Synthesis and structures of novel octadecanuclear clusters [Cu12RE6(μ3-OH)24(pyb) 12(H2O)18(μ12-ClO 4)]17+(RE=Sm, Eu)

Science in China, Series B: Chemistry

Volumn 39, Issue 5, 1996, Pages 536-545

  Chen, Xiaoming ^a   Wu, Yulan ^a   Wang, Ruji ^b  

^a SUN YAT SEN UNIVERSITY   (China)

^b TSINGHUA UNIVERSITY   (China)

Author keywords

Copper(II); Heterometallic cluster; Rare earth(III)

Indexed keywords

EID: 0009492181     PISSN: 10069291     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (16)

1. Wang, S., Heterometallic yittrium-copper complexes, Inorg. Chem., 1991, 30: 2252.
2. Blake, A. J., Cherepamov, V. A., Dunlop, A. A. et al., Synthesis, crystal structures and thermal decomposition studies of a series of copper-lanthanoid complexes of 6-methyl-2-pyridone, J. Chem. Soc., Dalton Trans., 1994, 2719.
3. 2 (Ln=Gd, Dy) species, Inorg. Chem., 1990, 29: 1750.
4. Andruh, M., Ramade, I., Codjovi, E. et al., Crystal structure and magnetic properties of hexanuclear clusters: Mechanism of the Gd(III)-Cu(II) magnetic interaction, J. Am. Chem. Soc., 1993, 115: 1822;
5. II molecular material, Inorg. Chem., 1992, 31: 110.
6. 2, Inorg. Chem., 1994, 33: 2444.
7. 2O, Polyhedron, 1994, 13: 1087.
8. Chen, X. M., Mak, T. C. W., Preparation and crystal structures of four silver(I) complexes of betaine derivatives, J. Chem. Soc., Dalton Trans., 1991, 2353.
9. Hathaway, B. J., Comprehensive Coordination Chemistry, Vol. 2, Oxford: Pergamon Press, 1987, 413.
10. Hesse, K. F., Eysel, W., Structure of dimercury(II) germanate, Acta Crystallogr., Sect. B, 1981, 37: 429.
11. Real, J. A., Munno, G. D., Chiappetta, R. et al., Structural and magnetic characterization of a novel heptanuclear hydroxo-bridged copper(II) clusters of corner-sharing dicubane type, Angew. Chem. Int. Ed. Engl., 1994, 33: 1184.
12. 2O)], J. Chem. Soc., Chem. Commun., 1994, 2455.
13. Ma Jianfang, Jin Zhong, Ni Jiazan, Synthesis and crystal structure of rare-earth complexes of m-methylbenzoic acid, Acta Chim. Sin. (in Chinese), 1993, 51: 784.
14. 2, J. of Inorganic Chemistry (in Chinese), 1992, 8: 22.
15. VI cluster encapsulating chloride anions, J. Chem. Soc., Chem. Commun., 1994, 1635.
16. 4], J. Chem. Soc., Chem. Commun., 1994, 2663.