Borabenzene derivatives. 26.1 syntheses of 1-methylboratabenzene complexes of titanium, zirconium, and hafnium. Structures of TiCl3(C5H5BMe), TiCl2Cp(C5H5BMe), ZrCl2(C5H5BMe)2, and ZrCl2Cp*(C5H5BMe)

Organometallics

Volumn 16, Issue 17, 1997, Pages 3751-3757

  Herberich, Gerhard E ^a   Englert, Ulli ^a   Schmitz, Andreas ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000335587     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970313b     Document Type: Article

References (55)

1. Englert, U.; Herberich, G. E.; Rosenplänter, J. Z. Anorg. Allg. Chem. 1997, in press.
2. (a) Hoic, D. A.; Davis, W. M.; Fu, G. C. J. Am. Chem. Soc. 1996, 118, 8176.
3. (b) Qiao, S.; Hoic, D. A.; Fu, G. C. J. Am. Chem. Soc. 1996, 118, 6329.
4. (c) Hoic, D. A.; Davis, W. M.; Fu, G. C. J. Am. Chem. Soc. 1995, 117, 8480.
5. Ashe, A. J., III; Kampf, J. W.; Müller, C.; Schneider, M. Organometallics 1996, 15, 387.
6. (a) Herberich, G. E.; Schmidt, B.; Englert, U. Organometallics 1995,14, 471.
7. (b) Herberich, G. E.; Englert, U.; Schmidt, M. U.; Standt, R. Organometallics 1996, 15, 2707.
8. (c) Herberich, G. E.; Schmidt, B.; Englert, U.; Wagner, T. Organometallics 1993, 12, 2891.
9. Herberich, G. E. Boratabenzene Chemistry Revisted. In Advances in Boron Chemistry; Siebert, W., Ed.; The Royal Society of Chemistry: Cambridge, U.K., 1997; Special Publication No. 201, p 211.
10. Herberich, G. E.; Ohst, H. Adv. Organomet. Chem. 1986, 25 199.
11. Bazan, G. C.; Rodriguez, G.; Ashe, A. J., III; Al-Ahmad, S.; Müller, C. J. Am. Chem. Soc. 1996, 118, 2291.
12. Herberich, G. E.; Rosenplänter, J.; Schmidt, B.; Englert, U. Organometallics 1997, 16, 926.
13. (a) Amendola, M. C.; Stockman, K. E.; Hoic, D. A.; Davis, W. M.; Fu, G. C. Angew. Chem., Int. Ed. Engl. 1997, 36, 267.
14. (b) Hoic, D. A.; Wolf, J. R.; Davis, W. M.; Fu, G. C. Organometallics 1996, 15, 1315.
15. (a) Brintzinger, H.-H.; Fischer, D.; Mülhaupt, R.; Rieger, B.; Waymouth, R. Angew. Chem., Int. Ed. Engl. 1995, 34, 1143.
16. (b) Ziegler Catalysts; Fink, G.; Mülhaupt, R.; Brintzinger, H.-H., Eds.; Springer-Verlag: Berlin, 1995.
17. (c) Jordan, R. F. Adv. Organomet. Chem. 1991, 32, 325.
18. (d) Bochmann, M. J. Chem. Soc., Dalton Trans. 1996, 255.
19. (e) Negishi, E.; Takahashi, T. Acc. Chem. Res. 1994, 27, 124.
20. (f) Jia, L.; Yang, X.; Seyam, A. M.; Albert, I. D. L.; Fu, P.-F., Yang, S.; Marks, T. J. J. Am. Chem. Soc. 1996, 118, 7900 and references cited therein.
21. See: (a) Hoveyda, A. H.; Morken, J. P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1262. (b) Pine, S. H. Org. React. 1993, 43, 1.
22. See: (a) Hoveyda, A. H.; Morken, J. P. Angew. Chem., Int. Ed. Engl. 1996, 35, 1262. (b) Pine, S. H. Org. React. 1993, 43, 1.
23. (a) 1-Phenyl-1,4-dihydroborinine can be deprotonated by NaCp in THF, see: Sandford, H. F. Ph.D. Thesis, University of Michigan, Ann Arbor, MI, 1979.
24. (b) Gas-phase acidities, see: Sullivan, S. A.; Sandford, H.; Beauchamp, J. L.; Ashe, A. J., III J. Am. Chem. Soc. 1978, 100, 3737.
25. 5BMe, see: Herberich, G. E.; Schmitz, A. Unpublished work.
26. Gorsich, R. D. J. Am. Chem. Soc. 1958, 80, 4744.
27. The cell parameters of the product were determined by X-ray crystallography and were identical with those of an authentic sample, cf.: Handlowics, M.; Miklos, D.; Zikmund, M. Acta Crystallogr., Sect. B 1981, 37, 811.
28. x possess polymeric structures. (a) Engelhardt, L. M.; Papasergio, R. I.; Raston, C. L.; White, A. H. Organometallics 1984, 3, 18. (b) Poli, R. Chem. Rev. 1991, 91, 509.
29. x possess polymeric structures. (a) Engelhardt, L. M.; Papasergio, R. I.; Raston, C. L.; White, A. H. Organometallics 1984, 3, 18. (b) Poli, R. Chem. Rev. 1991, 91, 509.
30. 3
31. 3
32. For the use of this mild and efficient oxidant, cf.: Luinstra, G. A.; Teuben, J. H. Organometallics 1992, 11, 1793.
33. Ashe, A. J., III; Shu, P. J. Am. Chem. Soc. 1971, 93, 1804.
34. Herberich, G. E.; Engelke, C.; Pahlmann, W. Chem. Ber. 1979, 112, 607.
35. Koelle, U. Inorg. Chim. Acta 1981, 47, 13.
36. Morse, D. B.; Hendrickson, D. N.; Rauchfuss, T. B.; Wilson, S. R. Organometallics 1988, 7, 496.
37. (a) Bajgur, C. S.; Tikkanen, W. R.; Petersen, J. L. Inorg. Chem. 1985, 24, 2539.
38. (b) Kucharenko, S. V.; Solveichik, G. L.; Strelets, V. V. Metallorg. Khim. 1989, 2, 295.
39. Fakhr, A.; Mugnier, Y.; Gautheron, B.; Laviron, E. J. Organomet. Chem. 1986, 302, C7.
40. Spek, A. L. Acta Crystallogr. 1990, A46, C34.
41. Keller, E. SCHAKAL 88, A Fortran Program for the Representation of Molecular and Crystallographic Models; Kristallographisches Institut der Universität Freiburg: Freiburg, Germany, 1980.
42. 5 plane.
43. (a) Huttner, G.; Gartzke, W. Chem. Ber. 1974, 107, 3786.
44. (b) Böhm, M. C.; Gleiter, R.; Herberich, G. E.; Hessner, B. J. Phys. Chem. 1985, 89, 2129.
45. See ref 8, p 204.
46. (a) Herberich, G. E.; Hessner, B.; Ohst, H.; Raap, I. A. J. Organomet. Chem. 1988, 348, 305.
47. (b) Herberich, G. E.; Englert, U.; Hostalek, M.; Laven, R. Chem. Ber. 1991, 124, 17.
48. (c) Herberich, G. E.; Negele, M.; Ohst, H. Chem. Ber. 1991, 124, 25.
49. (d) Quan, R. W.; Bazan, G. C.; Schaefer, W. P.; Bercaw, J. E.; Kiely, A. F. J. Am. Chem. Soc. 1994, 116, 4489.
50. Ashe, A. J., III; Kampf, J. W.; Waas, J. R. Organometallics 1997, 16, 163.
51. Ashe, A. J., III; Al-Taweel, S. M.; Drescher, C.; Kampf, J. W.; Klein, W. Organometallics 1997, 16 1884.
52. Gubin, S. P.; Smirnova, S. A.; Denisovich, L. I.; Lubovich, A. A. J. Organomet. Chem. 1971, 30, 243.
53. Sheldrick, G. M. SHELXS-86, Program for Structure Solution; Göttingen, Germany, 1986.
54. Frenz, B. A. ENRAF-Nonius, SDP Version 5.0; Delft, The Netherlands, 1989.
55. Further details of the crystal structure analysis are available on request from the Fachinformationszentrum Karlsruhe, Gesellschaft fur wissenschaftlich-technische Information mbH, D-76344 Eggenstein-Leopoldshafen, Germany, on quoting the depository number CSD-407116 for 6a, CSD-407115 for 7b, CSD-407114 for 8a, and CSD-407113 for 9b, the names of the authors and this journal citation.