Modular Self-Assembly of a Microporous Solid Based upon Mercuracarborand-4 and a New Bonding Motif

Angewandte Chemie - International Edition

Volumn 40, Issue 11, 2001, Pages 2124-2126

  Lee, Hans ^a   Knobler, Carolyn B ^a   Hawthorne, M Frederick ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000263311     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3773(20010601)40:11<2124::AID-ANIE2124>3.0.CO;2-W     Document Type: Article

References (39)

1. M. F. Hawthorne, Z. Zheng, Acc. Chem. Res. 1997, 30, 267-276.
2. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
3. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
4. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
5. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
6. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
7. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
8. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
9. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
10. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
11. Examples of multidentate Lewis acids: a) M. Tsunoda, F. P. Gabbaï, J. Am. Chem. Soc. 2000, 122, 8335-8336; b) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbaï, Angew. Chem. 1999, 111, 3769-3771; Angew. Chem. Int. Ed. 1999, 38, 3547-3549; c) T. Ooi, T. Miura, K. Maruoka, Angew. Chem. 1998, 110, 2524-2526; Angew. Chem. Int. Ed. 1998, 37, 2347-2349; d) J. D. Wuest, Acc. Chem. Res. 1999, 32, 81-89; e) R. Altmann, K. Jurkschat, M. Schürmann, Organometallics 1998, 17, 5858-5866; f) M. Tschinkl, A. Schier, J. Riede, F. P. Gabbä, Inorg. Chem. 1997, 36, 5706-5711; g) F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646; h) P. D. Beer, D. K. Smith in Progress in Inorganic Chemistry, Vol. 46 (Ed.: K. D. Karlin), Wiley, New York, 1997, pp. 1-97.
12. H. Lee, M. Diaz, C. B. Knobler, M. F. Hawthorne, Angew. Chem. 2000, 112, 792-794; Angew. Chem. Int. Ed. 2000, 39, 776-778.
13. H. Lee, M. Diaz, C. B. Knobler, M. F. Hawthorne, Angew. Chem. 2000, 112, 792-794; Angew. Chem. Int. Ed. 2000, 39, 776-778.
14. a) I. H. A. Badr, R. D. Johnson, M. Diaz, M. F. Hawthorne, L. G. Bachas, Anal. Chem. 2000, 72, 4249-4254;
15. b) I. H. A. Badr, M. Diaz, M. F. Hawthorne, L. G. Bachas, Anal. Chem. 1999, 71, 1371-1377.
16. H. Lee, M. Diaz, M. F. Hawthorne, Tetrahedron Lett. 1999, 40, 7651-7655.
17. J. Li, C. F. Logan, M. Jones, Jr., Inorg. Chem. 1991, 30, 4866-4868.
18. Z. Zheng, C. B. Knobler, M. D. Mortimer, G. Kong, M. F. Hawthorne, Inorg. Chem. 1996, 35, 1235-1243.
19. a) H. Lee, C. B. Knobler, M. F. Hawthorne, Chem. Commun. 2000, 2485-2486;
20. b) G. Harakas, T. Vu, C. B. Knobler, M. F. Hawthorne, J. Am. Chem. Soc. 1998. 120,6405-6406.
21. P. C. Andrews, C. L. Raston, J. Organomet. Chem. 2000, 600, 174-185.
22. a) M. J. Hardie, C. L. Raston, Eur. J. Inorg. Chem. 1999, 195-200;
23. b) P. D. Godfrey, W. J. Grigsby, P. J. Nichols, C. L. Raston, J. Am. Chem. Soc. 1997, 119, 9283-9284.
24. R. N. Grimes, Carboranes, Academic Press, New York, 1970, p. 66.
25. 3, both near Hg. Data were processed by using the Bruker SMART 1000 software package. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-158870. Copies of the data can be obtained free of charge on application to CTDC, 12 Union Road, Cambridge CB21EZ, UK (fax: ( + 44) 1223-336-033; e-mail: deposit@ccdc.cam. ac.uk).
26. A. J. Canty, G. B. Deacon, Inorg. Chim. Acta 1980, 45, L225-L227.
27. L. Pauling, The Nature of the Chemical Bond, 3rd ed., Cornell University Press, Ithaca, 1960, p. 260.
28. X. Yang, C. B. Knobler, M. F. Hawthorne, J. Am. Chem. Soc. 1992, 114, 380-382.
29. V.B. Shur, I.A. Tikhonova, A. I. Yanovsky, Y. T. Struchkov, P. V. Petrovskii, S. Y. Panov, G. G. Furin, M. E. Vol'pin, Dokl. Akad. Nauk SSSR 1991, 321, 1002-1004.
30. A. Bondi, J. Phys. Chem. 1964, 68, 441-451.
31. Angle B9-I9-I9′-B9′ = 180. a) V. R. Pedireddi, D.S. Reddy, B. S. Goud, D. C. Craig, A. D. Rae, G. R. Desiraju, J. Chem. Soc. Perkin Trans. 2 1994, 2354-2360; b) G. R. Desiraju, R. Parthasarathy, J. Am. Chem. Soc. 1989, 111, 8725-8726.
32. Angle B9-I9-I9′-B9′ = 180. a) V. R. Pedireddi, D.S. Reddy, B. S. Goud, D. C. Craig, A. D. Rae, G. R. Desiraju, J. Chem. Soc. Perkin Trans. 2 1994, 2354-2360; b) G. R. Desiraju, R. Parthasarathy, J. Am. Chem. Soc. 1989, 111, 8725-8726.
33. [14] [20]
34. O. M. Yaghi, H. Li, C. Davis, D. Richardson, T. L. Groy, Acc. Chem. Res. 1998, 31, 474-484.
35. a) J. S. Seo, D. Whang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature 2000, 404, 982-986;
36. b) A. Heckel, D. Seebach, Angew. Chem. 2000, 112, 165-167; Angew. Chem. Int. Ed. 2000, 39, 163-165;
37. b) A. Heckel, D. Seebach, Angew. Chem. 2000, 112, 165-167; Angew. Chem. Int. Ed. 2000, 39, 163-165;
38. T. Sawaki, T. Dewa, Y. Aoyama, J. Am. Chem. Soc. 1998, 120, 8539-8540.
39. M. A. Sens, N. K. Wilson, P. D. Ellis, J. D. Odom, J. Magn. Reson. 1975, 19, 323-336.