Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R) 2-1,3}3] (R=Me or tBu)

Journal of Organometallic Chemistry

Volumn 636, Issue 1-2, 2001, Pages 124-129

  Blake, Paul C ^a   Edelstein, Norman M ^b   Hitchcock, Peter B ^a   Kot, Wing K ^b   Lappert, Michael F ^a   Shalimoff, George V ^b   Tian, Shun ^a  

^a Sch Chem   (United Kingdom)

^b LAWRENCE BERKELEY NATIONAL LABORATORY   (United States)

Author keywords

EPR spectra; Structures; Thorium(III) cyclopentadienyls

Indexed keywords

EID: 0000277778     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)00860-9     Document Type: Article

References (14)

1. cf. F.T. Edelmann, in: E.W. Abel, F.G.A. Stone, G. Wilkinson (Eds.), Comprehensive Organometallic Chemistry, 2nd ed., vol. 4, (M.F. Lappert (Ed.)), Pergamon, Oxford, Ch. 2, 1995.
2. Blake P.C., Lappert M.F., Atwood J.L., Zhang H. J. Chem. Soc. Chem. Commun. 1986;1148.
3. Blake P.C., Lappert M.F., Taylor R.G., Atwood J.L., Hunter W.E., Zhang H. J. Chem. Soc. Dalton Trans. 1995;3335.
4. Kot W.K., Shalimoff G.V., Edelstein N.M., Edelman M.A., Lappert M.F. J. Am. Chem. Soc. 110:1988;986.
5. Bursten B.E., Rhodes L.F., Strittmatter R.J. J. Am. Chem. Soc. 111:1989;2756.
6. Parry J.S., Cloke F.G.N., Coles S.J., Hursthouse M.B. J. Am. Chem. Soc. 121:1999;6867.
7. Blake P.C., Edelman M.A., Hitchcock P.B., Hu J., Lappert M.F., Tian S., Müller G., Atwood J.L., Zhang H. J. Organomet. Chem. 551:1998;261.
8. cf. Phillips C.S.G., Williams R.J.P. Inorganic Chemistry. 1:1965;58 Oxford University Press, London.
9. J. Brennan, J.C. Green, Personal communication.
10. cf. Carnall W.T. Marks T.J., Fischer R.D. Organometallics of the f-Elements. 1979;Reidel, Dordrecht.
11. Ballhausen C.J. Introduction to Ligand Field Theory. 1962;McGraw Hill, New York. (p. 133).
12. Edelman M.A., Hitchcock P.B., Hu J., Lappert M.F. New J. Chem. 19:1995;481.
13. Gamp E., Edelstein N., Khan Malek C., Hubert S., Genet M. J. Chem. Phys. 79:1983;2023.
14. Fair C.F. MolEN: a program package for crystal structure determination. 1990;Enraf-Nonius, Delft, The Netherlands.