkar, Mrinalini G ^a   Murugavel, Ramaswarny ^a   Schmidt, Hans Georg ^a   Noltemeyer, Mathias ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000338425     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980768g     Document Type: Article

References (23)

1. (a) Nugent, W. A.; Mayer, J. M. Metal-Ligand Multiple Bonds The Chemistry of Transition Metal Complexes Containing Oxo, Nitrido, Imido, Alkylidene, or Alkylidyne Ligands; John Wiley & Sons: New York, 1988, and references therein
2. (b)Schrock, R.R., Fellmann, J.D. J. Am. Chem. Soc. 1978, 100, 3359.
3. (c) Li, L.; Hung, M.; Xue, Z. J. Am. Chem. Soc. 1996, 117, 12746.
4. (a) Herzog, A.; Liu, F.-Q.; Roesky, H. W., Demsar, A.; Keller, K.; Noltemeyer, M.; Pauer, F. Organometallics 1994, 13, 1251.
5. (b) Roesky, H. W.; Herzog, A.; Keller, K. Z. Naturforsch. B 1994, 49, 981.
6. (c) Roesky, H. W.; Keller, K. J. Fluor. Chem. 1998, 89, 3.
7. (a) Waezsada, S. D.; Liu, F.-Q.; Murphy, E. F.; Roesky, H. W.; Teichert, M.; Usón, I.; Schmidt, H.-G.; Albers, T.; Parisini, E.; Noltemeyer, M. Organometallics 1997, 16, 1260.
8. (b) Schnitter, C.; Klimek, K.; Roesky, H. W.; Albers, T.; Schmidt, H -G.; Ropken, C.; Parisini, E. Organometallics 1998, 17, 2249.
9. Roesky, H. W.; Schrumpf, F.; Noltemeyer, M. J. Chem Soc., Dalton Trans. 1990, 713.
10. (a) Chamberlain, L. R; Rothwell, I. P.; Folting, K.; Huffman, J. C. J. Chem. Soc., Dalton Trans. 1987, 155.
11. (b) Piersol, C. J.; Profilet, R. D.; Fanwick, P. E.; Rothwell, I. P. Polyhedron 1993, 12, 1779
12. (a) Cowley, A. H.; Lasch, J. G.; Norman, N. C.; Pakulski, M.; Whittlesey, B. R. Chem Commun. 1983, 881.
13. (b) Uhl, W. Z. Naturforsch. B 1988, 43, 1113.
14. (c) Uhl, W.; Layh, M.; Hildenbrand, T. J. Organomet. Chem. 1989, 364, 289.
15. (d) Flynn, K. M.; Olmstead, M. M.; Power, P. P. J. Am. Chem. Soc. 1983, 105, 2085.
16. (a) Schreck, R. R. J. Organomet. Chem. 1976, 122, 209
17. (b) Piersol, C. J.; Profilet, R. D.; Fanwick, P E.; Rothwell, I. P. Polyhedron 1993, 12, 1779.
18. (c) Moorhouse, S.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1974, 2187.
19. (d) Johnson, W. K. J. Org. Chem. 1960, 25, 2253.
20. (e) Levchuk, L. E.; Sams, J. R.; Aubke, F. Inorg. Chem. 1972, 11, 43.
21. Elemental analyses of compound 3 cannot be improved due to impurities in the crude product which we were not able to remove by distillation.
22. Sheldrick, G. M. Acta Crystallogr., Sect A 1990, 46, 467.
23. Sheldrick, G. M. SHELXL, Program for Crystal Structure Refinement; University of Göttingen: Göttingen, Germany, 1997.