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Preliminary communication: Brown, D.; Delville-Desbois, M.-H.; Vollhardt, K. P. C.; Astruc, D. Angew. Chem. 1994, 106, 715; Angew. Chem., Int. Ed. Engl. 1994, 33, 661.
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3843093498
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note
-
D are the charges of the acceptor and donor, respectively. In some cases, this term can be large, but not here. For more details, see for instance ref 4, Chapter 1.
-
-
-
-
90
-
-
3843109732
-
-
The reduction potential of the bimetallic complexes was reported in ref 55. The values obtained by us are more negative than in ref 55
-
The reduction potential of the bimetallic complexes was reported in ref 55. The values obtained by us are more negative than in ref 55.
-
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92
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0025399229
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(a) Similarly, the influence of counteranions on electrocatalytic reactions propagated by organometallic cations has also been observed; see ref 61 and: Verpeaux, J.-N.; Desbois, M.-H.; Madonik, A. M.; Amatore, C.; Astruc, D. Organometallics 1990, 9, 630.
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Verpeaux, J.-N.1
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93
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3843142405
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For discussion, see ref 4, Chapter 6
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(b) For discussion, see ref 4, Chapter 6.
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(c) Gubin, S. P.; Smirnova, S. A.; Denisovitch, L. I. J. Organomet. Chem. 1971, 30, 257.
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For previous examples of cathodically induced substitution of CO by more electron-releasing ligands in mononuclear complexes bearing an electron-sink ligand, see: (a) Lahuerta, P.; Latorre, J.; Sanan, M.; Kisch, H. J. Organomet. Chem. 1985, 286, C27. (b) Olbrich-Deussner, B.; Gross, R.; Kaim, W. J. Organomet. Chem. 1989, 366, 155.
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For previous examples of cathodically induced substitution of CO by more electron-releasing ligands in mononuclear complexes bearing an electron-sink ligand, see: (a) Lahuerta, P.; Latorre, J.; Sanan, M.; Kisch, H. J. Organomet. Chem. 1985, 286, C27. (b) Olbrich-Deussner, B.; Gross, R.; Kaim, W. J. Organomet. Chem. 1989, 366, 155.
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0001822401
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A similar delocalization is encountered in cathodically induced substitution of CO by phosphorus donors in transition-metal clusters; see refs 40, 41, and 61 (pp 434-443). For examples, see: Bruce, M. I. Coord. Chem. Rev. 1987, 76, 1.
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See ref. 4, Chapter 5 (pp 333-337), and for example: (a) Shi, Q. Z.; Richmond, T. G.; Trogler, W. C.; Basolo, F. J. Am. Chem. Soc. 1984, 106, 71; 1982, 104, 4032. (b) Brown, T. L. In Organometallic Radical Processes; Trogler, W. C., Ed.; J. Organomet. Chem. Libr. 22; Eisevier: New York, 1990; Vol. 22, p 67.
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See ref. 4, Chapter 5 (pp 333-337), and for example: (a) Shi, Q. Z.; Richmond, T. G.; Trogler, W. C.; Basolo, F. J. Am. Chem. Soc. 1984, 106, 71; 1982, 104, 4032. (b) Brown, T. L. In Organometallic Radical Processes; Trogler, W. C., Ed.; J. Organomet. Chem. Libr. 22; Eisevier: New York, 1990; Vol. 22, p 67.
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Organometallic Radical Processes; Trogler, W. C., Ed.; Eisevier: New York
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See ref. 4, Chapter 5 (pp 333-337), and for example: (a) Shi, Q. Z.; Richmond, T. G.; Trogler, W. C.; Basolo, F. J. Am. Chem. Soc. 1984, 106, 71; 1982, 104, 4032. (b) Brown, T. L. In Organometallic Radical Processes; Trogler, W. C., Ed.; J. Organomet. Chem. Libr. 22; Eisevier: New York, 1990; Vol. 22, p 67.
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Brown, T.L.1
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For the EE and ECE mechanisms see, for instance, ref 4, Chapter 2 (pp 123-128), and: Heinze, H. Angew. Chem., Int. Ed. Engl. 1984, 23, 831.
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37049079706
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For a thoroughly characterized example, see: (a) Astruc, D.; Lacoste, M.; Toupet, L. J. Chem. Soc., Chem. Commun. 1990, 558. (b) Lacoste, M.; Rabaâ, H.; Astruc, D.; Ardoin, N.; Varret, F.; Saillard, J.-Y.; Le Beuze, A. J. Am. Chem. Soc. 1990, 112, 9548.
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Astruc, D.1
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For a thoroughly characterized example, see: (a) Astruc, D.; Lacoste, M.; Toupet, L. J. Chem. Soc., Chem. Commun. 1990, 558. (b) Lacoste, M.; Rabaâ, H.; Astruc, D.; Ardoin, N.; Varret, F.; Saillard, J.-Y.; Le Beuze, A. J. Am. Chem. Soc. 1990, 112, 9548.
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Lacoste, M.1
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(a) Finke, R. G.; Voegeli, R. H.; Laganis, E. D.; Boekelheide, V. Organometallics 1983, 2, 347.
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(b) Bowyer, W. J.; Geiger, W. E.; Boekelheide, V. Organometallics 1984, 3, 1079.
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(a) Bower, W. J.; Merkert, J. W.; Geiger, W. E.; Rheingold, A. L. Organometallics 1989, 8, 191.
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84926121843
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3) has not been characterized to our knowledge; see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 2nd ed.; Wiley: New York, 1994. (b) Elschenbroich, Ch.; Salzer, A. Organometallics: A Concise Introduction, 2nd ed.; VCH: Weinheim, Germany, 1992. (c) Collman, J.-P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
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Salzer, A.2
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84926121843
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University Science Books: Mill Valley, CA
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3) has not been characterized to our knowledge; see: (a) Crabtree, R. H. The Organometallic Chemistry of the Transition Metals, 2nd ed.; Wiley: New York, 1994. (b) Elschenbroich, Ch.; Salzer, A. Organometallics: A Concise Introduction, 2nd ed.; VCH: Weinheim, Germany, 1992. (c) Collman, J.-P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
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See: (a) Reference 4, Chapter 7. (b) Savéant, J.-M. Acc. Chem. Res. 1980, 13, 323. (c) Savéant, J.-M. In Mechanisms and Processes in Molecular Chemistry. Astruc, D., Ed. New J. Chem. 1992, 16, 131. (d) Reference 4, Chapter 1.
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