메뉴 건너뛰기




Volumn 32, Issue 1, 1996, Pages 31-39

Temperature dependence of the carbon-13 isotope effect in the decarbonylation of concentrated formic acid solutions of sodium chloride and of metaphosphoric acid reagent

Author keywords

Carbon 13; Decarbonylation; Formic acid; Isotope effects; Metaphosphoric acid reagent; Sodium chloride; Structure breakers

Indexed keywords


EID: 0002208078     PISSN: 10256016     EISSN: None     Source Type: Journal    
DOI: 10.1080/10256019608036291     Document Type: Article
Times cited : (9)

References (31)
  • 1
    • 0000911245 scopus 로고
    • The decomposition of formic acid at low temperatures
    • H. N. Barham and L. W. Clark: The decomposition of formic acid at low temperatures. J. Am. Chem. Soc., 73 (1951) 4638-4640.
    • (1951) J. Am. Chem. Soc. , vol.73 , pp. 4638-4640
    • Barham, H.N.1    Clark, L.W.2
  • 2
    • 0009158098 scopus 로고
    • Temperature dependence of the carbon isotope effect in the decarbonylation of liquid formic acid
    • P. E. Yankwich and R. H. Haschemeyer: Temperature dependence of the carbon isotope effect in the decarbonylation of liquid formic acid. J. Phys. Chem., 67 (1963) 694-696.
    • (1963) J. Phys. Chem. , vol.67 , pp. 694-696
    • Yankwich, P.E.1    Haschemeyer, R.H.2
  • 4
    • 0028053882 scopus 로고
    • Carbon-13 kinetic isotope effects in the decarbonylation of formic acid of natural isotopic composition in phosphoric acid media
    • and ref. cited there
    • M. Zieliński, A. Zielińska, H. Papiernik-Zielińska: Carbon-13 kinetic isotope effects in the decarbonylation of formic acid of natural isotopic composition in phosphoric acid media. J. Radioanal. Nucl. Chem., Articles, 183 (1994) 301-311 and ref. cited there.
    • (1994) J. Radioanal. Nucl. Chem., Articles , vol.183 , pp. 301-311
    • Zieliński, M.1    Zielińska, A.2    Papiernik-Zielińska, H.3
  • 7
    • 33947464857 scopus 로고
    • The significance of isotopic reactions in rate theory
    • H. Eyring and F. W. Cagle, Jr : The significance of isotopic reactions in rate theory. J. Phys. Chem., 56 (1952) 897-901.
    • (1952) J. Phys. Chem. , vol.56 , pp. 897-901
    • Eyring, H.1    Cagle Jr., F.W.2
  • 8
    • 0003326074 scopus 로고
    • Isotope Effects in Chemistry
    • Warsaw
    • M. Zieliński: Isotope Effects in Chemistry. Polish Sci. Publ., 1979, Warsaw, pp. 102-104.
    • (1979) Polish Sci. Publ. , pp. 102-104
    • Zieliński, M.1
  • 9
    • 0028787282 scopus 로고
    • Carbon-13 kinetic isotope effects in the decarbonylation of liquid formic acid of natural isotopic composition initiated by phosphorus pentoxide
    • M. Zieliński, A. Zielińska: Carbon-13 kinetic isotope effects in the decarbonylation of liquid formic acid of natural isotopic composition initiated by phosphorus pentoxide. J. Radioanal. Nucl. Chem., Articles, 198 (1995) 3-15.
    • (1995) J. Radioanal. Nucl. Chem., Articles , vol.198 , pp. 3-15
    • Zieliński, M.1    Zielińska, A.2
  • 10
    • 3343008042 scopus 로고
    • The influence of addition of inorganic carbonates on the relative volatility factor of light and heavy water at temperatures close to the isotope effect inversion temperature
    • A. Selecki, A. G. Chmielewski: The influence of addition of inorganic carbonates on the relative volatility factor of light and heavy water at temperatures close to the isotope effect inversion temperature. Isotopenpraxis, 15 (1979) 99-103.
    • (1979) Isotopenpraxis , vol.15 , pp. 99-103
    • Selecki, A.1    Chmielewski, A.G.2
  • 11
    • 0342412135 scopus 로고
    • Vapor-pressure studies involving solutions in light and heavy waters. III. the separation factor for the isotopes of hydrogen during distillation from salts solution in the mixed waters at room temperature
    • [a] J. M. Googin and H. A. Smith: Vapor-pressure studies involving solutions in light and heavy waters. III. The separation factor for the isotopes of hydrogen during distillation from salts solution in the mixed waters at room temperature. J. Phys. Chem., 61 (1957) 345-350.
    • (1957) J. Phys. Chem. , vol.61 , pp. 345-350
    • Googin, J.M.1    Smith, H.A.2
  • 14
    • 85033805323 scopus 로고
    • Origin and Interpretation of Isotope Effects
    • Chapter 4 in: Isotope Effects in Chemical Reactions Eds.: C. J. Collins and N. S. Bowman, Van Nostrand Reinhold Co., New York, and ref. cited there
    • E. K. Thornton and E. R. Thornton: Origin and Interpretation of Isotope Effects. Chapter 4 in: Isotope Effects in Chemical Reactions. ACS Monograph (Eds.: C. J. Collins and N. S. Bowman), Van Nostrand Reinhold Co., New York, 1971, and ref. cited there.
    • (1971) ACS Monograph
    • Thornton, E.K.1    Thornton, E.R.2
  • 15
    • 0041491591 scopus 로고    scopus 로고
    • Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects
    • J. Szydłowski: Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects. J. Mol. Struct., 321(1994) 101-113 and ref. cited there: I. B. Rabinovich: Influence of Isotopy on Physicochemical Properties of Liquids. Consultant Bureau, New York, 1970, G. Janco and W. A. Van Hook: Condensed phase isotope effects. Chem. Rev., 74 (1974) 689-750 and 757 ref. cited there, R. A. More O'Ferrall, G. W. Koeppl and A. J. Kresge: Vibrational analyses of liquid water and the hydronium ion in aqueous solution. J. Am. Chem. Soc., 93 (1971) 1-9, ibid Solvent isotope effects upon proton transfer from the hydronium ion, pp. 9-20.
    • (1994) J. Mol. Struct. , vol.321 , pp. 101-113
    • Szydłowski, J.1
  • 16
    • 0041491591 scopus 로고    scopus 로고
    • Consultant Bureau, New York
    • J. Szydłowski: Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects. J. Mol. Struct., 321(1994) 101-113 and ref. cited there: I. B. Rabinovich: Influence of Isotopy on Physicochemical Properties of Liquids. Consultant Bureau, New York, 1970, G. Janco and W. A. Van Hook: Condensed phase isotope effects. Chem. Rev., 74 (1974) 689-750 and 757 ref. cited there, R. A. More O'Ferrall, G. W. Koeppl and A. J. Kresge: Vibrational analyses of liquid water and the hydronium ion in aqueous solution. J. Am. Chem. Soc., 93 (1971) 1-9, ibid Solvent isotope effects upon proton transfer from the hydronium ion, pp. 9-20.
    • (1970) Influence of Isotopy on Physicochemical Properties of Liquids
    • Rabinovich, I.B.1
  • 17
    • 33847804620 scopus 로고
    • Condensed phase isotope effects
    • and 757 ref. cited there
    • J. Szydłowski: Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects. J. Mol. Struct., 321(1994) 101-113 and ref. cited there: I. B. Rabinovich: Influence of Isotopy on Physicochemical Properties of Liquids. Consultant Bureau, New York, 1970, G. Janco and W. A. Van Hook: Condensed phase isotope effects. Chem. Rev., 74 (1974) 689-750 and 757 ref. cited there, R. A. More O'Ferrall, G. W. Koeppl and A. J. Kresge: Vibrational analyses of liquid water and the hydronium ion in aqueous solution. J. Am. Chem. Soc., 93 (1971) 1-9, ibid Solvent isotope effects upon proton transfer from the hydronium ion, pp. 9-20.
    • (1974) Chem. Rev. , vol.74 , pp. 689-750
    • Janco, G.1    Van Hook, W.A.2
  • 18
    • 33947291389 scopus 로고
    • Vibrational analyses of liquid water and the hydronium ion in aqueous solution
    • J. Szydłowski: Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects. J. Mol. Struct., 321(1994) 101-113 and ref. cited there: I. B. Rabinovich: Influence of Isotopy on Physicochemical Properties of Liquids. Consultant Bureau, New York, 1970, G. Janco and W. A. Van Hook: Condensed phase isotope effects. Chem. Rev., 74 (1974) 689-750 and 757 ref. cited there, R. A. More O'Ferrall, G. W. Koeppl and A. J. Kresge: Vibrational analyses of liquid water and the hydronium ion in aqueous solution. J. Am. Chem. Soc., 93 (1971) 1-9, ibid Solvent isotope effects upon proton transfer from the hydronium ion, pp. 9-20.
    • (1971) J. Am. Chem. Soc. , vol.93 , pp. 1-9
    • More O'Ferrall, R.A.1    Koeppl, G.W.2    Kresge, A.J.3
  • 19
    • 0041491591 scopus 로고    scopus 로고
    • ibid
    • J. Szydłowski: Isotope effects on phase equilibria in hydrogen bonded systems, especially vapor pressure and miscibility isotope effects. J. Mol. Struct., 321(1994) 101-113 and ref. cited there: I. B. Rabinovich: Influence of Isotopy on Physicochemical Properties of Liquids. Consultant Bureau, New York, 1970, G. Janco and W. A. Van Hook: Condensed phase isotope effects. Chem. Rev., 74 (1974) 689-750 and 757 ref. cited there, R. A. More O'Ferrall, G. W. Koeppl and A. J. Kresge: Vibrational analyses of liquid water and the hydronium ion in aqueous solution. J. Am. Chem. Soc., 93 (1971) 1-9, ibid Solvent isotope effects upon proton transfer from the hydronium ion, pp. 9-20.
    • Solvent Isotope Effects Upon Proton Transfer from the Hydronium Ion , pp. 9-20
  • 21
    • 84982076683 scopus 로고
    • Mixed carboxylic acid anhydrides. I. Acetic-formic anhydride
    • W. Stevens and A. van Es: Mixed carboxylic acid anhydrides. I. Acetic-formic anhydride. Rec. Trav. Chim., 83 (1964) 863-872, part II, ibid 83 (1964) 1287-1293, part III, ibid, 83 (1964) 1294-1298.
    • (1964) Rec. Trav. Chim. , vol.83 , pp. 863-872
    • Stevens, W.1    Van Es, A.2
  • 22
    • 84982076683 scopus 로고
    • Mixed carboxylic acid anhydrides. Part II. Acetic-formic anhydride
    • W. Stevens and A. van Es: Mixed carboxylic acid anhydrides. I. Acetic-formic anhydride. Rec. Trav. Chim., 83 (1964) 863-872, part II, ibid 83 (1964) 1287-1293, part III, ibid, 83 (1964) 1294-1298.
    • (1964) Rec. Trav. Chim. , vol.83 , pp. 1287-1293
  • 23
    • 84982076683 scopus 로고
    • Mixed carboxylic acid anhydrides. Part III. Acetic-formic anhydride
    • W. Stevens and A. van Es: Mixed carboxylic acid anhydrides. I. Acetic-formic anhydride. Rec. Trav. Chim., 83 (1964) 863-872, part II, ibid 83 (1964) 1287-1293, part III, ibid, 83 (1964) 1294-1298.
    • (1964) Rec. Trav. Chim. , vol.83 , pp. 1294-1298
  • 24
    • 84982383625 scopus 로고
    • Mixed carboxylic acid anhydrides. IV. Formic anhydride
    • R. Schijf, J. W. Scheeren, A. van Es, and W. Stevens: Mixed carboxylic acid anhydrides. IV. Formic anhydride. Rec. Trav. Chim., 84 (1965) 594-596.
    • (1965) Rec. Trav. Chim. , vol.84 , pp. 594-596
    • Schijf, R.1    Scheeren, J.W.2    Van Es, A.3    Stevens, W.4
  • 25
    • 84985565956 scopus 로고
    • Formic Anhydride
    • G. A. Olah, Y. D. Vankar, M. Arvanaghi and J. S. Sommer: Formic Anhydride. Angew. Chem. Int. Ed. Engl., 18 (1979) 614, (Angew. Chem., 91 (1979)649), and ref. cited there: I. Muramatsu, M. Itoi, M. Tsuji, and A. Hagitani, Bull. Chem. Soc. Japan, 37 (1964) 756.
    • (1979) Angew. Chem. Int. Ed. Engl. , vol.18 , pp. 614
    • Olah, G.A.1    Vankar, Y.D.2    Arvanaghi, M.3    Sommer, J.S.4
  • 26
    • 84985565956 scopus 로고
    • and ref. cited there
    • G. A. Olah, Y. D. Vankar, M. Arvanaghi and J. S. Sommer: Formic Anhydride. Angew. Chem. Int. Ed. Engl., 18 (1979) 614, (Angew. Chem., 91 (1979)649), and ref. cited there: I. Muramatsu, M. Itoi, M. Tsuji, and A. Hagitani, Bull. Chem. Soc. Japan, 37 (1964) 756.
    • (1979) Angew. Chem. , vol.91 , pp. 649
  • 27
    • 84985565956 scopus 로고
    • G. A. Olah, Y. D. Vankar, M. Arvanaghi and J. S. Sommer: Formic Anhydride. Angew. Chem. Int. Ed. Engl., 18 (1979) 614, (Angew. Chem., 91 (1979)649), and ref. cited there: I. Muramatsu, M. Itoi, M. Tsuji, and A. Hagitani, Bull. Chem. Soc. Japan, 37 (1964) 756.
    • (1964) Bull. Chem. Soc. Japan , vol.37 , pp. 756
    • Muramatsu, I.1    Itoi, M.2    Tsuji, M.3    Hagitani, A.4
  • 29
    • 0027772046 scopus 로고
    • Hydration of Alkynes in Anhydrous Medium with Formic Acid as Water Donor
    • N. Menashe and Y. Shvo: Hydration of Alkynes in Anhydrous Medium with Formic Acid as Water Donor. J. Org. Chem., 58 (1993) 7434-7439. ibid, N. Menashe, D. Reshef and Y. Shvo: The reaction of alkynes and formic acid. 56 (1991) 2912-2914.
    • (1993) J. Org. Chem. , vol.58 , pp. 7434-7439
    • Menashe, N.1    Shvo, Y.2
  • 30
    • 0027772046 scopus 로고
    • N. Menashe and Y. Shvo: Hydration of Alkynes in Anhydrous Medium with Formic Acid as Water Donor. J. Org. Chem., 58 (1993) 7434-7439. ibid, N. Menashe, D. Reshef and Y. Shvo: The reaction of alkynes and formic acid. 56 (1991) 2912-2914.
    • (1993) J. Org. Chem. , vol.58 , pp. 7434-7439
  • 31
    • 0000532109 scopus 로고
    • N. Menashe and Y. Shvo: Hydration of Alkynes in Anhydrous Medium with Formic Acid as Water Donor. J. Org. Chem., 58 (1993) 7434-7439. ibid, N. Menashe, D. Reshef and Y. Shvo: The reaction of alkynes and formic acid. 56 (1991) 2912-2914.
    • (1991) The Reaction of Alkynes and Formic Acid. , vol.56 , pp. 2912-2914
    • Menashe, N.1    Reshef, D.2    Shvo, Y.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.