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Volumn 18, Issue 8, 1999, Pages 1419-1429

Ruthenium silyl complexes containing the Cp(PMe3)2Ru moiety: Preparation, substituent effects, and silylene character in the Ru-Si bond

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EID: 0000297714     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980951+     Document Type: Article
Times cited : (35)

References (71)
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    • Tilley, T.D.1
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    • (1989) The Chemistry of Organic Silicon Compounds , pp. 1479-1526
    • Ojima, I.1
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    • King, R. B., Ed.; Wiley: Chichester
    • Harrod, J. F. In Encyclopedia of Inorganic Chemistry; King, R. B., Ed.; Wiley: Chichester, 1994; Vol. 3; pp 1486-1496.
    • (1994) Encyclopedia of Inorganic Chemistry , vol.3 , pp. 1486-1496
    • Harrod, J.F.1
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    • Corey, J. Y., Corey, E. R., Gaspar, P. P., Eds.; Ellis Horwood Limited: Chichester, West Sussex England
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    • note
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    • note
    • 2H) to silylene loss during sublimation parallels the preference for silylene loss observed in a mass spectral study of these hydrosilanes. Details of this mass spectral study will be reported in a later publication.
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    • 3743130867 scopus 로고    scopus 로고
    • note
    • i parameters.
  • 59
  • 60
    • 3743087306 scopus 로고    scopus 로고
    • note
    • 29Si chemical shift changes upon H/Cl, H/Me, and Cl/Me exchanges (see text). All substituent exchanges can be viewed as conversions within a silyl class just by changing the classification criteria. A classification criterion based on the number of chlorines on silicon is used throughout this paper for internal consistency.
  • 61


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