메뉴 건너뛰기




Volumn 130, Issue 9, 1997, Pages 1201-1212

Carbene structure of stable acyl (formyl) anion equivalents

Author keywords

Ab initio calculations; Acyllithium equivalents; Carbenes; Lithium; Structure elucidation

Indexed keywords


EID: 0000111699     PISSN: 00092940     EISSN: None     Source Type: Journal    
DOI: 10.1002/cber.19971300907     Document Type: Article
Times cited : (39)

References (169)
  • 1
    • 84913643549 scopus 로고
    • Staudinger mentioned that the corresponding imino com pounds (NR instead of O) should be more stable, see réf[6].
    • [1a] H. Staudinger, ber. Dtsch. Chem. Ges. 1908, 41, 2217-2219. Staudinger mentioned that the corresponding imino com pounds (NR instead of O) should be more stable, see réf[6].
    • (1908) Ber. Dtsch. Chem. Ges. , vol.41 , pp. 2217-2219
    • Staudinger, H.1
  • 4
    • 0001166234 scopus 로고
    • [1dl G. Wittig, Angew. Chem. 1940, 53, 241-247, footnote 58;
    • (1940) Angew. Chem. , vol.53 , pp. 241-247
    • Wittig, G.1
  • 16
    • 75449115093 scopus 로고
    • Angew. Chem. 1971, 83, 334;
    • (1971) Angew. Chem. , vol.83 , pp. 334
  • 33
    • 33745422684 scopus 로고
    • [1u] D. Seyferth, R. C. Hui, W. L. Wang ibid. 1993, 55, 5843-5845, and papers of D. Seyferth et al. cited therein.
    • (1993) Ibid. , vol.55 , pp. 5843-5845
    • Seyferth, D.1    Hui, R.C.2    Wang, W.L.3
  • 42
    • 0001232019 scopus 로고
    • D. Seebach, Angew. Chem. 1969, 81, 690-700. Angew. Client. Int. Ed. Engl. 1969, 8, 639-649.
    • (1969) Angew. Chem. , vol.81 , pp. 690-700
    • Seebach, D.1
  • 58
    • 33745421664 scopus 로고
    • respect. 1970, 9, 458;
    • (1970) Respect. , vol.9 , pp. 458
  • 60
    • 33745353209 scopus 로고
    • respect. 1972, 11, 311.
    • (1972) Respect. , vol.11 , pp. 311
  • 67
    • 85085781931 scopus 로고    scopus 로고
    • [26-28].
    • [26-28].
  • 69
    • 33745343897 scopus 로고    scopus 로고
    • taken from the Ph. D. Dissertation of C. Hilf, Phi lipps-Universität Marburg, 1995.
    • taken from the Ph. D. Dissertation of C. Hilf, Phi lipps-Universität Marburg, 1995.
  • 71
    • 33745366249 scopus 로고
    • [10b] Tetrahedron Lett. 1978, 1, 9-12.
    • (1978) Tetrahedron Lett. , vol.1 , pp. 9-12
  • 72
  • 84
    • 0000772702 scopus 로고
    • [12e] J. Org. Chem. 1989, 54, 693-702.
    • (1989) J. Org. Chem. , vol.54 , pp. 693-702
  • 90
    • 0027302593 scopus 로고
    • [13c] Tetrahedron Lett. 1993, 34, 5475-5478.
    • (1993) Tetrahedron Lett. , vol.34 , pp. 5475-5478
  • 94
    • 33745407224 scopus 로고
    • and réf. cit.
    • [14b] D. M. Smith ibid. 1981, 40, 332-333, and réf. cit.
    • (1981) Ibid. , vol.40 , pp. 332-333
    • Smith, D.M.1
  • 107
    • 33745363668 scopus 로고    scopus 로고
    • Dissertation, Universität Marburg, 1993 and réf. cit.
    • [7d] A. Opel, Dissertation, Universität Marburg, 1993 and réf. cit.
    • Opel, A.1
  • 116
    • 27744536758 scopus 로고    scopus 로고
    • More recent investigations have been published by: [19a]
    • More recent investigations have been published by: [19a] W. A. Herrmann, M. Elison, J. Fischer, C. Köcher, G. R. J. Artus, Chem. Enr. J. 1996,2, 772-780. - (Transition)metal complexes with these carbenes:
    • (1996) Chem. Enr. J. , vol.2 , pp. 772-780
    • Herrmann, W.A.1    Elison, M.2    Fischer, J.3    Köcher, C.4    Artus, G.R.J.5
  • 123
    • 0000081750 scopus 로고    scopus 로고
    • [20a] A recent hiehlight dealing with these carbenes has been published by MT Regitz, Angew. Chem. 1996, 108, 791-794;
    • (1996) Angew. Chem. , vol.108 , pp. 791-794
  • 125
    • 0001602606 scopus 로고    scopus 로고
    • [20b] The crystal structure of bis(diisopropylamino)carbene makes clear, not only that heterocyclic five-membered ring carbenes are stable, but also that donor substituents are required to stabilize a carbene sicnificantly, R. W. Alder, P. R. Allen, M. Murray, A. G. Orpen, Angew. Chem. 1996, 108, 1211-1213;
    • (1996) Angew. Chem. , vol.108 , pp. 1211-1213
    • Alder, R.W.1    Allen, P.R.2    Murray, M.3    Orpen, A.G.4
  • 129
    • 33745350184 scopus 로고    scopus 로고
    • personal communication, July 11, 1994. We are very grateful to A. J. Arduengo III for prepar ing the complex 17, determining its structure, and reporting its structural data to us.
    • A. J. Arduengo III, M. Tamm, personal communication, July 11, 1994. We are very grateful to A. J. Arduengo III for prepar ing the complex 17, determining its structure, and reporting its structural data to us.
    • Arduengo III, A.J.1    Tamm, M.2
  • 130
    • 33745331395 scopus 로고    scopus 로고
    • A. J. Arduengo III, J. R. Gerlich, W. J. Marshall, personal com munication, ^July 25, 1996, and We are grateful to A. J. Arduengo III for providing us with the results prior to publication
    • A. J. Arduengo III, J. R. Gerlich, W. J. Marshall, personal com munication, ^July 25, 1996, and Liebigs Ann.l Recueil, 1997, 365-374. We are grateful to A. J. Arduengo III for providing us with the results prior to publication.
    • (1997) Liebigs Ann.l Recueil , pp. 365-374
  • 136
    • 33745355340 scopus 로고    scopus 로고
    • note
    • Our NMR investigations reveal that lithiated oxazoles lead to fast and complete (within the limits of the measurement: 95±5%) ring opened products 7′, even at -78 °C. The structure of [7'-diglyme]2 could be determined by an X-ray structure analysis, as pointed out earlier'91.
  • 153
    • 0004175997 scopus 로고
    • Siemens Analyti cal X-Ray Instruments, Inc., Madison
    • Siemens SHELXTL PLUS (VMS) Vers. 4.21, Siemens Analyti cal X-Ray Instruments, Inc., Madison 1990.
    • (1990) Siemens SHELXTL plus (VMS) Vers. 4.21
  • 157
    • 33745396604 scopus 로고    scopus 로고
    • note
    • Crystallographic data (excluding structure factors) for the struc ture^) reported in this paper have been deposited with the Cambridge Cristallographie Data Centre. Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge, CB2 1EZ, UK (fax: int. code +44 (0) 1223/336033, e-mail: deposit@chemcrys.cam. ac.uk).
  • 158
    • 33745393653 scopus 로고    scopus 로고
    • Beilstein, Vol. 23, Eil, Springer Verlac, Berlin 1954, p. 187.
    • Beilstein, Vol. 23, Eil, Springer Verlac, Berlin 1954, p. 187.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.