Direct Observation of (Me3ECH2)5Ta (E = C, Si) as the Precursors to (Me3ECH2)3Ta==CHEMe3 and (Me3SiCH2)2Ta(μ-CSiMe3)2Ta(CH2SiMe3)2. Kinetic and Mechanistic Studies of the Formation of Alkylidene and Alkylidyne Ligands

Journal of the American Chemical Society

Volumn 117, Issue 51, 1995, Pages 12746-12750

  Li, Liting ^a   Hung, Meiling ^a   Xue, Ziling ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000601195     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja00156a011     Document Type: Article

References (43)

1. Schrock, R.R. J. Am. Chem. Soc. 1974, 96, 6796.
2. Schrock, R.R.; Fellmann, J.D. J. Am. Chem. Soc. 1978, 100, 3359.
3. Schrock, R.R. Acc. Chem. Res. 1979, 12, 98.
4. Schrock, R.R. In Reactions of Coordinated Ligands; Braterman, P.S., Ed.; Plenum: New York, 1986.
5. Schrock, R.R. J. Organomet. Chem. 1986, 300, 249.
6. Feldman, J.; Schrock, R.R. Prog. Inorg. Chem. 1991, 39, 1.
7. Nugent, W.A.; Mayer, J.M. Metal-Ligand Multiple Bonds; Wiley: New York, 1988.
8. Advances in Metal Carbene Chemistry; Schubert, U., Ed.; NATO ASI Series, Series C, 1989; Vol. 269.
9. Aguero, A.; Osborn, J.A. New J. Chem. 1988, 12, 111.
10. Grubbs, R.H. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F.G.A., Abel, E.W., Eds.; Pergamon: New York, 1982; Vol. 8, Chapter 54.
11. Schrock, R.R. Acc. Chem. Res. 1990, 23, 158.
12. Fujimura, O.; Fu, G.C.; Rothemund, P.W.K.; Grubbs, R.H. J. Am. Chem. Soc. 1995, 117, 2355 and references therein.
13. Schrock, R.R.; Meakin, P. J. Am. Chem. Soc. 1974, 96, 5288.
14. Wu, Y.-D.; Chan, K.W.K.; Xue, Z. J. Am. Chem. Soc. 1995, 117, 9259.
15. Schrock, R.R. J. Organomet. Chem. 1976, 122, 209.
16. Malatesta, V.; Ingold, K.U.; Schrock, R.R. J. Organomet. Chem. 1978, 152, C53.
17. Piersol, C.J.; Profilet, R.D.; Fanwick, P.E.; Rothwell, I.P. Polyhedron 1993, 12, 1779.
18. Mowat, W.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1973, 1120.
19. Davidson, P.J.; Lappert, M.F.; Pearce, R. Chem. Rev. 1976, 76, 219.
20. Schrock, R.R.; Parshall, G.W. Chem. Rev. 1976, 76, 243.
21. Moorhouse, S.; Wilkinson, G. J. Chem. Soc., Dalton Trans. 1974, 2187.
22. Moorhouse, S.; Wilkinson, G. J. Organomet. Chem. 1973, 52, C5.
23. Rupprecht, G.A. Thesis, Massachusetts Institute of Technology, 1979.
24. Xue, Z.; Li, L.; Hoyt, L.K.; Diminnie, J.B.; Pollitte, J.L. J. Am. Chem. Soc. 1994, 116, 2169.
25. Li, L.; Diminnie, J.B.; Pollitte, J.L.; Xue, Z. Manuscript in preparation.
26. Tessier-Youngs, C.; Beachley, O.T., Jr. Inorg. Synth. 1986, 24, 95.
27. Lewis, H.L.; Brown, T.L. J. Am. Chem. Soc. 1970, 92, 4664.
28. Morse, P.M.: Spencer, M.D.: Wilson, S.R.: Girolami. G.S. Organometallics 1994, 13, 1646.
29. Taylor, J.R. An Introduction to Error Analysis; University Science Books: Milley Valley, CA, 1982; Chapter 4.
30. Wilkins, R.G. The Study of Kinetics and Mechanism of Reactions of Transition Metal Complexes; Allyn and Bacon: Boston, 1974; pp 79–82.
31. Espenson, J.H. Chemical Kinetics and Reaction Mechanisms, 2nd ed.; McGraw-Hill Book Co.: New York, 1995; pp 171—172.
32. Noggle, J.H. Physical Chemistry; Little, Brown and Co.: Boston, 1985; pp 504—508.
33. Atwood, J.D. Inorganic and Organometallic Reaction Mechanisms; Brooks/Cole Publishing Co.: Montery, CA, 1985.
34. Wood, C.D.; McLain, S.J.; Schrock, R.R. J. Am. Chem. Soc. 1979, 101, 3210.
35. Smith, G.M.; Carpenter, J.D.; Marks, T.J. J. Am. Chem. Soc. 1986, 108, 6805.
36. McDade, C.; Green, J.C.; Bercaw, J.E. Organometallics 1982, 1, 1629.
37. Bulls, A.R.; Schaefer, W.P.; Serfas, M.; Bercaw, J.E. Organometallics 1987, 6, 1219.
38. Rothwell, I.P. Acc. Chem. Res. 1988, 21, 153.
39. Buchwald, S.L.; Nielson, R.B. J. Am. Chem. Soc. 1988, 110, 3171.
40. Caulton, K.G.; Chisholm, M.H.; Streib, W.E.; Xue, Z. J. Am. Chem. Soc. 1991, 113, 6082.
41. Shi, Q.-Z.; Richmond, T.G.; Trogler, W.C.; Basolo, F. J. Am. Chem. Soc. 1984, 106, 71.
42. Jordan, R.B. Reaction Mechanisms of Inorganic and Organometallic Systems; Oxford University Press: New York, 1991.
43. Schmidbaur, H.; Hasslberger, G. Chem. Ber. 1978, 111, 2702.