Synthesis, characterization, and structural studies of transition metal open fulvalene complexes

Organometallics

Volumn 17, Issue 19, 1998, Pages 4240-4248

  Weng, Wei Qing ^a   Arif, Atta M ^a   Ernst, Richard D ^a  

^a UNIVERSITY OF UTAH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000250547     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980426a     Document Type: Article

References (72)

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27. Obviously one could envision also end-center-coupled open fulvalene ligands, which although being more complicated spectroscopically should lead to some interesting behavior as a result of the metal centers then becoming nonequivalent.
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49. ( 19) An esd of 0.001 Å for the average value can be derived on the basis of the esd's of the individual values. This esd will reflect the uncertainty in the average value, but not the distribution of the individual values, which vary significantly.
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55. Turpin, G, C.; Ernst, R. D. Unpublished results.
56. A similar tilt of 12.0° can also be derived, on the basis of the average deviation of 0.307 Å of C5 and C6 from their adjacent planes and the C5-C6 distance.
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63. 28b
64. (b) Trupia, S.; Vos, D.; Geiger, W. E. Personal communication.
65. Boone, D. R.; Ernst, R. D. Unpublished results.
66. See also: (a) Bohlmann, F. Chem. Ber. 1952, 85, 386. (b) Hayashi, T.; Sasaoka, K; Oishi, T. Chem. Commun. 1990, 1362.
67. See also: (a) Bohlmann, F. Chem. Ber. 1952, 85, 386. (b) Hayashi, T.; Sasaoka, K; Oishi, T. Chem. Commun. 1990, 1362.
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69. 32b
70. (b) Weng, W.-Q.; Trankarnpruk, W.; Ernst, R. D.; Rheingold, A. L. Unpublished results.
71. For similar species see also: (a) Doering, W.v. E.; Birladeanu, L.; Sarma, K.; Shao, L.-S. J. Am. Chem. Soc. 1996, 118, 6660. (b) Rubin, Y.; Knobler, C. B.; Diedrich, F. Ang. Chem. Intl. Ed. 1991, 30, 698.
72. For similar species see also: (a) Doering, W.v. E.; Birladeanu, L.; Sarma, K.; Shao, L.-S. J. Am. Chem. Soc. 1996, 118, 6660. (b) Rubin, Y.; Knobler, C. B.; Diedrich, F. Ang. Chem. Intl. Ed. 1991, 30, 698.