1-Pyrrolyldiisobutylalane. A stereoselective reducing agent for reduction of cyclic ketones to thermodynamically more stable alcohols

Bulletin of the Korean Chemical Society

Volumn 21, Issue 6, 2000, Pages 659-661

  Kwon, Oh Oun ^a   Cha, Jin Soon ^a  

^a Yeungnam University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL DERIVATIVE; KETONE DERIVATIVE; PYRROLE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; REACTION ANALYSIS; REDUCTION; STEREOCHEMISTRY; THERMODYNAMICS;

EID: 0000320854     PISSN: 02532964     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (12)

1. (a) Cha, J. S.; Kwon, O. O.; Kwon, S. Y.; Kim, J. M.; Seo, W. W.; Chang, S. W. Synlett 1995, 1055.
2. (b) Cha, J. S.; Kwon, O. O.; Kwon, S. Y. Bull. Korean Chem. Soc. 1995, 16, 1009.
3. (a) Cha, J. S.; Kwon, O. O.; Kwon, S. Y.; Kim, J. M.; Seo, W. W.; Chang, S. W. Bull. Korean Chem. Soc. 1996, 17, 221.
4. (b) Cha, J. S.; Kwon, O. O.; Kwon, S. Y. Org. Prep. Proced. Int. 1996, 28, 355.
5. (c) Cha, J. S.; Kwon, O. O. J. Org. Chem. 1997, 62, 3019.
6. (d) Cha, J. S.; Kwon, O. O. Bull. Korean Chem. Soc. 1997, 18, 689.
7. (e) Cha, J. S.; Kwon, O. O.; Kim, J. M.; Chun, J. H.; Lee, Y. S.; Lee, H. S.; Cho, S. D. Ibid. 1998, 19, 236.
8. Cha, J. S.; Kwon, S. Y.; Kwon, O. O.; Kim, J. M. Bull. Korean Chem. Soc. 1996, 17, 900.
9. (a) Haubenstock, H.; Davidson, E. B. J. Org. Chem. 1963, 28, 2772.
10. (b) Heinsohn, G. E.; Ashby, E. C. Ibid. 1973, 38, 4232.
11. (c) Cha, J. S.; Kwon, O. O.; Kim, J. M.; Cho, S. D. Synlett 1997, 1465.
12. 2 atmosphere. All chemicals used were commercial products of the highest purity available; ethyl ether was dried over 4-Å molecular sieves and distilled from sodium-benzophenone ketyl prior to use. Gas chromatographic analyses were carried out with a Varian 3300 chromatograph using a 30 m DB-WAX capillary column.