Carbon-13 kinetic isotope effects in the decarbonylation of liquid formic acid in water solution

Isotopes in Environmental and Health Studies

Volumn 35, Issue 3, 1999, Pages 157-165

  Zielinski M ^a   Ogrinc, N ^b   Kobal, I ^b   Zielinska A ^a   Papiernik Zielinska H ^a  

^a JAGIELLONIAN UNIVERSITY   (Poland)

^b JO EF STEFAN INSTITUTE   (Slovenia)

Author keywords

Carbon 13; Decarbonylation; Formic acid; Isotope effects; Kinetic parameters; Water solution

Indexed keywords

EID: 0000220506     PISSN: 10256016     EISSN: None     Source Type: Journal    
DOI: 10.1080/10256019908234091     Document Type: Article

References (20)

1. Yankwich, P. E. and Haschemeyer, R. H. (1963). Temperature dependence of the carbon isotope effect in the decarbonylation of liquid formic acid. J. Phys. Chem., 67, 694-696.
2. Zieliński, M., Zielińska, A., Bernasconi, S. and Papiernik-Zielińska, H. (1997). Carbon-13 intermolecular isotope effect in the decarbonylation of liquid extrapure Merck formic acid. J. Radioanal. Nucl. Chem., 220, 263-265.
3. Barham, H. N. and Clark, L. W. (1951). The decomposition of formic acid at low temperatures. J. Am. Chem. Soc., 73, 4638-4640.
4. 13C Isotope effect in the decarboxylation of phenylpropiolic acid in water solution. Manuscript (No. 1123); submitted for publication in Polish J. Chem.; Zieliński, M. and Zielińska, A., Paul, H., Bernasconi, S., Ogrinc, N., Kobal, I. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid in sulphuric acid, manuscript (No. 1134), 73, 1029-1036 Polish. J. Chem.; Zielińska, A., Zieliński, M. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid (PPA) in orthophosphoric acid. NUKLEONIKA The International J. of Nucl. Research, 44, 403-410.
5. 13C Isotope effect in the decarboxylation of phenylpropiolic acid in water solution. Manuscript (No. 1123); submitted for publication in Polish J. Chem.; Zieliński, M. and Zielińska, A., Paul, H., Bernasconi, S., Ogrinc, N., Kobal, I. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid in sulphuric acid, manuscript (No. 1134), 73, 1029-1036 Polish. J. Chem.; Zielińska, A., Zieliński, M. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid (PPA) in orthophosphoric acid. NUKLEONIKA The International J. of Nucl. Research, 44, 403-410.
6. 13C Isotope effect in the decarboxylation of phenylpropiolic acid in water solution. Manuscript (No. 1123); submitted for publication in Polish J. Chem.; Zieliński, M. and Zielińska, A., Paul, H., Bernasconi, S., Ogrinc, N., Kobal, I. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid in sulphuric acid, manuscript (No. 1134), 73, 1029-1036 Polish. J. Chem.; Zielińska, A., Zieliński, M. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid (PPA) in orthophosphoric acid. NUKLEONIKA The International J. of Nucl. Research, 44, 403-410.
7. 13C Isotope effect in the decarboxylation of phenylpropiolic acid in water solution. Manuscript (No. 1123); submitted for publication in Polish J. Chem.; Zieliński, M. and Zielińska, A., Paul, H., Bernasconi, S., Ogrinc, N., Kobal, I. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid in sulphuric acid, manuscript (No. 1134), 73, 1029-1036 Polish. J. Chem.; Zielińska, A., Zieliński, M. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid (PPA) in orthophosphoric acid. NUKLEONIKA The International J. of Nucl. Research, 44, 403-410.
8. 13C Isotope effect in the decarboxylation of phenylpropiolic acid in water solution. Manuscript (No. 1123); submitted for publication in Polish J. Chem.; Zieliński, M. and Zielińska, A., Paul, H., Bernasconi, S., Ogrinc, N., Kobal, I. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid in sulphuric acid, manuscript (No. 1134), 73, 1029-1036 Polish. J. Chem.; Zielińska, A., Zieliński, M. and Papiernik-Zielińska, H. (1999). Carbon-13 isotope effect in the decarboxylation of phenylpropiolic acid (PPA) in orthophosphoric acid. NUKLEONIKA The International J. of Nucl. Research, 44, 403-410.
9. Zieliński, M., Zielińska, A., Paul, H. and Papiernik-Zielińska, H., Kinetyczny efekt izotopowy wȩgla-13 w reakcji dekarboksylacji kwasu fenylopropiolowego w bezwodnym kwasie mrówkowym (in Polish, summary in English: Kinetic isotope effect of carbon-13 in the decarboxylation reaction of phenylpropiolic acid in water free formic acid.). Lecture published in Proceedings of The National Symposium on Isotope Applications in Industry, Medicine, Agriculture and Environmental Protection, Cracow, September 16-18, 1998, pp. 211-215. (Editors: Galant, S., Olszyńska, E. and Zimnoch, M., Fax (12)634-00-10, e-mail: KONF98@FTJ.AGH.EDU.PL).
10. Zieliński, M., Zielińska, A. and Papiernik-Zielińska, H. (1996). Temperature dependence of the carbon-13 isotope effect in the decarbonylation of concentrated formic acid solutions of sodium chloride and metaphosphoric acid reagent. Isotopes Environ. Health Stud., 32, 31-39.
11. Oesselman, J., Sample Preparation and Sample Handling for Gas Mass Spectrometers, Finnigan MAT Textronica, Oberriet/Switzerland 1990/1991.
12. Zieliński, M. Isotope Effects in Chemistry, Part I, Chapter 6, Experimental methods of determination of isotopic ratios, 1974 Jag. Univ. Press (Waligóra, B. and Ślaska, H., Eds.), pp. 62-112.
13. Eyring, H. and Cagle, F. W., Jr. (1952). The significance of isotopic reactions in rate theory. J. Phys. Chem., 56, 897-901.
14. Zieliński, M. (1979). Isotope Effects in Chemistry. Polish Sci. Publ. (Wawrzeńczak, A. Ed.), Warsaw, pp. 102-104.
15. Zieliński, M., Zielińska, A. and Papiernik-Zielińska, H. (1994). Carbon-13 kinetic isotope effects in the decarbonylation of formic acid of natural isotopic composition in phosphoric acid media. J. Radioanal. Nucl. Chem. Articles, 183, 301-311.
16. Zieliński, M. and Zielińska, A. (1995). Carbon-13 kinetic isotope effects in the decarbonylation of liquid formic acid of natural isotopic composition initiated by phosphorus pentoxide. J. Radioanal Nucl. Chem. Articles, 198, 3-15.
17. Zieliński, M., Zielińska, A. and Papiernik-Zielińska, H. (1998). A contribution to studies of carbon-13 kinetic isotope effect of the decarbonylation of liquid formic acid in the presence of phosphoric acids. Nukleonika, 43, 41-48.
18. 7. Nukleonika, 43, 49-56.
19. 5. Nukleonika, 43, 57-64.
20. Zieliński, M., Zielińska, A. and Papiernik-Zielińska, H. (1998). Carbon-13 kinetic isotope effects in the decarbonylation of liquid formic acid assisted with acetic anhydride. Isotopes Environ. Health Stud., 34, 285-289.