Electroreduction of Pd2(dppm)2Cl2 and Pd(dppm)Cl2 [dppm = bis(diphenylphosphino)methane] in aprotic medium under carbon dioxide: Electrogeneration of Pd3(μ3-CO)(μ-dppm)3

New Journal of Chemistry

Volumn 22, Issue 3, 1998, Pages 237-246

  Gauthron, Isabelle ^a   Mugnier, Yves ^a   Hierso, Karine ^b   Harvey, Pierre D ^b  

^a UNIVERSITÉ DE BOURGOGNE   (France)

^b UNIVERSITÉ DE SHERBROOKE   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000295195     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/a708331i     Document Type: Article

References (76)

1. (a) B. J. Fisher and R. Eisenberg, J. Am. Chem. Soc., 1980, 102, 7361;
2. (b) M. R. M. Bruce, E. Megehee, B. P. Sullivan, H. Thorp, T. R. O'Toole, A. Downard and T. J. Meyer, Organometallics, 1988, 7, 238 and references therein;
3. (c) K. W. Frese, D. P. Summers and M. J. Cinibulk, J. Electrochem. Soc., 1988, 135, 264;
4. (d) C. Amatore and J. M. Savéant, J. Am. Chem. Soc., 1981, 103, 5021;
5. (e) E. Lamy, L. Nadjo and J. M. Savéant, J. Electroanal Chem., 1977, 78, 403;
6. (f) B. J. Fisher, T. Lehman and E. J. Heitz, Appl. Electrochem., 1981, 11, 743;
7. (g) P. A. Christensen, A. Hammett and A. V. G. Muir, J. Electroanal. Chem., 1990, 288, 197;
8. (h) J. Desilvestro and S. Pons, J. Electroanal. Chem., 1989, 267, 207.
9. 4 as supporting electrolyte has been estimated to be -2.2 V vs. SCE by cyclic voltammetry on a mercury electrode [see ref. 1(e)].
10. Recent reviews: (a) G. Silvestri, in Carbon Dioxide as a Source of Carbon, ed. M. Aresta and G. Forti, NATO ASI Series: Ser. C, Reidel, Dordrecht, 1987, p. 339.
11. 2 Utilization, NATO ASI Series, Reidel, Dordrecht, 1990, 314, 101.
12. J. P. Collin and J. P. Sauvage, Coord. Chem. Rev., 1989, 93, 245.
13. D. L. DuBois and A. Miedaner, J. Am. Chem. Soc., 1987, 109, 113.
14. S. Slater and J. H. Wagenknecht, J. Am. Chem. Soc., 1984, 106, 5367.
15. A. Szymaszek and F. P. Pruchnik, J. Organomet. Chem., 1987, 376, 133.
16. D. L. DuBois, A. Miedaner and R. C. Haltiwanger, J. Am. Chem. Soc., 1991, 113, 8753.
17. K. S. Ratcliff, R. E. Lentz and C. P. Kubiak, Organometallics, 1992, 11, 1986.
18. (a) D. L. DuBois and A. Miedaner, Inorg. Chem., 1986, 25, 4642;
19. D. L. DuBois and A. Miedaner, Inorg. Chem., 1988, 27, 2479;
20. (c) A. Miedaner, D. L. DuBois and C. J. Curtis, Organometallics, 1993, 12, 299;
21. (d) B. D. Stefey, C. J. Curtis and D. L. DuBois, Organometallics, 1995, 14, 4937.
22. (a) L. S. Benner and A. L. Balch, J. Am. Chem. Soc., 1978, 100, 6099;
23. (b) E. W. Stern and K. Maples, J. Catal., 1972, 27, 120.
24. E. J. Baerends, D. E. Ellis and P. Ros, J. Chem. Phys., 1973, 2, 41.
25. E. J. Baerends, Ph.D. Thesis, Vrije Universiteit, Amsterdam, 1975.
26. W. Raveneck, in Algorithms and Applications on Vector and Parallel Computers, ed. H. J. J. Rigie, Th. J. Dekkor and H. A. van de Vorst, Elsevier, Amsterdam, 1987.
27. P. M. Boerrigter, G. te Velde and E. J. Baerends, Int. J. Quantum Chem., 1988, 33, 87.
28. L. Versluis and T. Ziegler, J. Chem. Phys., 1988, 88, 322.
29. (a) G. J. Snijders, E. J. Baerends and P. Vernooÿs, At. Nucl. Data Tables, 1982, 26, 483;
30. (b) P. Bernooÿs, G. J. Snijders and E. J. Baerends, Int. Slater Type Basis Functions for the Whole Periodic System, Free University of Amsterdam, Amsterdam, 1981.
31. (a) L. Noodleman and J. G. Norman, J. Chem. Phys., 1979, 70, 4903;
32. (b) L. Noodleman, J. Chem. Phys., 1981, 74, 5737;
33. (c) L. Noodleman and E. J. Baerends, J. Am. Chem. Soc., 1984, 106, 2316.
34. J. Krijn and E. J. Baerends, in Fit Functions in the JFS Method, (in Dutch), Free University of Amsterdam, Amsterdam, 1984.
35. S. D. Vosko, L. Wilk and M. Nusair, Can. J. Phys., 1990, 58, 1200.
36. (a) C. Amatore, M. Azzali and A. Jutand, J. Organomet. Chem., 1989, 363, C41;
37. C. Amatore, M. Azzali and A. Jutand, J. Am. Chem. Soc., 1991, 113, 8375.
38. I. Gauthron, Y. Mugnier, K. Hierso and P. D. Harvey, Can. J. Chem., in the press.
39. (a) L. Manojlovic-Muir, K. W. Muir, B. R. Lloyd and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1983, 1336;
40. (b) B. R. Lloyd and R. J. Puddephatt, Inorg. Chim. Acta, 1984, 90, L77;
41. (c) L. Manojlovic-Muir, K. W. Muir, B. R. Lloyd and R. J. Puddephatt, J. Chem. Soc., Chem. Commun., 1985, 536.
42. B. R. Lloyd, L. Manojlovic-Muir, K. W. Muir and R. J. Puddephatt, Organometallics, 1993, 12, 1231.
43. 2+ has been observed recently by UV-visible spectroscopy. This reactivity is reversible by bubbling another gas.
44. M. Sakamoto, I. Shimizu and A. Yamamoto, Organometallics, 1994, 13, 407.
45. D. T. Pierce and W. E. Geiger, J. Am. Chem. Soc., 1992, 114, 6063.
46. (a) C. Amatore, L. Nadjo and J. M. Savéant, Nouv. J. Chim., 1979, 3, 545;
47. (b) E. Lamy, L. Nadjo and J. M. Savéant, J. Electroanal Chem., 1977, 78, 403;
48. (c) C. Amatore and J. M. Savéant, J. Am. Chem. Soc., 1981, 103, 5021;
49. (d) C. Amatore, L. Nadjo and J. M. Savéant, Nouv. J. Chim., 1984, 8, 565.
50. See for example: (a) G. R. Lee, J. M. Maher and N. J. Cooper, J. Am. Chem. Soc., 1987, 109, 2956;
51. G. Fachinetti, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Am. Chem. Soc., 1979, 101, 1767;
52. (c) J. Chatt, M. Kubota, G. J. Leigh, T. C. March, R. Mason and D. J. Yarrow, J. Chem. Soc., Chem. Commun., 1974, 1033;
53. (d) H. H. Karsch, Chem. Ber., 1977, 110, 2213;
54. (e) E. Carmona, F. Gonzalez, M. L. Poveda and J. M. Marin, J. Am. Chem. Soc., 1983, 105, 3365;
55. (f) R. Alvarez, E. Carmona, M. L. Poveda and R. Sanchez-Delgado, J. Am. Chem. Soc., 1984, 106, 2731.
56. R. H. Crabtree, The Organometallic Chemistry of the Transition Metals, Wiley, New York, 2nd edn., 1994, p. 318.
57. D. H. Gibson, Chem. Rev., 1996, 96, 2063.
58. W. Leitner, Coord. Chem. Rev., 1996, 153, 257.
59. M. Aresta, C. F. Nobile, V. G. Albano, E. Form and M. Manassro, J. Chem. Soc., Chem. Commun., 1975, 636.
60. T. Heckovitz, J. Am. Chem. Soc., 1977, 99, 2391.
61. E. Kaufmann, S. Sieber and P. von Ragué Schleyer, J. Am. Chem. Soc., 1989, 111, 4005.
62. S. Sakaki and K. Ohkubo, Inorg. Chem., 1988, 27, 2020.
63. S. Sakaki and Y. Musashi, J. Chem. Soc., Dalton Trans., 1994, 3047.
64. C. Bo and A. Dedieu, Inorg. Chem., 1989, 28, 304.
65. M. Sodupe, V. Branchadell and A. Oliva, J. Phys. Chem., 1995, 99, 8567.
66. S. Sirois, M. Castro and D. R. Salahub, Int. J. Quantum Chem.: Quantum Chem. Symp., 1994, 28, 645.
67. R. Provencher and P. D. Harvey, Inorg. Chem., 1996, 35, 2113.
68. P. D. Harvey, R. Provencher, J. Gagnon, T. Zhang, D. Fortin, K. Hierso, M. Drouin and S. M. Socal, Can. J. Chem., 1996, 74, 2268.
69. F. A. Cotton, G. Wilkinson and P. D. Gaus, Basic Inorganic Chemistry, Wiley, Toronto, 3rd edn., 1995, p. 61. The covalent radii for Ni is 1.25 Å.
70. We estimate the covalent radii for Pd to be ≈1.32 Å, which is half of the average of all known Pd-Pd bond distances for singly bonded dimers. See, for example: P. D. Harvey and Z. Murtaza, Inorg. Chem., 1993, 32, 4721.
71. M. J. Fink, J. T. Mague and Y. Pan, J. Am. Chem. Soc., 1993, 115, 3842.
72. For a recent review see: P. D. Harvey, J. Cluster Sci., 1993, 4, 377.
73. P. D. Harvey, R. F. Dallinger, W. H. Woodruff and H. B. Gray, Inorg. Chem., 1989, 28, 3057.
74. P. D. Harvey and H. B. Gray, J. Am. Chem. Soc., 1988, 110, 2145.
75. R. V. Kirss and R. Eisenberg, Inorg. Chem., 1989, 28, 3372.
76. S. Sakaki, M. Ogawa and Y. Musashi, J. Phys. Chem., 1995, 99, 17134.