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Volumn 59, Issue 6, 1999, Pages 6838-6841

Low-temperature interface between the gas and solid phases of hard spheres with a short-ranged attraction

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ARTICLE;

EID: 0000325233     PISSN: 1063651X     EISSN: None     Source Type: Journal    
DOI: 10.1103/PhysRevE.59.6838     Document Type: Article
Times cited : (7)

References (36)
  • 9
    • 85037183722 scopus 로고    scopus 로고
    • (URL: http://xxx.lanl.gov). Note that the terminology in this paper is different to that here. There as here, I take the (Formula presented) limit to obtain the (Formula presented) model, but in this reference I describe the (Formula presented) model as sticky spheres. This does not mean that in this reference I am considering the model defined by Baxter 21
    • R. P. Sear, Mol. Phys. (to be published) (e-print cond-mat/9805201) (URL: http://xxx.lanl.gov). Note that the terminology in this paper is different to that here. There as here, I take the (Formula presented) limit to obtain the (Formula presented) model, but in this reference I describe the (Formula presented) model as sticky spheres. This does not mean that in this reference I am considering the model defined by Baxter 21.
    • Sear, R.P.1
  • 27
    • 85037250633 scopus 로고    scopus 로고
    • The temperature range when (Formula presented) is zero 5 9. For finite but short-ranged potentials it is small, as can be seen in the computer simulation results of Hagen and Frenkel 33, and in the theoretical results of Baus and co-workers 34 35 36. Even as the range of the potential increases toward the value at which a liquid phase becomes stable, the temperature range over which the coexisting fluid density decreases from rather high values, volume fractions above 40%, to very low values is narrow. This is enforced by the approach from below the metastable vapor-liquid critical point, to the fluid–solid-coexistence curve. Isotherms are very flat near a critical point and so the approaching critical point forces the curve of the coexisting fluid density (plotted against temperature) to be very flat
    • The temperature range when (Formula presented) is zero 59. For finite but short-ranged potentials it is small, as can be seen in the computer simulation results of Hagen and Frenkel 33, and in the theoretical results of Baus and co-workers 343536. Even as the range of the potential increases toward the value at which a liquid phase becomes stable, the temperature range over which the coexisting fluid density decreases from rather high values, volume fractions above 40%, to very low values is narrow. This is enforced by the approach from below the metastable vapor-liquid critical point, to the fluid–solid-coexistence curve. Isotherms are very flat near a critical point and so the approaching critical point forces the curve of the coexisting fluid density (plotted against temperature) to be very flat.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.